全文获取类型
收费全文 | 969篇 |
免费 | 60篇 |
国内免费 | 2篇 |
专业分类
电工技术 | 34篇 |
综合类 | 1篇 |
化学工业 | 347篇 |
金属工艺 | 26篇 |
机械仪表 | 27篇 |
建筑科学 | 13篇 |
矿业工程 | 1篇 |
能源动力 | 53篇 |
轻工业 | 114篇 |
水利工程 | 2篇 |
石油天然气 | 1篇 |
无线电 | 49篇 |
一般工业技术 | 172篇 |
冶金工业 | 37篇 |
原子能技术 | 52篇 |
自动化技术 | 102篇 |
出版年
2023年 | 27篇 |
2022年 | 51篇 |
2021年 | 70篇 |
2020年 | 37篇 |
2019年 | 39篇 |
2018年 | 54篇 |
2017年 | 40篇 |
2016年 | 53篇 |
2015年 | 44篇 |
2014年 | 35篇 |
2013年 | 79篇 |
2012年 | 69篇 |
2011年 | 82篇 |
2010年 | 49篇 |
2009年 | 46篇 |
2008年 | 54篇 |
2007年 | 40篇 |
2006年 | 20篇 |
2005年 | 22篇 |
2004年 | 16篇 |
2003年 | 15篇 |
2002年 | 10篇 |
2001年 | 3篇 |
2000年 | 5篇 |
1999年 | 4篇 |
1998年 | 16篇 |
1997年 | 7篇 |
1996年 | 8篇 |
1995年 | 1篇 |
1994年 | 4篇 |
1993年 | 6篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 4篇 |
1982年 | 2篇 |
1981年 | 5篇 |
1980年 | 2篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1973年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有1031条查询结果,搜索用时 0 毫秒
51.
Koji Sugano Yuki Uchida Osamu Ichihashi Hideo Yamada Toshiyuki Tsuchiya Osamu Tabata 《Microfluidics and nanofluidics》2010,9(6):1165-1174
Gold nanoparticles with diameters of a few tens of nanometer and a narrow size distribution were synthesized using a pulsed
mixing method with a microfluidic system which consists of a Y-shaped mixing microchannel and two piezoelectric valveless
micropumps. This mixing method enables control of the mixing speed of gold salts and reducing agent by changing the switching
frequency of the micropumps, which was our focus to improve the particle size distribution, which is an essential parameter
in gold nanoparticle synthesis. In the proposed method, the mixing time was inversely proportional to the switching frequency
and the minimum mixing time was 95 ms at a switching frequency of 200 Hz. During synthesis experiments, the mean diameter
of the synthesized gold nanoparticles was found to increase, and the coefficient of variation of particle size was found to
decrease with decreasing mixing time. We successfully improved the coefficient of variation to less than 10% for a mean diameter
of around 40 nm. 相似文献
52.
By applying square wave AC voltage to the Au source electrode of tetracene based field-effect transistor (FET), electroluminescence (EL) was obtained. The results suggest that electrons and holes were injected alternately from the source electrode and recombined each other, and lead to the EL. This type of EL was localized at the interface between the source electrode and tetracene, and enhanced periodically with two relaxation times in accordance with the applied AC voltage cycle. We modeled the carrier behavior in the FET and explained the decay of EL, taking into account the space charge field contribution. Finally, using an AC voltage superposed on DC bias voltage, it was shown that electron injection was prompted only by space charge field. 相似文献
53.
54.
55.
Hisamoto H Shimizu Y Uchiyama K Tokeshi M Kikutani Y Hibara A Kitamori T 《Analytical chemistry》2003,75(2):350-354
Here we report a design and synthesis of a chemically functional polymer membrane by an interfacial polycondensation reaction and multilayer flow inside a microchannel. Single and parallel dual-membrane structures are successfully prepared by using organic/aqueous two-layer flow and organic/aqueous/organic three-layer flow inside the microchannel followed by an interfacial polycondensation reaction. By using the inner-channel membrane, permeation of ammonia species through the inner-channel membrane is successfully achieved. Furthermore, horseradish peroxidase is immobilized on one side of the membrane surface to integrate the chemical transform function onto the inner-channel membrane. Here substrate permeation through the membrane and subsequent chemical transformation at the membrane surface are realized. The polymer membrane prepared inside the microchannel has an important role in ensuring stable contact of different phases such as gas/liquid or liquid/ liquid and the permeation of chemical species through the membrane. Furthermore, membrane surface modification chemistry allows chemical transformation of permeated chemical species. These methods are expected to lead to development of complicated and sophisticated chemical systems involving membrane permeation and chemical reactions. 相似文献
56.
Hiromi?YoshidaEmail author Kyoko?Matsuda Yuki?Hirakawa Yoshiyuki?Mizushina 《Journal of the American Oil Chemists' Society》2003,80(7):665-674
To clarify the effects of microwave roasting on the distribution of tocopherols and FA of phospholipids within soybeans, whole
soybeans (Glycine max) were treated by microwave and further evaluted as compared to a raw sample. Tocopherol homologs, measured using HPLC, and
phospholipid profiles, quantified with GC, were determined in the seed coat, the embryonic axis, and selections of cotyledons
separated from three cultivars. The tocopherols were predominantly detected in the axis, followed by the cotyledons, and then
very little in the coat. As much as 25% of the individual tocopherols originally present in the coat were lost at 12 min of
roasting, whereas <25% was lost in the cotyledons and the axis after 20 min of roasting. The greatest rate of phospholipid
loss (P<0.05) was observed in PE, followed by PC and PI, and their changing patterns were more pronounced in the coat than in the
cotyledons or the axis. Thus, tocopherol content and phospholipid profiles change with microwave roasting according to tissue. 相似文献
57.
Ryo Toda Yuki Matsushita Mitsunori Hieda Taku Matsushita Nobuo Wada 《Journal of Low Temperature Physics》2007,148(5-6):785-790
We have measured the heat capacity of 3He adsorbed on three-dimensionally connected nanopores, 2.7 nm in diameter, preplated with about 1.3 atomic layers of 4He. At low coverages of 3He, the 3He heat capacity is roughly constant at the measured temperatures between 0.1 and 1 K. Its molar heat capacity is on the order
of the gas constant R, between 1.1R and 1.8R. This suggests a Boltzmann gas state of the adsorbed 3He. At high coverages, the heat capacity is likely approaching linear in T at low temperatures, which suggests a degenerate state at further lower temperatures. 相似文献
58.
Dr. Ivan A. Yaremenko Dr. Paolo Coghi Parichat Prommana Congling Qiu Peter S. Radulov Yuanqing Qu Yulia Yu. Belyakova Dr. Enrico Zanforlin Dr. Vladimir A. Kokorekin Yuki Yu Jun Wu Prof. Fabrice Fleury Dr. Chairat Uthaipibull Dr. Vincent Kam Wai Wong Prof. Alexander O. Terent'ev 《ChemMedChem》2020,15(13):1118-1127
This article discloses a new horizon for the application of peroxides in medical chemistry. Stable cyclic peroxides are demonstrated to have cytotoxic activity against cancer cells; in addition a mechanism of cytotoxic action is proposed. Synthetic bridged 1,2,4,5-tetraoxanes and ozonides were effective against HepG2 cancer cells and some ozonides selectively targeted liver cancer cells (the selectivity indexes for compounds 11 b and 12 a are 8 and 5, respectively). In some cases, tetraoxanes and ozonides were more selective than paclitaxel, artemisinin, and artesunic acid. Annexin V flow-cytometry analysis revealed that the active ozonides 22 a and 23 a induced cell death of HepG2 by apoptosis. Further study showed that compounds 22 a and 23 a exhibited a strong inhibitory effect on P-glycoprotein (P-gp/ABCB5)-overexpressing HepG2 cancer cells. ABCB5 is a key player in the multidrug-resistant phenotype of liver cancer. Peroxides failed to demonstrate a direct correlation between oxidative potential and their biological activity. To our knowledge this is the first time that peroxide diastereoisomers have been found to show stereospecific antimalarial action against the chloroquine-sensitive 3D7 strain of Plasmodium falciparum. Stereoisomeric ozonide 12 b is 11 times more active than stereoisomeric ozonide 12 a (IC50=5.81 vs 65.18 μm ). Current findings mean that ozonides merit further investigation as potential therapeutic agents for drug-resistant hepatocellular carcinoma. 相似文献
59.
Kiyonobu Ida Masanori TomonariYasuyuki Sugiyama Yuki ChujyoTomoharu Tokunaga Tetsu YonezawaKotaro Kuroda Katsuhiro Sasaki 《Thin solid films》2012,520(7):2789-2793
Cu nanoparticle ink was prepared from Cu nanoparticles that were coated with a gelatin layer at an average diameter of 46 nm. The Cu nanoparticle ink was applied on the polyimide substrate. Conductive films were fabricated using the Cu nanoparticle ink with a two-step annealing process consisting of oxidative pre-heating at 200 °C under 10 ppm O2-N2 mixed gas flow and reductive calcination at 250 °C under 3 vol.% H2-N2 mixed gas flow showed a low resistivity of 5 μΩ cm. The hydrolysis of the remaining gelatin layer by H2O vapor, which was formed during the reduction of the Cu oxide by 3 vol.% H2-N2 mixed gas, was suggested. The results suggest the possibility of the removal of the gelatin layer without oxidative pre-heating and simultaneous sintering of Cu nanoparticles in reductive calcination. 相似文献
60.
Takayuki Sasaki Takayuki Koukami Taishi Kobayashi Akira Kirishima Hiroaki Murakami Yuki Amano 《Journal of Nuclear Science and Technology》2017,54(3):373-381
At two underground research laboratories situated at Horonobe and Mizunami, Japan, trace amounts of natural thorium and uranium dissolved in deep groundwater were investigated with the help of chemical pre-concentration method. The groundwater was sampled from underground boreholes under the geochemical condition of no atmospheric exposure, and the colloid contribution was checked by in situ two size-fractionated ultrafiltration systems. A rough decrease by half in the concentration after in situ filtration suggested the presence of natural colloids and suspended matter that were carriers of a portion of the elements. The Th and U concentrations in groundwater after 10 kDa filtration was evaluated as dissolved species, and was identified thermodynamically using existing hydrogeological and geochemical data, such as the mineral components in the groundwater at a given pH, ionic strength, concentration of co-existing ions, redox potential, and a hypothetical solubility-limiting solid phase. The crystalline solid phase of tetravalent thorium and uranium dioxides made the solubility very low compared with that of the amorphous phase. 相似文献