Preparation and adsorption behavior of a cellulose‐based,mixed‐mode adsorbent with a benzylamine ligand for expanded bed applications

A novel mixed‐mode expanded bed adsorbent with anion‐exchange properties was explored with benzylamine as the functional ligand. The cellulose composite matrix, densified with stainless steel powder, was prepared with the method of water‐in‐oil suspension thermal regeneration. High activation levels of the cellulose matrix were obtained with allyl bromide because of the relative inertness of the allyl group under the conditions of the activation reaction. After the formation of the bromohydrin with N‐bromosuccinimide and coupling with benzylamine, the activated matrix was derived to function as a mixed‐mode adsorbent containing both hydrophobic and ionic groups. The protein adsorption capacity was investigated with bovine serum albumin as a model protein. The results indicated that the prepared adsorbent could bind bovine serum albumin with a high adsorption capacity, and it showed salt tolerance. Effective desorption was achieved by a pH adjustment across the isoelectric point of the protein. The interactions between the cell and adsorbent were studied, and the bioadhesion was shielded by the adjustment of the salt concentration above 0.1M. Stable fluidization in the expanded bed was obtained even in a 2% (dry weight) yeast suspension. The direct capture of target proteins from a biomass‐containing feedstock without extra dilution steps could be expected with the mixed‐mode adsorbent prepared in this work, and this would be especially appropriate for expanded bed adsorption applications. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

OMA协议下的TS节目DRM解决方案

数字版权保护技术已经成为网络电视中除了视频编码技术以外的又一项核心技术。它用于保护内容所有人的版权,控制客户对于内容的使用。文章在阐述OMADRM标准的基础上,提出了一种适应国内广电系统实际播控环境的TS制式节目的DRM解决方案,并根据自行开发的演示系统,就其加密效率加以论证。     

Preparation and Characterization of Carboxymethyl Chitosan and β-Cyclodextrin Microspheres by Spray Drying

Three kinds of carboxymethyl chitosan/β-cyclodextrin microspheres loaded with theophylline were prepared by spray drying intended for pulmonary delivery. Mucociliotoxicity, permeation rate, and drug release characteristics of the product were investigated. The microspheres obtained by spray drying were found to be spherical with smooth or wrinkled surfaces. The mean particle size was between 3.39 and 6.06 µm. The microspheres demonstrated high product yield (43.7-50.2%), high drug loading (13.7-38.1%), and high encapsulation efficiency (86.9-92.8%). FT-IR indicated that there were interactions of theophylline with carboxymethyl chitosan matrix. Further studies on mucociliotoxicity and permeation confirmed that microspheres had better adaptability and high permeation rate. In vitro drug release from the microspheres was not related to the drug/polymer ratios.     

Hartstoffschichten für das Pressen und Prägen von Gläsern bei hohen Temperaturen

Hard and wear resistant coatings for the moulding and embossing of glasses at elevated temperatures Hard and wear resistant coatings of Titanium Aluminium Nitride TiAlN were deposited on various substrates by the application of different reactive deposition processes: RF-magnetron-sputtering, ion beam-sputtering and by the energetic cluster impact (ECI) process. The deposition of the coatings was performed under variation of biasing conditions and of process parameters such as pressures and flow rates of the process gases argon and nitrogen as well as of energies of species hitting the substrate surfaces. The microstructure particularly the growth morphology of several films was investigated by pictures of film cross sections recorded by transmission electron microscopy. Residual intrinsic film stresses were analyzed by measuring deflections of substrates in an interference optical microscope before and after the deposition of the coatings. By heating coated substrates and in-situ observation of deflections at elevated temperatures dependencies of thermally induced stresses on temperatures and variations of intrinsic stresses due to changes within the films could be analyzed and related to microstructure and growth conditions. In the paper specific characteristics of the deposition processes occuring on the scale both of atoms and of clusters which may contain several thousand of atoms are described and related to microstructure, residual stress states and damaging conditions. Different contributions to residual film stresses are analyzed on the base of theoretical considerations taking into account deposition kinetics and thermomecanical properties. The significance of achieved film properties for application, i. e. for the coating of tools for the manufacturing of optical components by moulding and embossing of glasses is discussed.     

硬质合金与铁基复合材料热等静压扩散连接

以烧结结态硬质合金和粉末态铁基复合材料为连接对象，研究了两种材料的热等静压扩攻连接工艺，获得了直接连接接头和加镍作中间过渡层的间接连接接头，考察了接头的结合界面形貌，界面的元素扩散和界面结合强度。     

稀土萃取信息系统

应稀土化学发展的需要,我们组建了稀土萃取信息系统。其中包括:数据的来源和数据类型;数据的组织;检索功能;数据间的关联;最优化设计以及萃取剂结构与其物理性质和结构与萃取性能的相关分析研究。     

在VB6．0中实现多表综合查询

利用VB6.0Data控件实现了多表任选字段的综合查询,并给出了关键部分的编码,经应用和测试,该方法不仅实用,而且操作方便、反应快捷,较数据库编程简单、灵活。     

矫直状态下钢管弹塑性变形区的研究

根据钢管矫直时的变形规律，通过对矫直中钢管的力学状态及矫直前后的状态参数分析，建立了一种适于现场应用的确定钢管弹、塑性变形区的新方法。     

分偏移距动校正方法的改进

在地震资料处理中，速度分析和动校正对资料品质的影响很大。由于动校正速度是随偏移距变化而变化的，而常规速度分析并没有考虑这一因素，动校正效果往往不是很理想，从而影响资料的叠加和成像效果。分偏移距动校方法是在不同偏移距上采用不同的速度进行动校正。但由于是在不同偏移距组上分别独立进行速度分析和动校正，因此不能将不同偏移距组的同一反射同相轴校正到同一to层位上。这样就需要进行繁琐的后续处理，而且还会降低同相轴的连续性和平滑性。为此，对该方法进行了一些改进，即固定to在不同的分偏移距段进行速度扫描，段与段之间的衔接问题采用平滑处理解决。理论模型分析表明，采取上述改进措施后，动校正效果得到了一定提高，改善了同相轴的连续性和平滑性。     

直馏汽油异构化装置的运行

长庆油田公司第二助剂厂新建的 70kt a直馏汽油异构化装置 ,采用二个反应器 ,以常压直馏汽油为原料 ,采用非临氢重整催化剂 ,生产的异构化汽油的研究法辛烷值约 90 ,但改质汽油收率较低 ,仅 65 %左右