Synthesis of (+/-)-cassumunins A and B, new curcuminoid antioxidants having protective activity of the living cell against oxidative damage

A chemical synthesis of cassumunins A (1) and B (2), natural curcuminoid antioxidants, was developed. The synthesis was started from o-vanillin and after nine reaction steps resulted in 20% and 26% overall yields of 1 and 2, respectively. The synthetic cassumunins showed stronger protective activity than curcumin against oxidative cell death induced by hydrogen peroxide in a rat thymocyte system.     

A 98 mm2 die size 3.3-V 64-Mb flash memory with FN-NORtype four-level cell

In order to realize high-capacity and low-cost flash memory, we have developed a 64-Mb flash memory with multilevel cell operation scheme. The 64-Mb flash memory has been achieved in a 98 mm² die size by using four-level per cell operation scheme, NOR type cell array, and 0.4-μm CMOS technology. Using an FN type program/erase cell allows a single 3.3 V supply voltage. In order to establish fast programming operation using Fowler-Nordheim (FN)-NOR type memory cell, we have developed a highly parallel multilevel programming technology. The drain voltage controlled multilevel programming (DCMP) scheme, the parallel multilevel verify (PMV) circuit, and the compact multilevel sense-amplifier (CMS) have been implemented to achieve 128 b parallel programming and 6.3 μs/Byte programming speed     

A new psychophysical method: Method of transposition or equal-appearing relations.

"In many experiments dealing with perceptual phenomena, investigators try to find a stimulus which appears equal to a standard stimulus. It often happens, however, that the procedure involved in finding the equivalent stimulus alters the stimulus pattern so that the measurement is not made on the original stimulus pattern. To avoid this difficulty, a new psychophysical method, which is named the method of transposition or the method of equal-appearing relations, was proposed. The major advantage of this method over the traditional ones is that it leaves the original stimulus pattern intact." (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Soft-x-ray hollow fiber optics with inner metal coating

A glass capillary with an inner metal coating is proposed to be used as soft-x-ray fiber optics in medical applications. Based on the results of theoretical calculations, nickel was chosen as the coating material for x rays radiated from a conventional x-ray tube. A nickel-coated capillary was fabricated by electroless deposition, and focusing and collimating effects were observed from measurements of the transmission efficiency of soft x rays. The transmission of a nickel-coated capillary with an inner diameter of 0.53 mm and a length of 300 mm was 10%, which is approximately double that of an uncoated glass capillary.     

Effect of composition and promoters in Au/TS-1 catalysts for direct propylene epoxidation using H2 and O2

A series of Au/titanium silicalite-1 (TS-1) catalysts with different Si/Ti ratios and promoted with alkali and alkaline earth cations were prepared by deposition–precipitation (DP) and tested for direct propylene epoxidation. It was found that the gold loading and catalytic activity was highly dependent on the pH of the DP synthesis solution and the final composition of the catalyst. Addition of Group 1 metals such as K or Cs had little effect on the gold content, but increased activity, while Group 2 metals such as Mg, Ca, Sr, and Ba increased both the gold content and the catalytic activity. The highest improvement was provided by a Mg promoted catalyst, which at 443 K and 0.1 MPa with a H₂/O₂/C₃H₆/Ar = 1/1/1/7 feed mixture gave a propylene oxide (PO) formation rate of 88 gPO h⁻¹ kg_cat⁻¹, compared to 57 gPO h⁻¹ kg_cat⁻¹ for an unpromoted catalyst, corresponding to a 50% enhancement of activity. Ammonia temperature-programmed desorption (NH₃-TPD) measurements indicated little change in adsorption amount with promotion indicating that the yield increase was not due to the elimination of acidic sites on the catalyst. Instead, the improved catalytic performance was ascribed to increased Au capture efficiency and dispersion by the catalyst. The effect of Si/Ti ratio, pH of synthesis, and the promoter ions on the gold content could be understood from their effect on the surface charge of the support.     

MISCELA: discovering simultaneous and time-delayed correlated attribute patterns

This article addresses a new pattern mining problem in time series sensor data, which we call correlated attribute pattern mining. The correlated attribute patterns (CAPs for short) are the sets of attributes (e.g., temperature and traffic volume) on sensors that are spatially close to each other and temporally correlated in their measurements. Although the CAPs are useful to accurately analyze and understand spatio-temporal correlation between attributes, the existing mining methods are inefficient to discover CAPs because they extract unnecessary patterns. Therefore, we propose a mining method Miscela to efficiently discover CAPs. Miscela can discover not only simultaneous correlated patterns but also time delayed correlated patterns. Furthermore, we extend Miscela to automatically search for correlated patterns with any time delays. Through our experiments using three real sensor datasets, we show that the response time of Miscela is up to 20.84 times faster compared with the state-of-the-art method. We show that Miscela discovers meaningful patterns for urban managements and environmental studies.

     

Suprathermal plasma analyzer for the measurement of low-energy electron distribution in the ionosphere

It is commonly believed that an energy transfer from thermal to suprathermal electrons (相似文献