Palladium and Copper Cocatalyzed Intermolecular Cyclization Reaction: Synthesis of 5‐Aminopyrazole Derivatives

A novel and efficient palladium and copper co‐catalyzed intermolecular cyclization of acetonitriles with hydrazones has been developed for the synthesis of 5‐aminopyrazoles through C C and C N bond formation. The reaction has the advantages of easily available starting materials, simple manipulation and mild reaction conditions. The reaction involving various substituted acetonitriles and hydrazones proceeds smoothly and 5‐aminopyrazoles are synthesized in good yields. In contrast to the aliphatic and heteroaromatic substrates, the aromatic substrates tend to have a higher degree of reactivity.

     

Dearomatization of Indole Derivatives via Palladium‐Catalyzed C?H Bond Functionalization of Pyrroles: Convenient Construction of Spiroindolenines

An intramolecular palladium(II)‐catalyzed dearomative arylation reaction of indoles via C H bond functionalization was developed, providing access to structurally novel spiroindolenines with moderate to good yields. A one‐pot process for the synthesis of spiroindoline derivatives was also realized.

     

Efficient Catalyst for Both Suzuki and Heck Cross‐Coupling Reactions: Synthesis and Catalytic Behaviour of Geometry‐ Constrained Iminopyridylpalladium Chlorides

A series of geometry‐constrained iminopyridyl‐palladium chlorides were synthesized and characterized. These phosphine‐free palladium complexes were explored for their catalytic activities in both Suzuki and Heck cross‐coupling reactions, achieving turnover numbers as high as 10⁶ towards various aryl bromides, even those containing various functionalities. In addition, the influence of substituents with steric and electronic factors was reflected by the differences observed in their activities.

     

Preparation of antimicrobial activated carbon fiber for adsorption

Journal of Porous Materials - Activated carbon fiber (ACF) is often used as efficient adsorption material for removal of contaminants from water. However, the propagation of microorganism on ACF...     

As-cast microstructure of Al-Zn-Mg-Cu-Zr alloy containing trace amount of Sc

It has been reported that the element scandium(Sc) is the most effective modificator which can significantly refine the grain size, prohibit recrystallization process and increase the strength. Adding trace of Sc in 7000 series aluminum alloys is considered to be an effective way to modify its micros tructure and promote mechanical properties. In order to study the effect of Sc element on ascast microstructure of Al-Zn-Mg-Cu-Zr alloy, ingots containing different amounts of Sc were prepared by ferrous-mold cast. Microstructures were characterized by means of differential scanning calorimeter(DSC), X-ray diffraction(XRD), optical microscope(OM) and scanning electrical microscope(SEM). The results indicate that when the Sc level exceeds a critical concentration,Al_3(Sc,Zr) primary phase would form in the melt and act as an efficient nucleant, resulting in very refined grain and an equiaxed grain structure. Sc element reduces the number of eutectic phases formed during solidification,coupled with an increase in the concentration of major alloying elements retained in the solute. This behavior suggests possible benefits in improving the integrated properties of terminal products.     

COW清洗机工作机构改进设计及应用

根据原油储罐机械清洗工艺的需要,对现有的日本COW清洗机工作机构进行了改进设计,并进行了实际的清洗施工应用,效果良好,有效解决了工程中的技术难题,扩大了COW清洗机的应用范围.     

超因瓦合金薄壁筒件的加工变形控制研究

针对高温低膨胀合金4J32薄壁筒件的车削问题,从材料特性以及零件结构的方面分析可加工性,通过改进装夹方式,合理选用刀具以及切削用量来减小加工变形,并运用ANSYS有限元分析软件进行分析论证,提出了相应解决问题的方法.     

气流扰动下单液滴撞击单根干燥扁网丝特性数值研究

丝网分离器在工业中有着广泛地应用。本文针对液滴撞击网丝的动态过程,采用CLSVOF方法对单个液滴撞击干燥网丝的问题进行数值模拟,经过合理的简化,建立了气流扰动下单液滴撞击干燥扁网丝面的二维数学模型,分析了液滴撞击角和撞击位置对液滴撞击行为特性的影响。数值计算的结果表明:液滴撞击到干燥网丝上分为铺展和飞溅2个过程,撞击角越小,上铺展半径越大,下铺展半径越小,分离的二次液滴体积越大;液滴撞击网丝的位置离网丝边缘越近,越容易产生二次液滴,二次液滴的总体积越多。     

日本雪印乳业集团食品安全事件及企业社会责任体系重构的追踪研究

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不同光质对苦荞萌发过程中的黄酮类化合物及其抗氧化活性的影响

本文以萌发3 d的苦荞为实验材料,通过红光、黄光、绿光、白光、蓝光、紫外A（254 nm）、紫外C（365 nm）七种不同的光质处理萌发过程中的苦荞,研究了不同光质对萌发苦荞中黄酮类化合物、抗氧化活性以及与黄酮合成和降解有关酶类的影响。实验结果表明:经紫外、蓝光、白光、绿光、黄光和红光处理均可显著地增加苦荞芽中总黄酮和芦丁的含量（与暗处理比较）,不同处理之间有显著性差异（p<0.05）。C段紫外（UV-C）处理后,苦荞芽中总黄酮和芦丁含量最高,与对照相比分别提高了30.1%、40.9%,蓝光处理其次。同时,经光处理后,苦荞芽中黄酮类物质代谢的关键酶苯丙氨酸解氨酶（PAL）和察尔酮异构酶（CHI）活性均显著升高,与总黄酮和芦丁含量呈现正相关。此外,苦荞萌发过程中,光处理可增加苦荞芽对DPPH自由基的清除率,最高可达35.1%,清除率与总黄酮含量呈正相关,表明光处理可以通过增加苦荞芽中黄酮类物质含量进而提高苦荞的抗氧化活性。