添加物对Fe_2O_3超微粒的稳定作用

粒子的尺寸直接关系着气敏元件性能的好坏．为了防止Ｆｅ２Ｏ３超微粒在气敏元件烧结过程中长大，我们在纯Ｆｅ２Ｏ３中掺入５ｍｏｌ％碱土金属离子，利用ＸＲＤ和ＴＥＭ系统研究了掺杂物对Ｆｅ２Ｏ３超微粒子的稳定作用，并对由掺杂引起的Ｆｅ２Ｏ３电学性质的变化作了初步探讨．     

超高效液相色谱串联质谱法测定牛奶中三氮脒残留

目的 本研究旨在结合超高效液相色谱－串联质谱(ultra performance liquid chromatography-tandem mass spectrometry, UPLC-MS/MS)技术,建立简便、快速的样品前处理方法,对牛奶中的痕量三氮脒残留进行检测。方法 用1%乙酸乙腈溶液振荡提取后,在-4℃条件下高速离心,取上清液旋转蒸干后,用10%乙腈水溶液复溶,用超高效液相色谱-串联质谱仪在正离子扫描及多反应监测(multiple reaction monitoring, MRM)模式下分析,外标法定量。结果 牛奶中三氮脒的检出限(limit of detection, LOD)为5 μg/kg,定量限(limit of quantification, LOQ)为15 μg/kg,在20~1000 μg/L浓度范围内线性良好,相关系数(r)为0.9993。将所研究的方法应用于实际牛奶样本中,其加标回收率在81.65%至85.49%之间,日内精密度分别在4.5%~5.5%,日间精密度在5.9%~8.2%之间。结论 本方法采用振荡提取加低温高速离心净化的前处理方法,简单快速,结合UPLC-MS/MS,可实现痕量水平残留的高灵敏度检测,适用于快速、高灵敏检测牛奶及其他动物源性食品中的三氮脒残留。     

正切型弹性体材料的缓冲包装设计

提出一种利用正切型弹性体材料的力学数据进行缓冲包装结构设计的方法,对这种方法的原理进行详细的理论推导,得出计算缓冲垫结构尺寸的关系式。该关系式简单实用,设计出的缓冲衬垫具有最佳的理论缓冲效率。     

良分布的多特征遥感图像自动配准算法

针对基于点特征的遥感图像自动配准算法中存在特征点分布不均匀的问题,提出了一种基于SIFT(尺度不变特征变换)、Harris-Laplace(多尺度角点)、MSER(最大稳定极值区域)特征提取算法的多特征遥感影像配准方法。通过多特征与二次匹配,极大的提高了匹配点数目;通过基于距离的筛选,保证匹配点分布均匀合理;通过局部互信息精校正,使匹配点精度更高,最终达到高质量(空间分布均衡,匹配精度高)自动配准目的。     

金属氧化物和分子筛在CO2环加成中的研究进展

二氧化碳（CO2）是主要的温室气体,同时也是一种廉价、无毒且可再生的一碳资源,因此将CO2转化为有价值的精细化学品可有效减缓气候变化、助力实现碳中和。CO2与环氧化物的环加成反应具有高原子经济、高选择性、低污染等优点,其产物环状碳酸酯可作为锂离子电池电解质、聚合物材料前体以及精细化学品中间体,应用前景广阔。氧化物因具有结构多样、可调性强等优点在CO2与环氧化物的环加成反应中的应用引起了广泛的关注。文章综述了两种典型且成本低廉、易于规模化生产的氧化物——金属氧化物与分子筛催化CO2与环氧化物的环加成反应的研究进展,重点分析了反应机理以及催化剂的应用。今后的研究重点是高性能无助剂的非均相催化剂的开发以及催化机理的探究。     

Micro-Service-Based Radio Access Network

The convergence of information, communication, and data technologies(ICDT) has been identified as one of the developing trends of the sixth generation(6G) network. Service-based architecture(SBA) as one of the promising information technology, has been preliminarily introduced into the fifth generation(5G) core network(CN) and successfully commercialized, which verifies its feasibility and effectiveness. However, SBA mainly focuses on the control plane of CN at present and the SBA-CN user plane ...     

考虑局部磁滞损耗的复合电机铁损耗计算

磁性齿轮复合电机无论是机械结构还是磁路结构,均比普通永磁同步电机复杂,如何高效准确地计算出铁损耗,对该类电机的设计与优化具有重要的意义。该文设计制造了一台磁性齿轮复合电机样机,并采用有限元时步法进行了详细计算。在此基础上,通过对每一个铁心单元的磁密变化进行分析,计算了该复合电机的铁损耗计算。在计算磁滞损耗时,应用通常用于机械应力应变迟滞计算的雨流计数法,快速统计出构成局部磁滞回环的峰谷点,从而计算出局部磁滞损耗。最后通过两个试验步骤,把电机的铁损耗从空载损耗中分离出来,所得的试验结果验证了所述方法的有效性。     

Carbon Metabolism of a Soilborne Mn(II)-Oxidizing Escherichia coli Isolate Implicated as a Pronounced Modulator of Bacterial Mn Oxidation

Mn(II)-oxidizing microorganisms are generally considered the primary driving forces in the biological formation of Mn oxides. However, the mechanistic elucidation of the actuation and regulation of Mn oxidation in soilborne bacteria remains elusive. Here, we performed joint multiple gene-knockout analyses and comparative morphological and physiological determinations to characterize the influence of carbon metabolism on the Mn oxide deposit amount (MnODA) and the Mn oxide formation of a soilborne bacterium, Escherichia coli MB266. Different carbon source substances exhibited significantly varied effects on the MnODA of MB266. A total of 16 carbon metabolism-related genes with significant variant expression levels under Mn supplementation conditions were knocked out in the MB266 genome accordingly, but only little effect on the MnODA of each mutant strain was accounted for. However, a simultaneous four-gene-knockout mutant (namely, MB801) showed an overall remarkable MnODA reduction and an initially delayed Mn oxide formation compared with the wild-type MB266. The assays using scanning/transmission electron microscopy verified that MB801 exhibited not only a delayed Mn-oxide aggregate processing, but also relatively smaller microspherical agglomerations, and presented flocculent deposit Mn oxides compared with normal fibrous and crystalline Mn oxides formed by MB266. Moreover, the Mn oxide aggregate formation was highly related to the intracellular ROS level. Thus, this study demonstrates that carbon metabolism acts as a pronounced modulator of MnODA in MB266, which will provide new insights into the occurrence of Mn oxidation and Mn oxide formation by soilborne bacteria in habitats where Mn(II) naturally occurs.     

Chemical Coupled PEDOT:PSS/Si Electrode: Suppressed Electrolyte Consumption Enables Long‑Term Stability

Huge volume changes of Si during lithiation/delithiation lead to regeneration of solid-electrolyte interphase(SEI)and consume electrolyte.In this article,γ-glycidoxypropyl trimethoxysilane(GOPS)was incorporated in Si/PEDOT:PSS electrodes to construct a flexible and conductive artificial SEI,effectively suppressing the consumption of electrolyte.The optimized electrode can maintain 1000 mAh g^−1 for nearly 800 cycles under limited electrolyte compared with 40 cycles of the electrodes without GOPS.Also,the optimized electrode exhibits excellent rate capability.The use of GOPS greatly improves the interface compatibility between Si and PEDOT:PSS.XPS Ar+etching depth analysis proved that the addition of GOPS is conducive to forming a more stable SEI.A full battery assembled with NCM 523 cathode delivers a high energy density of 520 Wh kg^−1,offering good stability.