3D交联复合结构凝胶聚合物电解质制备研究

通过对类聚环氧乙烷(PEO)交联聚合物进行纳米复合改性,制备了3D交联复合结构凝胶聚合物电解质(C-GCPE).详细表征了该电解质膜的微观形貌、物相组成和分子结构等性质,同时深入考察了其离子电导率、锂离子迁移数等基础电化学性能,并完成磷酸亚铁锂准固态锂离子电池组装测试.结果表明,C-GCPE电解质膜具有显著提高的吸液率...     

基于IFAHP的BIM管线碰撞优化模型

针对BIM管线碰撞技术尚不能根据碰撞位置给出管线的优化方案问题,利用直觉模糊层次分析法(IFAHP)建立了一种BIM管线碰撞优化模型。首先,依据建筑管线施工规范,从施工成本、施工难度、施工安全性和施工美观度四个方面建立了管线碰撞评价指标体系;其次,根据碰撞点位置状况,依据IFAHP构造出不同的直觉模糊判断矩阵,建立相应的直觉模糊决策模型,进而给出不同管线碰撞点的管线优化方案。最后,通过实例验证了该BIM管线碰撞优化模型的有效性和可行性。     

采用径流式塔盘对尿素合成塔的改造

介绍尿素合成塔的基本要求、结构、流程及反应原理,分析尿素合成塔塔盘改造前系统存在的问题,对比改造前、后尿素合成塔的性能特点、运行参数.通过对尿素合成塔的塔盘改造,尿素日产能可增加约205t,吨尿素蒸汽单耗减少约0.05t,吨尿素氨耗由0.571t降至0.568t,改造取得较好效果.     

Plant-wide control for the economic operation of modified single mixed refrigerant process for an offshore natural gas liquefaction plant

The marine operation of floating liquefied natural gas (FLNG) demands process compactness, flexibility, simplicity of operation, safety, and higher efficiency. The modified single mixed refrigerant (MSMR) process satisfies the FLNG process requirements and is accepted as a suitable technology for FLNG operation. The aim of this study was to develop a plant-wide control structure or strategy that can sustain the economic efficiency of the MSMR process. The NGL recovery and liquefaction units were integrated in the MSMR process to provide a compact plant structure with an efficient operation. Steady-state optimality analysis was intensively conducted in a rigorous dynamic simulation environment to determine the correct variable to sustain the economic efficiency of MSMR process. The results showed that the flow rate ratio of heavy and light mixed refrigerant (HK/LK ratio) is a promising self-optimizing controlled variable. Controlling this variable can sustain the MSMR optimality, even when the process is operated under off-design operating conditions or in the presence of disturbances. Based on the control structure tests, the control configuration with the HK/LK ratio loop showed excellent performance, maintaining the process stability against a range of disturbances. The proposed approach can also be applied to any cryogenic liquefaction technology for determining a possible optimizing controlled variable.     

Synthesis of superabsorbent resin by ultraviolet photopolymerization

Synthesis of superabsorbent resin (SAR) was achieved by a new method, that of direct UV photopolymerization, and in particular the synthesis of a SAR of acrylic acid–potassium acrylate copolymer by UV photopolymerization was investigated. Influences of ratio (mol) of acrylate monomer to acrylic acid monomer, photoinitiators, crosslinking agents, and exposure time of UV light on the water‐absorbent properties were investigated. The results showed that the water absorbency (Q) of SAR based on Irgacure 1700 or Irgacure 1800 was 545–530 mL/g, but under the same conditions Q was 450 mL/g for the SAR based on Irgacure 651. N,N′‐Methylene bisacrylamide, hydroethyl acrylate, and glycerol were used as crosslinking agents, of which N,N′‐methylene bisacrylamide was the most effective. It crosslinked the molecular chains through attending the copolymerization with acrylic acid (AA) and potassium acrylate. When the exposure time was 5 min, the value of Q was 1368 mL/g (the content of N,N′‐methylene bisacrylamide was 100 ppm). © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 1618–1624, 2004     

适用于三维有限元网格显示的逐步消隐法

在分析现有消隐方法及三维有限元网格划分特点的基础上,提出了一种将外法线法与线面比较法相结合的消隐方法──逐步消隐法,快速有效地实现了三维网格的可视化。结果表明,用于三维有限元网格划分的消隐是简便实用的。     

复杂变形过程刚粘塑性有限元模拟的快速算法

基于加快刚塑性有限无法迭代收敛的三次因子法原理，首次建立了在刚粘塑性有限元迭代计算中确定减速因子的公式，并结合进退搜索法的优点，提出了改进的三次因子快速算法。并将该方法应用于自主开发的叶片三维刚粘塑性有限元模拟系统。计算结果表明，这种方法可以比原三次因子法更明显地改善迭代的计算速度和提高收敛的稳定性。     

Preparation and characterization of transparent conductive zinc doped tin oxide thin films prepared by radio-frequency magnetron sputtering

High transparent and conductive thin films of zinc doped tin oxide (ZTO) were deposited on quartz substrates by the radio-frequency (RF) magnetron sputtering using a 12 wt% ZnO doped with 88 wt% SnO2 ceramic target.The effect of substrate temperature on the structural,electrical and optical performances of ZTO films has been studied.X-ray diffraction (XRD) results show that ZTO films possess tetragonal rutile structure with the preferred orientation of (101).The surface morphology and roughness of the films was investigated by the atomic force microscope (AFM).The electrical characteristic (including carrier concentration,Hall mobility and resistivity) and optical transmittance were studied by the Hall tester and UV- VIS,respectively.The highest carrier concentration of -1.144×1020 cm-3 and the Hall mobility of 7.018 cm2(V ·sec)-1 for the film with an average transmittance of about 80.0% in the visible region and the lowest resistivity of 1.116×10-2 Ω·cm were obtained when the ZTO films deposited at 250 oC.     

论知识经济与现代教育技术的创新

从知识经济的特征入手,分析知识经济对人的素质要求的变化,进而论述现代教育技术如何创 新以满足知识经济对人才培养的需要