由乙腈一步法制备乙酸丁酯的研究

以丁醇和制备丙烯腈的副产物乙腈为原料 ,采用一步法合成了乙酸丁酯。通过正交实验得到了影响反应的 4种因素。确定了最佳的工艺条件为 :催化剂的量为样品质量的 40 % ;n(CH3CN)∶ n(C4 H9OH) =1∶ 1 .0 5 ;反应温度为 1 0 5℃ ;反应时间为 8h。在此反应条件下 ,乙酸丁酯的收率为 88.8% ,纯度可达 99.5 %。并用气相色谱及红外光谱对产品的纯度进行了表征     

千米桥潜山构造特征及其在油气成藏中的作用

千米桥潜山是黄骅坳陷最典型的新生古储型油气藏，恢复潜山古构造是认识其油气藏特征的重点和难点之一，运用地质力学方法研究潜山内幕构造之后认为，该潜山的形成基础是古生界印支期宽缓复背斜，在燕山期挤压构造作用下形成由逆冲叠瓦扇和反冲断层构成的三角带内幕构造，抬升受侵蚀形成潜山主体，喜马拉雅的两次古旋拉张使潜山掀斜定型。晚第三纪以来发生整体热沉降，潜山两侧凹陷沙三段生成油气向潜山侧向运移成藏。     

吹风气余热回收锅炉在我厂的应用

介绍了吹风气余热回收锅炉在兖矿鲁南化肥厂的应用情况。实践证明，系统运行稳定，取得了良好的经济效益。     

The Synthesis of Sulfated Titanium Oxide Nanotubes

TiO₂ nanotubes can be prepared in gram quantities by treating anatase TiO₂ powder with concentrated NaOH solution. These TiO₂ nanotubes acquired strong acidity after being impregnated with sulfuric acid solution and calcined at 300 °C. The anatase TiO₂ powder used to prepare the nanotube did not catalyze the esterification between cyclohexanol and acetic acid, while sulfated TiO₂ nanotubes were very reactive toward the esterification reaction.     

数字化制模新技术

数字化制模技术是将三维CAD模型直接转化成为铸造用模的新技术。文中介绍了华中科技大学开发的HRP系列数字化制模技术的原理及制模工艺。与传统制模方法相比 ,具有制模速度快、精度高、质量好、价格便宜等优点。文中还以制作轿车制动器卡钳体模样、搅拌叶片模样、蜗壳凸样为例说明了运用数字化制模新技术的优点     

A general framework for debugging

The state of the art of debugging is examined. A debugged process model that serves as the basis of a general debugging framework is described. The relationship of the model to traditional debugging processes and support tools is discussed. A minimal set of requirements for a general debugging framework is described in terms of both the theory behind debugging methodologies and the support tools. An execution monitor, Eden, that serves as a debugging tool within this general framework is described     

Effect of polymerization conditions on the melt rheological properties of vinyl chloride–vinyl acetate copolymers

Mathematical models have been developed which predict the composition, molecular weight, and melt rheological properties for vinyl chloride/vinyl acetate copolymers of inherent viscosity range 0.4–0.7 dL/g and bound vinyl acetate levels of 3.8–17.4%. The effect of polymer long chain branching on the viscous/elastic moduli ratio is discussed as well as the comparison of Tinius–Olsen melt index measurements vs. mechanical spectrometer results. The reactivity ratio for vinyl chloride/vinyl acetate comonomer pairs was remeasured and found to be significantly different from literature values.     

Particle structure of PVC based on cellulosic suspension system. III. Effect of monomer refluxing

The effects of monomer refluxing on both resin properties and reactor fouling of suspension PVC have been studied in a laboratory-scale 14-L reactor. Process control equations were developed which related the particle properties to the reflux condenser operation by controlling the parameters of (1) the time at which refluxing is begun and (2) the rate profile of heat removal from the condenser. An operating envelope has been developed for laboratory scale operations which optimizes the cycle time of polymerization while minimizing the adverse effects on particle properties. These operating conditions may have application to production scale operations when the proper scaling factors are employed.     

PKI技术在社保电子政务中的应用

背景和意义劳动保障部门作为统一管理和组织协调社会劳动力,统筹城乡就业,规划、引导劳动力市场的发展,组织建立健全就业服务体系,负责社会保障基金的缴纳、记录、核算、支付的部门,运用信息技术来实现劳动保障管理工作的电子化、自动化和网络化,更科学、更迅速、更准确地汇集、加工、传递、运用各类信息,是社会保障电子政务系统建设的重要内容,也是加快由行政管理向社会服务转化的突破口。随着社会保障电子政务系统建设的不断深入以及网络技术的发展,基于Internet的网上应用已逐步开展。如参保单位的网上申报、网上缴费以及信息查询等。这…     

A subspace detection method of analog space-time codes for multiantenna ultra-wideband transmissions

In this letter, we propose a subspace based detection method for space-time block codes (STBC) wedded with ultra-wideband (UWB) transmissions. Without the need of channel information, the proposed algorithm yields the estimation of transmitted symbols by minimizing some quadratic form built on the orthogonality between signal and noise subspaces. Simulations in flat-faded application scenarios show that the subspace method can achieve the same diversity and a loss of about 2 dB at the 10/sup -3/ level with more than four successive space-time codes being decoded jointly, compared to the coherent decoding algorithm.