Study on esterification of acrylic phenolic resin by maleic anhydride and photocrosslinking properties of the alkali‐soluble product

An alkali‐soluble, photocrosslinkable polymer was synthesized by esterification of OH groups of acrylic phenolic resin with maleic anhydride. The OH groups were formed by the ring‐opening reaction of epoxy groups of epoxy phenolic resin with acrylic acid. The esterification conditions were studied. The results showed that it is better to use tetramethyl ammonium bromide as catalyst than N,N‐dimethylbenzylamine. The conversion of maleic anhydride in acetone can reach about 80% at 56°C for 4 h. The purified product was characterized by IR, DSC, and TGA. The product containing acrylate and maleic acid monoester groups, above a certain content, can be dissolved in 1% Na₂CO₃ solution. The photocrosslinkable properties of the product were investigated through selection of photoinitiator, accelarator, crosslinkable diluent monomer, etc. The acrylate and maleic acid monoester group‐containing phenolic resin exhibited very good photocrosslinking behavior, since it contains double bonds from both acrylate groups and maleic acid monoester groups. The activity of photoinitiator decreases in the order: isopropylthioanthraquinone > benzoin ethyl ether (BE) > anthraquinone (AQ) > benzophenone > Michel ketone (MK) > 2,2‐diethoxyacetophenone. The combination of some photoinitiators showed synergistic effects. The order of increasing activity for the accelerator is as follows: MK > ethyl p‐(dimethylamino)benzoate > N,N‐dimethylaniline > triethanolamine. The optimum diluent monomer is trimethylolpropane trimethacrylate. The gel content of the mixture of the resin and trimethylolpropane trimethacrylate could reach 85% using the combined photoinitiators of BE and AQ under UV exposure for 120 s. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 1607–1614, 2005     

提高φ5m×11.5m生料磨产量的措施

针对粘土资源枯竭问题,江苏巨龙水泥集团实施了以粉煤灰和硅石代替粘土的技改工程。但改造后因原料的变更,导致入房物料易磨性变差而影响了φ5m×11.5m生料磨的产质量,并进一步影响察系统的运行。因此该厂在工艺分析的基础上,采取了调整钢球级配、用高铬球替代合金刚球、改造选粉机、加强石灰石二破的管理和减少系统是否是“漏风”等技术措施,效果显著。改造后的生料磨台时产量比调整前提高了12t/h,且节电效果显著。     

Surface Modification of Titania Nanoparticles Using Ultrathin Ceramic Films

Surface modification of titania nanoparticles was achieved by coating them with ultrathin alumina films using atomic layer deposition. The coating process was performed in a fluidized bed reactor at low pressure and under mechanical vibration. Films were deposited using self-limiting, sequential surface reactions of trimethylaluminum and water. The composition of alumina-coated particles was verified using infrared spectroscopy. The deposited films had an average growth rate of 0.2 nm/coating cycle and were highly uniform and conformal as demonstrated by transmission electron microscopy and X-ray spectroscopy. Deposited alumina films were amorphous as verified through X-ray diffraction and high-resolution electron microscopy. The coating process did not promote particle sintering as validated via particle size and surface area analysis.     

Preparation and properties of T300 carbon fiber‐reinforced thermoplastic polyimide composites

In this study, a series of T300 carbon fiber‐reinforced polyimide (CFRPI) composites were prepared by laminating premolding polyimide (PI) films with unidirectional carbon fiber (CF) layers. On the basis of PI systems design, the effect of CF volume fraction, processing conditions, and PI molecular structure on the properties of CFRPI composites was studied in detail. In addition, two kinds of nano‐particles, including carbon nano‐tube (CNT) and SiO₂ were filled into the premolding PI films with different concentrations. And the effect of nano‐particles on the properties of CFRPI composites was also investigated. The surface characteristic of T300 CF was measured by X‐ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR). The properties of premolding PI film and CFRPI composites were measured by dynamic mechanical analysis (DMTA), SANS testing machine, scanning electron microscopy (SEM), and so forth. These experimental results showed that the properties of CFRPI composites were mainly affected by the premolding PI film and molding condition. The change of CF volume fraction from 55% to 65% took little effect on the mechanical properties of CFRPI composites. In addition, the incorporation of nano‐particle SiO₂ could further improve the properties of CFRPI composites, but CNT hardly improved the properties of CFRPI composites. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 646–654, 2006     

千年前的求爱诗：震旦之恋·扶桑之情——《关雎》与《天皇御制歌》之比较研究

从主题、内容、形式结构、语言特色、视点、表现手法、诗歌风格等方面比较<关雎>与<天皇御制歌>的异同,探寻产生其异同的原因以及由此给日本文学发展带来的影响.     

OCDMA系统中变重光正交码的构造及误码率分析

变重光正交码是基于不同用户带有不同的QoS(Quality of Service)需求而提出的,由于它的码重不是固定值,使得其码字的容量较之常重光正交码有所增加.给出了变重光正交码的定义及其码字容量界,介绍了构造变重光正交码的一种方法,给出一些码字的构造结果,并对码重数不同的码字进行多址干扰误码率的仿真比较和理论分析.结果表明:在相同的码重数下,码重越大的误码率越小;而当码重数不同时,在相同的码重下,码重数大的误码率小.     

无线射频识别技术（RFID）及其在物联网中的应用

随着物联网知识的普及,以及其技术的广泛推广应用,物联网被越来越多的人所关注。本文介绍了物联网及其关键技术RFID,并结合RFID在物联网的实际应用,并对其未来的发展作出了展望。     

化学教学与思想教育的融汇

本文阐述了在化学教学中要进行辩证唯物主义和爱国主义教育,要关注社会问题,要融汇政治思想教育。思想教育融汇在化学教学环节中首先要求我们对学生进行科学素养的培养;思想教育融汇在化学教学环节中要求我们的教学要与工农业生产相结合;思想教育融汇在化学教学环节中还要求我们的教学要与思想道德教育相结合,要与法制教育相结合;思想教育融汇在化学教学环节中还要求我们的教学要与现代教育技术相结合。     

A recognition method of vibration parameter image based on improved immune negative selection algorithm for rotating machinery

To overcome the limitations of traditional monitoring methods, based on vibration parameter image of rotating machinery, this paper presents an abnormality online monitoring method suitable for rotating machinery using the negative selection mechanism of biology immune system. This method uses techniques of biology clone and learning mechanism to improve the negative selection algorithm to generate detectors possessing different monitoring radius, covers the abnormality space effectively, and avoids such problems as the low efficiency of generating detectors, etc. The result of an example applying the presented monitoring method shows that this method can solve the difficulty of obtaining fault samples preferably and extract the turbine state character effectively, it also can detect abnormality by causing various fault of the turbine and obtain the degree of abnormality accurately. The exact monitoring precision of abnormality indicates that this method is feasible and has better on-line quality, accuracy and robustness.     

教师直接纠错与标识纠错对学生英文写作准确性的影响

本文分析了2004年以来国内有关于纠错对英语学习者写作准确性影响的相关研究,并对研究结果进行定性分析。分析发现,在纠正学生的写作错误时,采取教师直接纠错和标识错误处的纠错策略对学生英文写作的准确性有益,写作教师可以根据不同的错误类型灵活地选择不同的纠错方式以达到最好的效果。