芳香酮不对称催化氢化反应过程的手性毛细管气相色谱分析

提出了一种跟踪监测芳香酮手性催化氢化反应过程的气相色谱分析新方法。它可以快速准确地测定反应过程芳香酮的转化率、产物芳香醇对映体的过量百分数(e.e.值)及其构型。该法用于一系列芳香酮不对称催化氢化反应催化剂的性能评价,对筛选催化剂和优化反应条件,取得了到良好的效果。     

用木薯液化滤液对木薯粉调浆进行浓醪酒精发酵工艺研究

研究用木薯液化滤液对木薯粉调浆进行浓醪酒精发酵的工艺条件。主要利用α-淀粉酶对木薯浆进行液化、过滤处理,重点考察液化时固液比、保温时间、pH值、酶用量等因素对木薯粉液化得率的影响。再用液化滤液对木薯粉调浆进行浓醪酒精发酵试验,考察发酵醪液在整个发酵过程中物料流动性能及发酵效果。结果表明木薯浆液化的固液比为1∶11,pH值为6.2,在90℃以上保温75min,液化酶用量为15U/g。在此工艺条件下木薯粉液化固形物得率为85.10%。使用不同比例液化液对木薯粉调浆至初始总糖为25.5%(w/v)进行浓醪酒精发酵,发酵醪酒精度均达15.0%vol以上。结论:利用木薯液化滤液对木薯粉调浆进行浓醪酒精发酵,发酵醪在发酵过程的流动性增加50%,能够顺利进行浓醪酒精发酵。     

城市小区天然气钢质埋地管道防腐层检测与修复

对埋地天然气钢质管道防腐层定期进行检测和修复,是管道安全运行的重要保证措施.本文介绍了克拉玛依市南泉小区庭院天然气钢质埋地管道的检测方法、管道外防腐层修复等技术的应用,旨在交流管道腐蚀状况检测与修复技术的实践经验,并对检测仪器的正确使用及庭院埋地管道防腐层的修复提出建议.     

Nonequilibrium Operation of Arsenic Diffused Long-Wavelength Infrared HgCdTe Photodiodes

We demonstrated a device with a unique planar architecture using a novel approach for obtaining low arsenic doping concentrations in long-wavelength (LW) HgCdTe on CdZnTe substrates. HgCdTe materials were grown by molecular beam epitaxy (MBE). We fabricated a p-on-n structure that we term P ⁺/π/N ⁺ where the symbol “π” is to indicate a drastically reduced extrinsic p-type carrier concentration (on the order of mid 10¹⁵ cm⁻³); P ⁺ and N ⁺ denote a higher doping density, as well as a higher energy gap, than the photosensitive base π-region. Fabricated devices indicated that Auger suppression is seen in the P ⁺/π/N ⁺ architecture at temperatures above 130 K and we obtained a saturation current on the order of 3 mA on 250-μm-diameter devices at 300 K with Auger suppression. Data shows that about a 50% reduction in dark current is achieved at 300 K due to Auger suppression. The onset of Auger suppression voltage is 450 mV at 300 K and 100 mV at 130 K. Results indicate that a reduction of the series resistance could reduce this further. A principal challenge was to obtain low p-type doping levels in the π-region. This issue was overcome using a novel deep diffusion process, thereby demonstrating successfully low-doped p-type HgCdTe in MBE-grown material. Near-classical spectral responses were obtained at 250 K and at 100 K with cut-off wavelengths of 7.4 μm and 10.4 μm, respectively. At 100 K, the measured non-antireflection-coated quantum efficiency was 0.57 at 0.1 V under backside illumination. Received November 7, 2007; accepted March 19, 2008     

Identification of dynamic stiffness and damping in active magnetic bearings using transfer functions of electrical control system

The dynamic rotor behavior is significantly affected by the stiffness and damping characteristics of the bearings. Therefore, it is important to identify these bearing parameters. For active magnetic bearings (AMBs), these bearing parameters not only could be identified from rotor dynamic response, but also from electrical control system transfer function. Some identification works from rotor dynamic response have been reported, but identification from electrical control system transfer function is relatively few. In this paper, we deduced the equivalent stiffness and damping expressions with electrical control system transfer function for rotor AMBs and identified these values from electrical control system model. To evaluate the identified results, previous reported results from rotor dynamic response is employed for comparison. We found that for the stiffness, a complete and precise electrical control model will obtain relatively consistent values; however, for the damping, the accurate electrical control model is still not enough and the eddy current loss should be included.

     

基于历史数据聚类的火电机组工况划分

针对调峰背景下火电机组非稳态工况增多,以及常见运行工况偏离设计工况等问题,提出了基于历史运行数据聚类的工况划分模型。首先,考虑到运行数据中非稳态工况与稳态工况并存的情况,以功率作为特征变量,提出基于功率差值期望区间估计的稳态判别算法,筛选出历史数据中的非稳态工况;其次,由于稳态工况下外部边界条件变量的分布差异性,提出改进的多步K-均值聚类算法进行稳态工况的划分,并利用silhouette评价准则确定每步条件下的最佳聚类数;最后,采用某实际发电用重型燃气轮机的历史运行数据进行模型验证。通过与传统K-均值聚类算法比较,所提出的模型能够有效解决工况分类数目较少以及样本分布不均的问题。     

优化GD-模糊规则的滑坡预报模型研究

为了提高滑坡灾害预报准确率，改善传统的滑坡监测和预报中存在的参数选取困难及模糊控制系统作为预报模型精确度不高的问题，首先采用山体结构稳定性分析法进行滑坡灾害参数的选取，得出降雨量、含水率、土压力及岩土表面位移增量作为预报参数的结论；其次将选取的参数作为模糊系统的输入，建立滑坡灾害发生概率模型，并引入优化的GD算法修正预报模型中的动态参数，使模糊控制模型具有自适应性；同时与未优化的模糊控制模型以及单独模糊控制模型进行仿真对比，仿真结果表明，该控制算法收敛速度快，具有很好的收敛性；最后将该模型在某滑坡重点灾区实验区进行实验测试，实验结果显示该模型具有较好的收敛性，且预报精度达到90%。     

Achieving Highly Efficient Nonfullerene Organic Solar Cells with Improved Intermolecular Interaction and Open‐Circuit Voltage

A new acceptor–donor–acceptor‐structured nonfullerene acceptor ITCC (3,9‐bis(4‐(1,1‐dicyanomethylene)‐3‐methylene‐2‐oxo‐cyclopenta[b]thiophen)‐5,5,11,11‐tetrakis(4‐hexylphenyl)‐dithieno[2,3‐d′:2,3‐d′]‐s‐indaceno[1,2‐b:5,6‐b′]‐dithiophene) is designed and synthesized via simple end‐group modification. ITCC shows improved electron‐transport properties and a high‐lying lowest unoccupied molecular orbital level. A power conversion efficiency of 11.4% with an impressive V _OC of over 1 V is recorded in photovoltaic devices, suggesting that ITCC has great potential for applications in tandem organic solar cells.     

基于熵权和模糊物元的改进多元过程能力分析

为解决多品种小批量产品数据采集困难及各指标间存在交互影响致使传统方法难以奏效的现状,基于主成分分析法的多元过程能力指数会造成信息量缺损。该方法将工序能力影响因素采用模糊物元方法构造工序相似条件,选出相似工序将小批量问题变成大批量处理,应用公差系数法将原始数据转化为相对数据。提出基于熵权理论和模糊物元的改良多元过程能力指数。该论文结合某产品进行实例分析,验证了该方法的实用性和有效性。     

Rational Tuning of Molecular Interaction and Energy Level Alignment Enables High‐Performance Organic Photovoltaics

The performance of organic photovoltaics (OPVs) has rapidly improved over the past years. Recent work in material design has primarily focused on developing near‐infrared nonfullerene acceptors with broadening absorption that pair with commercialized donor polymers; in the meanwhile, the influence of the morphology of the blend film and the energy level alignment on the efficiency of charge separation needs to be synthetically considered. Herein, the selection rule of the donor/acceptor blend is demonstrated by rationally considering the molecular interaction and energy level alignment, and highly efficient OPV devices using both‐fluorinated or both‐nonfluorinated donor/acceptor blends are realized. With the enlarged absorption, ideal morphology, and efficient charge transfer, the devices based on the PBDB‐T‐F/Y1‐4F blend and PBDB‐T‐F/Y6 exhibit champion power conversion efficiencies as high as 14.8% and 15.9%, respectively.