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991.
992.
Hai‐Xia Yang Yan‐Feng Li Jin‐Gang Liu Shi‐Yong Yang Da‐Xue Yin Lincheng Zhou Lin Fan 《应用聚合物科学杂志》2004,91(6):3981-3990
A series of new polymerized monomer reactants (PMR) matrix resins of poly(pyrrolone‐benzimidazole)s containing a pyridine unit (PPBP) were synthesized by polycondensation of monoethyl ester of cis‐5‐norbornene‐endo‐2,3‐dicarboxylic acid, 2,6‐diphenyl ester pyridinedicarboxylic acid or 3,5‐diphenyl ester pyridinedicarboxylic acid, and diethyl ester of 4,4′‐oxydiphthalic acid with 3,3′‐diaminobenzidine in a mixing solution of anhydrous ethyl alcohol and N‐methylpyrrolidone under given temperature and pressure conditions. The resulting resin solutions showed good solubility in polar organic solvents and stability at room temperature. The corresponding PPBP matrix resin, molded powder, and molded plate were prepared by undergoing amidation, imidization, cyclization, and crosslinking reactions when the reaction temperature was increased from 80 to 350°C, successively; the crosslinking structure was formed by the reverse Diels–Alder reaction at 270–290°C under 50 MPa pressure (2.5–3.5 MPa displayed by the pressure meter). The chemical reactions and properties of the resulting PPBP were studied by means of FTIR, TGA, and DMA methods, and the results indicated that the kinds of PPBP materials retain excellent thermal stability and processability; when the initial decomposition temperature was above 620°C the Tg was at 413.5°C for 3,5‐PPBP‐20 molded plate. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 3981–3990, 2004 相似文献
993.
Jung Joon Lee Heeyeon Kim Jae Hyun Koh Ara Jo Sang Heup Moon 《Applied catalysis. B, Environmental》2005,61(3-4):274-280
The performance of a new type of CoMoS/Al2O3 catalyst, with added fluorine and prepared by sonochemical and chemical vapor deposition (CVD) methods, was investigated in the hydrodesulfurization (HDS) of dibenzothiophene (DBT) and 4,6-dimethyldibenzothiophene (4,6-DMDBT). The catalyst, which was designed to contain optimum amounts of fluorine and cobalt, exhibited a higher activity, ca. 4.6 times higher activity particularly in the HDS of 4,6-DMDBT, than a fluorine-free catalyst prepared by a conventional impregnation method. The enhanced activity of the new catalyst can be attributed to the cumulative effects of individual factors involved in the catalyst preparation. That is, the use of a sonochemical synthesis led to a high dispersion of small MoS2 crystallites on the alumina, and the addition of the Co species to the catalyst by CVD caused a close interaction between the Co species and the MoS2 crystallites to produce numerous CoMoS species, which are the catalytically active species for HDS. The addition of fluorine increased the amounts of acidic sites in the catalyst, which promoted hydrogenation (HYD) route to a greater extent than the direct desulfurization (DDS) route in DBT HDS and both HYD and DDS routes to similar extents in the case of 4,6-DMDBT HDS. Accordingly, the addition of fluorine led to a greater increase in catalytic activity for 4,6-DMDBT HDS than for DBT HDS. 相似文献
994.
The curing behavior of two kinds of commercial powdered resol phenolic resins was studied by differential scanning calorimetry. Liquid‐state 13C‐NMR spectroscopy was used to aid in understanding the curing behavior by detecting the structure of powdered resins. The reaction mechanism was interpreted with the dependency of activation energy on the degree of conversion. The results indicate that there are differences in the curing mechanism between core and face phenolic resins. The curing process of core resin was faster than that of face resin at the same reaction temperature. The water added in the curing system played an important role of plasticizer or diluent according to different curing stages and water content. In the initial curing stage, water mainly diluted the system and retarded the curing reactions. However, at the higher degrees of conversion, water played the role of plasticizer to decrease the effect of diffusion on the curing reactions to make the curing reactions more complete. The excess water added in the curing system played the role of diluent at almost all stages during the curing process. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1371–1378, 2003 相似文献
995.
基于轨迹频率抑制的轨迹隐私保护方法 总被引:8,自引:0,他引:8
移动终端和定位技术的快速发展带来了轨迹大数据.研究者通过挖掘和分析发布的轨迹数据集,可获得一些有价值的信息.攻击者也可利用所掌握的知识对发布的轨迹数据集进行推理分析,以较高的概率推断出用户的隐私信息.轨迹抑制是一类实现隐私保护的重要方法,然而轨迹抑制的点数越多会造成数据效用越低.因此,在满足用户隐私需求的情况下,如何选择合理的抑制点来提高匿名处理后的数据效用是数据发布中要解决的重要问题.针对以上问题,文中提出两种基于轨迹频率的方案对轨迹数据进行匿名处理.第一种方案是根据情况抑制整条有问题的轨迹数据或向有问题的轨迹数据集中添加假数据;第二种方案是采用特定的轨迹局部抑制法对数据进行抑制处理.实验表明相对于已有方案,在满足同等隐私需求的情况下,文中方案处理后的数据效用提升了近30%. 相似文献
996.
针对智能家居系统架构复杂、开发难度较大等问题,提出了一种基于Android平台嵌入式Web服务器i-Jetty的智能家居系统方案。在ARM硬件平台及Android软件平台上,采用i-Jetty服务器实现了家居环境信息网络远程监控功能。系统以Mini6410开发板为中央控制器、服务器和室内监控平台,采用蓝牙与被控设备进行通信,通过Linux层驱动加载、Android本地服务和Web服务的联合编程,实现对传感器数据的获取、家电控制和信息发布。实验结果证明了方案的可行性和实用性。 相似文献
997.
Poly(vinyl pyrrolidone‐co‐isobutyl styryl polyhedral oligomeric silsesquioxane)s (PVP–POSS) were synthesized by one‐step polymerization and characterized using FTIR, high‐resolution 1H‐NMR, solid‐state 13C‐NMR, 29Si‐NMR, GPC, and DSC. The POSS content can be controlled by varying the POSS feed ratio. The Tg of the PVP–POSS hybrid is influenced by three main factors: (1) a diluent role of the POSS in reducing the self‐association of the PVP; (2) a strong interaction between the POSS siloxane and the PVP carbonyl, and (3) physical aggregation of nanosized POSS. At a relatively low POSS content, the role as diluent dominates, resulting in a decrease in Tg. At a relatively high POSS content, the last two factors dominate and result in Tg increase of the PVP–POSS hybrid. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 2208–2215, 2004 相似文献
998.
Jui‐Ming Yeh Chi‐Lun Chen Tai‐Hung Kuo Wen‐Fen Su Hsi‐Ya Huang Der‐Jang Liaw Hsin‐Yi Lu Chi‐Fong Liu Yuan‐Hsiang Yu 《应用聚合物科学杂志》2004,92(2):1072-1079
A series of polymer–clay nanocomposite (PCN) materials consisting of 1,4‐bis(4‐aminophenoxy)‐2‐tert‐butylbenzene–4,4′‐oxydiphthalic anhydride (BATB–ODPA) polyimide (PI) and layered montmorillonite (MMT) clay were successfully prepared by an in situ polymerization reaction through thermal imidization up to 300°C. The synthesized PCN materials were subsequently characterized by Fourier‐Transform infrared (FTIR) spectroscopy, wide‐angle powder X‐ray diffraction (XRD) and transmission electron microscopy (TEM). The effects of material composition on thermal stability, mechanical strength, molecular permeability and optical clarity of bulk PI and PCN materials in the form of membranes were studied by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA), molecular permeability analysis (GPA) and ultraviolet‐visible (UV/VIS) transmission spectra, respectively. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 1072–1079, 2004 相似文献
999.
Summary An aromatic copolyester with the ordered sequence of terephthalic acid (TA)-p-hydroxybenzoic acid (HB)-2,7-naphthalenediol (ND)-p-hydroxybenzoic acid (HB) was prepared and its properties were compared with those of the corresponding random copolyester having the same overall monomer composition. Thermal and crystallizing properties of the two polymers are quite different. The former exhibits significantly higher glass transition and melting temperatures than the latter. The former's degree of crystallinity also is much higher than the latter's. Both polymers are thermotropic and form nematic melts. 相似文献
1000.
In the knowledge and information society, the value of utilizing ICT technology in companies is being newly interpreted upon the convergence of business and information technology of companies. Accordingly, companies are ensuring corporate competitiveness by improving product productivity and reducing the consumption of human/physical resources through the change of strategic management environment using ICT technology. On the other hand, companies’ core information is being leaked outside of company from the convergence with ICT technology and its scale is increasing each year. Accordingly, the need for improving the level of security according to companies’ informatization level is increasing. However, studies are lacking on the composition of security strategy in suitable forms according to the scale of company and level of retaining resources. Accordingly, this study examined the security advancement steps to verify the present condition of companies’ security and design security strategy from a macroscopic perspective by improving the level of security according to the scale of company and present condition of resources. 相似文献