Experimental and theoretical study of particle dispersion phenomena in a turbulent gas jet of the flash-smelting process by the image analysis technique

The particle dispersion phenomena in a turbulent gas jet of the flash-smelting process have been investigated. The particle number density in a nonreacting jet was measured experimentally by taking photographs of the particles in flight and counting them using the image analysis technique. Numerical computations were also performed using a mathematical model for a turbulent particle-laden gas jet. The experimental particle number density data were then compared with the predicted results of the model. Good agreement was obtained between the experimental and predicted data. The effects of the parameters such as the injector design, particle loading, and air flow rate are discussed. Optimization of the concentrate burner design can be achieved with the help of experimental and theoretical simulations as performed in this work. YUTAKA YASUDA, formerly Graduate Student, Department of Metallurgical Engineering, University of Utah.     

BWR core-wide stability analysis with respect to dominant feedback mechanisms and characteristic poles

BWR core-wide stability is studied from the viewpoint of linear dynamic stability treated via poles of a closed-loop transfer function. The quantitative study is performed using a BWR noise model describing neutronic and thermal-hydraulic core dynamics. Transfer functions of neutron power to reactivity and core inlet flow are derived in explicit forms and their poles are evaluated both numerically and analytically. It is shown that the characteristic poles may be classed into three groups relating to neutronic process, fuel heat transfer and core void dynamics. In particular, the poles for the void dynamics take complex values and hence give rise to core-wide damped oscillation of neutron power. Furthermore, the study of characteristic poles serves for the stability analysis of the Ringhals-1 benchmark test data. It is shown and clarified that two stability indexes, decay ratio and resonance frequency, have clear dependence on reactor power and core inlet flow.     

Spark plasma sintering and pressureless sintering of SiC using aluminum borocarbide additives

Aluminum borocarbide powders (Al₃BC₃ and Al₈B₄C₇) were synthesized, and the ternary powders were used as a sintering additive of SiC. The densification of SiC was nearly completed at 1670 °C using spark plasma sintering (SPS) and pressureless sintering was possible at 1950 °C. The sintering behavior of SiC using the new additive systems was nearly identical with that using the conventional Al–B–C system, but grain growth was suppressed when adding the borocarbides. In addition, oxidation of the fine additive powders did not intensively occur in air, which has been a problem in the case of the Al–B–C system for industrial application. The hardness, Young's modulus and fracture toughness of a sintered SiC specimen were 21.6 GPa, 439 GPa and 4.6 MPa m^1/2, respectively. The ternary borocarbide powders are efficient sintering additives of SiC.     

Electrochemical reduction of graphene oxide in organic solvents

Graphene oxide (GO) cast on conductive substrates was electrochemically reduced in some organic solvents. The amount of electricity required for the almost complete reduction of GO was 2.0 C for 1 mg GO, corresponding to attaching of a one-electron reducible species to each benzene ring in graphene. The electrochemically reduced GO film gave an electrical conductivity of about 3 S cm⁻¹ and exhibited a relatively high specific capacitance of 147.2 F g⁻¹ in propylene carbonate. The electrochemical reduction of GO was feasible on Al foils as well.     

Chemical Synthesis and Gas Chromatographic Behaviour of γ‐Stearidonic (18:4n‐6) Acid

γ‐Stearidonic acid, 18:4n‐6, a potential product of β‐oxidation of arachidonic acid (20:4n‐6), was only recently positively identified in a living organism—a thermophilic cyanobacterium Tolypothrix sp., albeit at low levels, whilst some indirect evidence suggests its wider presence, e.g. in a unicellular marine alga. We have prepared 18:4n‐6 using an iodolactonisation chain‐shortening approach from 22:5n‐6 and obtained its ¹H‐, ¹³C‐, COSY‐ and HSQC NMR spectra, with 18:5n‐3 spectra also recorded for a comparison. The GC and GC‐MS behaviour of its methyl ester was also studied. Like another Δ3 polyunsaturated acid, octadecapentaenoic (18:5n‐3), 18:4n‐6 rapidly yields 2‐trans isomer upon formation of dimethyloxazoline derivative. On a polar ionic liquid phase (SLB‐IL100, 200 °C) the methyl ester could be mistaken for 18:3n‐3, while on methylsilicone phase (BP1, 210 °C) it eluted ahead of 18:3n‐6 and 18:4n‐3, suggesting that when present it may be easily misidentified during GC analysis of fatty acids.     

On standard control problems for systems with infinitely many unstable poles

In this paper, H^∞ control for a class of linear time invariant systems with infinitely many unstable poles is studied. An example of such a plant is a high gain system with delayed feedback. We formulate the problem via a generalized plant which consists of a rational transfer matrix and the inverse of a scalar (possibly irrational) inner function. It is shown that the problem can be decomposed into a finite-dimensional H^∞ control problem and an additional rank condition.