Enhanced Hydrolysis of Cellulose to Reducing Sugars on Kaolinte Clay Activated by Mineral Acid

Catalysis Letters - Kaolinite, a natural, layered phyllosilicate, has been used as the solid catalyst for the hydrolysis of cellulose in our previous work. In the present study, kaolinite was...     

Efficient cycloaddition of CO2 and epoxides to cyclic carbonates using salen-based covalent organic framework as a heterogeneous catalyst

Journal of Porous Materials - Salen-based covalent organic framework (COF), constructed by salen skeleton, has great potential applications as the heterogeneous catalyst due to its unique...     

UPLC-MS/MS法测定美洛昔康中两个中间体杂质

建立UPLC-MS/MS法测定美洛昔康中杂质A和杂质B.采用ACQUITY UPLC?HSS T3 C18(2.1 mm×100 mm,1.8μm)色谱柱,流动相为0.1％甲酸水溶液-甲醇(45:55).采用电喷雾离子源(ESI),多反应监测(MRM)模式,正离子扫描;脱溶剂温度:500℃;干燥气流速:15 L/min...     

季铵盐缓蚀剂在高温高压电化学环境下缓蚀行为研究

在油气田的开发和运营中,设备和管道面临着严苛的腐蚀环境,绝大多数研究只针对缓蚀剂在常温常压的缓蚀行为,而对于高温高压环境下这种实际应用环境的缓蚀剂开发和研究较少.基于以上问题,选用并制备两种季铵盐缓蚀剂,使用电化学高温高压釜模拟油气田环境,通过电化学方法以及SEM和EDS表征,研究了N80钢在模拟油气田环境下的电化学行...     

TS法的改进及其在求解化工优化问题中的应用

TS算法属于现代优化算法,是局部领域搜索法的推广,常用于求解组合优化问题.利用TS法搜索过程的有向性和能够跳离局部最优解的特点,对其进行了改造,以适应求解连续变量化工优化问题.首先,根据化工优化问题变量的特性,提出了一种简便的邻域映射方案,并改进了迭代过程中自适应因子的下降函数;进一步分析对比了禁忌步数、自适应因子和初始解等参数对于优化结果的影响.然后通过算例和换热网络优化问题的求解,表明改造后的TS法在求解连续变量化工优化问题中的有效性,及其在化工优化领域的发展价值.     

碱渣脱除锌冶炼烟气中SO2的工艺

利用水合肼生产过程中副产的碱渣(含Na2CO3.10 H2O)吸收锌冶炼烟气,得到结晶亚硫酸钠。重点考察了尾气中SO3含量、碱液比重、中和液pH值对脱SO2工艺、效率和产品的影响。     

Isothermal crystallization kinetics and melting behavior of multiwalled carbon nanotubes/polyamide‐6 composites

Pristine and functionalized multiwalled carbon nanotubes (MWNTs) were used to fabricate polyamide 6 (PA6) composites through melt blending. The functionalized MWNTs were obtained by grafting 1,6‐hexamethylenediamine (HMD) onto the pristine MWNTs to improve their compatibility with PA6 matrix. The effect of MWNTs on the isothermal crystallization and melting behavior of PA6 was investigated by differential scanning calorimetry (DSC) and X‐ray diffraction (XRD). The Avrami and Lauritzen–Hoffmann equations are used to describe the isothermal crystallization kinetics. The values of the Avrami exponent found for neat PA6, the pristine MWNTs/PA6 and functionalized MWNTs/PA6 composite samples are about 4.0, 1.7, and 2.3, respectively. The activation energies are determined by the Arrhenius method, which is lower for the composites, ?320.52 KJ/mol for pristine MWNTs/PA6 and ?293.83 KJ/mol for functionalized MWNTs/PA6, than that for the neat PA6 (?284.71 KJ/mol). The following melting behavior reveals that all the isothermally crystallized samples exhibit triple melting endotherms at lower crystallization temperature and double melting endotherms at higher crystallization temperature. The multiple melting endotherms are mainly caused by the recrystallization of PA6 during heating. The resulting equilibrium melting temperature is lower for the composites than for neat PA6. In addition, polarizing microscopy (PLM) and small angle light scanning (SALS) were used to study the spherulite morphology. The results show that the MWNTs reduce the spherulite radius of PA6. This reduction is more significant for pristine MWNTs. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

多目的间歇过程短期排程的柔性研究

本文建立了一个多目的间歇过程短期排程柔性的模型，并开发了一个实用的计算程序求解此ＭＩＮＬＰ模型。通过例证研究说明，应用此模型进行短期排程可实现快速有效的间歇化工厂生产管理。