碘仿电解合成的工艺研究

开发了一种以石墨为阳极、铅为阴极、采用旋转阳极和离子膜分隔电解槽的碘仿电解合成的先进工艺 ,经过 5因素 4水平的正交试验 ,发现影响电流效率的各工艺因素中 ,阳极电流密度的影响最大 ,其次分别为阳极液温度 ,阳极液 p H值 ,阳极液中碘化钾的浓度和阳极转速。优化得到碘仿电合成的最佳工艺条件为 :碘化钾浓度 2 0 0 g· L- 1 ,阳极电流密度 2 5 A· dm- 2 ,阳极液温度为 2 0℃ ,阳极液 p H值为 9.5,阳极转速为2 0 0 r· min- 1 ,在此最佳工艺条件下 ,电流效率可达 97.2 3%。     

Water Bloom Precursor Analysis Based on Two Direction S-Rough Set

In the field of water quality management, it is vital to determine the main precursory anomalies from the precursor of intricate water bloom in the context of a given area. In this paper, a water bloom precursor analysis method, based on two direction singular rough set, was proposed. This approach was produced on the basis of the different sections and pre-water bloom of water bloom precursor anomalies and characteristic of elements transferred in singular rough set. For testing the validity of two direction singular rough set application in water bloom precursor analysis, Xiangxi River, which is one of the typical tributaries of Three Gorges Reservoir in China, was selected as study area. The result showed that compared with other indexes, pH and dissolved oxygen (DO) are the most valuable indicators of water bloom in the precursory anomalies. Furthermore, regarding with water bloom precursory anomalies in Xiangxi River, most of the nutrient loading and biological community are the key indicators. Hence, this method can determine the main precursory anomaly for water bloom in the study area, which provides powerful knowledge support to water quality specialists for them to comprehensively analyze precursory anomaly so as to find out its relationship with occurrence law of water bloom.     

载锰氮化碳催化臭氧法降解水中草酸研究

草酸是废水中多种有机物氧化降解的中间产物,与臭氧反应速率很低,难以直接氧化去除。本研究通过热解法煅烧不同摩尔比例的三聚氰胺与醋酸锰(Ⅲ)二水合物,制备出不同负载量的载锰氮化碳催化剂,并研究了不同条件下载锰氮化碳催化臭氧法对草酸的降解效果,考察三聚氰胺与醋酸锰摩尔比、催化剂投加量、p H值、臭氧浓度等因素以及叔丁醇对草酸去除效果的影响。实验结果表明:相对于单独臭氧氧化而言,载锰氮化碳催化臭氧法可以极大的提高草酸的去除率,在投加0.15 g/L三聚氰胺与醋酸锰20∶1的催化剂后,草酸在60 min的TOC去除率可达到89.1%。叔丁醇加入对草酸的去除率影响较小,表明·OH在载锰氮化碳催化氧化草酸的过程中起作用但不是唯一因素。     

药用中间体苯丙酮含量的气相色谱/质谱分析

苯丙酮是合成利胆药苯丙醇的重要中间体。本文建立了用气相色谱 /质谱法 (GC/MS)测定苯丙酮含量的方法。组分的定性依靠GC/MS联用技术和NIST谱库标准质谱图对照分析。以苯乙酮为内标 ,苯丙酮含量在 1.0× 10 -5～ 2 .0× 10 -4g/mL范围内呈线性 ,线性相关系数r =0 .994 9,苯丙酮最低检测浓度为 1.0× 10 -8g/mL。该法操作简便、快速 ,结果准确可靠 ,且具有很好的实用价值     

支持多种手机客户端的校园信息发布系统

针对数字化校园建设中存在的信息孤岛问题,设计开发了基于客户服务架构的能支持多种手机客户端的校园信息发布系统。分析了系统功能,描述了系统拓扑结构和软件架构,对数据交换接口、网页和手机客户端信息提醒等关键技术进行了探讨。试用结果表明系统运行良好,达到了设计目的。     

高斯型模糊润饰图像的模糊核反演算法

为了从模糊润饰图像恢复模糊核,基于对数傅里叶空间图像高斯型模糊润饰前、后的指数黎曼度量具有等距性特点,提出一种高斯型模糊润饰图像的模糊核反演算法.首先将模糊润饰前、后的图像转换到对数傅里叶空间;然后利用黎曼测地距离度量图像高斯型模糊润饰前、后的模糊不变量,从模糊不变量携带的信息中反演恢复出高斯型模糊核.在对高斯模糊、中值模糊、盒式模糊和多步高斯模糊润饰图像进行的实验结果表明,文中算法能够鲁棒地恢复出模糊核.     

High-g impact resistance for epoxy molding compound

The behavior of resistance high-g impact of EMC (epoxy molding compound) with two package models, small outline package (POS) and Globtop, was evaluated by experimental method used Hopkinson bar. At 120,000 g (generated in the Hopkinson bar with widths about 70 μ s) no damage in either the POS devices or the Globtop devices was observed. In order to enhance the EMC’s ability of resistance high-g impact, buffering effect of epoxy resin was also studied. The experimental results above all show that EMC has a better performance of impact resistance at about 120,000 g, and epoxy resin can absorb the stress wave to have the protected ability. The study of this paper could serve as a basis for selection packaging materials and enhance its reliability in high-g impact environment.     

光照变化条件下的光流估计

目的 为了提高光流法在处理光照变化和大位移方面的稳健性。提出一种结合结构纹理分解预处理和加权中值滤波的光流场模型。方法 该方法数据项采用灰度守恒假设和梯度守恒假设相结合、局部约束与全局约束相结合的思想。同时采用结构纹理分解、加权中值滤波、金字塔结构等高效的光流估计技术,进一步增强了光流算法的精确性与实用性。结果 分别通过Middlebury光流数据库图像和真实场景图像对提出的光流估计算法进行了大量实验验证。实验结果表明,改进的光流估计法在处理光照变化方面表现不错,不仅获得稠密的光流场,而且提高了光流场准确提取目标边缘的能力。结论 和传统光流方法相比,所提方法在光照变化情况下能获得更加理想的结果,降低了实际场景中光线变化的干扰,能更好地适用于实际场景中。     

Full-scaled deep metric learning for pedestrian re-identification

Multimedia Tools and Applications - The pedestrian re-identification problem (i.e., re-id) is essential and pre-requisite in multi-camera video surveillance studies, provided the fact that...     

考虑坝基岩体抗剪强度各向异性的重力坝抗滑稳定分析方法

为研究节理岩体抗剪强度各向异性特征对重力坝抗滑稳定性的影响,利用结构面网络模拟技术,计算节理岩体在主滑动方向上沿不同角度剪切的连通率与相应的抗剪强度参数,对Mohr-Coulomb强度准则进行各向异性修正。在此基础上,结合极限分析法,提出了一种考虑岩体抗剪强度各向异性特征的重力坝抗滑稳定分析方法。将该方法应用于向家坝泄12坝段的深层抗滑稳定分析,并与传统方法的计算结果进行对比。结果表明:该方法与传统方法获得的临界滑裂面位置比较接近,但其抗滑稳定安全系数明显小于传统方法,且临界滑裂面的剪出段倾角与坝基岩体连通率的最大值方向基本一致,和实际情况相符。该方法充分考虑了岩体抗剪强度各向异性的影响,对合理评价重力坝的抗滑稳定性具有重要的工程和现实意义。