基体温度对磁控溅射沉积ZAO薄膜性能的影响

利用中频交流磁控溅射方法 ,采用氧化锌铝陶瓷靶材 [w(ZnO) =98%、w(Al2 O3 ) =2 % ]制备了ZAO(ZnO∶Al)薄膜 ,观察了基体温度对ZAO薄膜的晶体结构、电学和光学性能的影响 ,采用X射线衍射仪对薄膜的结构进行了分析 ,采用光学分度计和电阻测试仪测量了薄膜的光学、电学特性 ,采用霍尔测试仪测量了薄膜的载流子浓度和霍尔迁移率。结果表明 :沉积薄膜时的基体温度对薄膜的结构、结晶状况、可见光透射率以及导电性有较大的影响。当基体温度为 2 5 0℃ ,Ar分压为 0 8Pa时 ,薄膜的最低电阻率为 4 6× 10 -4Ω·cm ,方块电阻为 35Ω时 ,可见光 (λ =5 5 0nm)透射率高达 92 0 %。     

Thermal solution of Kashpir shale in pressurized benzene under supercritical conditions

The results of the thermal solution of oil shale in benzene in a flow unit under supercritical conditions are reported. It was found that the conversion of shale organic matter into liquid products increased by a factor of 2.5 with an increase in the solvent pressure from 5 to 15 MPa.     

Model of the magmatic thermolysis of coal matter deep in the earth (short communication)

A model of contact thermolysis was constructed based on a combined set of equations for heat transfer from a magmatic intrusion to a coal bed and the kinetics of thermal coal conversion. This model was illustrated by the generation of petroleum hydrocarbons deep in the earth by the thermolysis of the sapropelic matter of boghead.     

Kinetics of concentrating and ultrapurifying dichlorosilane by batch distillation with periodical withdrawals

The results of theoretical and experimental studies for the kinetics of separating dichlorosilane from a mixture of volatile chlorosilanes and ultrapurifying the dichlorosilane concentrate by batch distillation are reported. A mathematical model of the process is proposed. It is shown that the model and computational algorithm adequately describe both processes. The obtained experimental and theoretical data made it possible to design a concentration and ultrapurification process with a maximal productivity at a specified product purity.     

Properties of impregnants from shale phenols

Impregnants prepared from shale phenols for cellular materials had a cohesive strength of 2.4–18.5 J/m² and a specific elongation of 160–170%. The adhesive strength toward a metal was 3.5–6.0 J/m²; in the case of concrete, it was greater than the concrete strength.     

Corundum concretes based on modified phosphate-containing binders

Physicotechnical properties are provided for concretes based on mechanically-activated phosphate suspensions previously modified with magnesium and aluminum hydroxides and silicic acid. The results obtained demonstrate the efficiency of using modifying additions in order to increase the strength and heat resistance of corundum concretes. Translated from Novye Ogneupory, No. 5, pp. 32–35, May 2008.     

Investigation of the structure and properties of modified Armenian minerals for polymer-based composites

The results of investigation of the modification of the Armenian minerals with fluorine-containing oligomers show that a modified product appears when the mineral fillers are treated with fluoroalkanes. The product preserves the structure of the fillers with a “grafted” fluoroalkane layer in which chlorine atoms locate mainly over their periphery. The composite materials based on heterochained polymers and the modified fillers possess a stronger wear resistance and a low friction coefficient.     

Rehabilitation of the radioactively contaminated objects and territory of the Russian Science Center Kurchatov Institute

This article is devoted to work done in 2002–2006 as part of the unified project Reabilitatsiya to rehabilitate radiation hazardous objects and sections of the radioactively contaminated territory of the Russian Science Center Kurchatov Institute. The main objects of the rehabilitation work were old storage sites built for radioactive wastes on the territory of the Institute when military and civilian nuclear technologies were under development. The structural features of the storage sites, including the volumes and characteristics of the wastes stored, are presented. The salient aspects of the disposal sites, taken into account during the rehabilitation work, are discussed. The organization of the rehabilitation operations and the sequence in which they are performed, the special features of the technical design solutions used, the technological methods, and ways for conducting the work are described. __________ Translated from Atomnaya énergiya, Vol. 102, No. 5, pp. 300–306, May, 2007.     

油气田在用燃气轮机系统的热力学分析及改进建议

目前油气田在用的燃气轮机系统实际运行指标（热效率及火用效率）与设计数值相差很大，使燃气轮机系统的性能未能得到充分发挥，达不到预期的经济效益，限制了燃气轮机在油气田的进一步推广。为此，对油气田在用燃气轮机的运行特性进行分析，其主要问题是余热锅炉运行时间短、负荷率低。根据燃气轮机热电联产系统特点，给出了热力学分析（能量平衡分析和火用分析）方法、评价准则及计算公式。利用实测运行参数，对一油气田在用燃气轮机系统进行了运行工况下的热力学分析。测算分析结果表明，该系统运行效率偏离设计值较远，运行效率较低。在各子系统的能量损失分布中，余热锅炉能损系数最大；火用损分布中，燃烧室火用损系数最大，其次为余热锅炉，表明燃气轮机的燃烧室和余热锅炉为系统能量利用的薄弱环节，为重点改造对象。建议扩大集中供热范围、采用余热发电和循环蒸气回注等提高运行效率的措施。