Dynamic responses of K-type and inverted-K-type jacket support structures for offshore wind-turbines

Journal of Central South University - The jacket structure has become more popular as the offshore wind-turbine support structure. K-type and inverted-K-type jacket support structures have superior...     

紫外光引发聚合P(AM-MAPTAC)及其响应面优化制备

以丙烯酰胺（AM）与甲基丙烯酰胺丙基三甲基氯化铵（MAPTAC）为共聚单体,通过紫外光引发聚合法制备阳离子聚丙烯酰胺絮凝剂P（AM-MAPTAC）。通过红外光谱（IR）与差热热重分析（TG/DSC）分别对P（AM-MAPTAC）进行结构表征与热稳定性分析,并采用响应曲面法得到优化制备条件：反应体系pH为4.75,引发剂v-044质量分数为0.07%,EDTA-2Na质量分数为0.20%,n（MATPAC）/n（AM）为0.33,光照时间为60 min。在优化条件下制备P（AM-MAPTAC）絮凝剂,特性粘度可达14.72 dL/g,通过污泥脱水实验可验证该特性粘度下的污泥脱水效果最好,滤饼含水率（FCMC）达70%,污泥比阻（SRF）达6.94×10¹²m/kg,上清液剩余浊度达9.70 NTU,污泥脱水效果优于市售常用絮凝剂。     

Controllable preparation and superior rate performance of spinel LiMn<Subscript>2</Subscript>O<Subscript>4</Subscript> hollow microspheres as cathode material for lithium-ion batteries

Spinel LiMn₂O₄ microspheres and hollow microspheres with adjustable wall thickness have been prepared using controllable oxidation of MnCO₃ microspheres precursors and following solid reactions with lithium salts. Scanning electron microscopy (SEM) investigations demonstrate that the microsphere morphology and hollow structure of precursors are inherited. The effect of hollow structure properties of as-prepared LiMn₂O₄ on their performance as cathode materials for lithium-ion batteries has been studied. Electrochemical performance tests show that LiMn₂O₄ hollow microspheres with small wall thickness exhibit both superior rate capability and better cycle performance than LiMn₂O₄ solid microspheres and LiMn₂O₄ hollow microspheres with thick wall. The LiMn₂O₄ hollow microspheres with thin wall have discharge capacity of 132.7 mA·h·g^-1 at C/10 (14.8 mA·g^-1) in the first cycle, 94.1% capacity retention at C/10 after 40 cycles and discharge capacity of 116.5 mAh·g^-1 at a high rate of 5C. The apparent lithium-ion diffusion coefficient (D _app) of as-prepared LiMn₂O₄ determined by capacity intermittent titration technique (CITT) varies from 10^-11 to 10^-8.5 cm²·s^-1 showing a regular “W” shape curve plotted with test voltages. The Dapp of LiMn₂O₄ hollow microspheres with thin wall has the largest value among all the prepared samples. Both the superior rate capability and cycle stability of LiMn₂O₄ hollow microspheres with thin wall can be ascribed to the facile ion diffusion in the hollow structures and the robust of hollow structures during repeated cycling.     

区域电磁环境的动态特性表征

区域电磁环境中各种电磁干扰辐射信号种类繁多、调制体制各异,信号参数的动态变化,传播路径及其相应影响的不确定性,表现为电磁信号在时间、能量上相互干扰发生异常变化造成电磁环境动态性异常激烈,导致区域内接受设备系统性能下降。针对这一问题,提出基于分形理论与数学形态学相结合的方法,研究区域电磁环境动态特征,利用分形维数表征电磁环境动态性。首先,基于信号基础理论对区域接收点处电磁信号的集合进行建模;其次,利用数学形态学滤波原理对接收的电磁信号集合进行交替滤波,滤除电磁信号中的脉冲噪声和白噪声;最后,运用分形理论求解电磁环境接收点集合的关联维数,并对计算结果进行仿真分析,表明该方法能从时间、空间和能量上为电磁环境的动态性提供有利支撑。     

GFRP肋式剪力连接件受力性能对比试验研究

剪力连接件是保证GFRP混凝土组合梁/板中两种不同材料共同工作的重要构造,设计了矩形肋和T形肋两类GFRP肋式剪力连接件,进行了3组共8个GFRP肋式剪力连接件的推出试验,包括：矩形肋开孔、T形肋开孔、T形肋不开孔3组GFRP肋式剪力连接件,得到了其破坏形态、极限承载力、荷载滑移曲线及荷载应变变化规律,重点研究肋内开孔及肋的截面形式对GFRP肋式剪力连接件受力性能的影响。试验结果表明：GFRP肋式剪力连接件的破坏形态均为混凝土劈裂破坏;对比矩形肋开孔试件,T形肋开孔试件强度高、延性好;对比T形肋不开孔试件,T形肋开孔试件强度与延性均能提高。基于试验结果,建立了考虑肋内开孔及肋截面形式影响的GFRP肋式剪力连接件极限承载力计算公式,拟合得到了GFRP肋式剪力连接件的荷载滑移曲线上升段的理论模型,建立了其抗剪刚度计算公式。     

乌东德水电站建设岩石力学工程问题科技创新的思考

乌东德工程因所处河谷复杂严峻的自然环境条件及区域地质地震背景,面临枢纽工程布置、高陡边坡治理、大坝建基岩体选择与建基面确定、复杂地下洞室群安全施工、远程泥石流灾害预警、近坝大型滑坡体及水库岸坡安全稳定等工程地质和岩石力学关键问题的挑战。建设单位、设计单位、科研单位与技术咨询单位的众多工程师和科学家协同攻关,艰辛探索,攻克了工程建设过程中一系列的岩石力学关键技术问题,创新了遵循岩石力学规律特性的工程管理方法,促进了乌东德工程安全优质建设。本文结合工程建设进展,总结了乌东德工程岩石力学关键技术的科技创新,展望了绿色水电开发、建设、运行科技创新的方向。     

An optimal fracture geometry design method of fractured horizontal wells in heterogeneous tight gas reservoirs

In this work, the unified fracture design (UFD) is extended for the first time to the fractured horizontal wells in heterogeneous closed box-shaped tight gas reservoirs. Utilizing the direct boundary element method and influence function, the dimensionless fracture productivity index is obtained and expressed in the function of proppant volume and fracture geometry at the pseudo- steady state. With the iterative method, the effectively propped permeability, k_fe, is corrected using the in-situ Reynolds number, N_Re. The goal of this paper is to present a new UFD extension to design the proppant volume and the optimal fracture geometry. The results show that there exists an optimal proppant volume for a certain reservoir. The small aspect ratio (y_e/x_e) and high permeability reservoirs need short and wide fractures to diminish the non-Darcy effect. On the contrary, long and narrow fractures are required for the large aspect ratio and low permeability reservoirs. A small proppant volume is prone to creating long fractures, while a relatively large proppant volume creates wide fractures. The new extension can be used to evaluate the previous fracture parameters and design the following fracture parameters of the fractured horizontal well in heterogeneous tight gas reservoirs, with the non-Darcy effect taken into account.     

Fabrication of iridium oxide neural electrodes at the wafer level

Electro-deposition, electrical activation, thermal oxidation, and reactive ion sputtering are the four primary methods to fabricate iridium oxide film. Among these methods, reactive ion sputtering is a commonly used method in standard micro-fabrication processes. In different sputtering conditions, the component, texture, and electrochemistry character of iridium oxide varies considerably. To fabricate the iridium oxide film compatible with the wafer-level processing of neural electrodes, the quality of iridium oxide film must be able to withstand the mechanical and chemical impact of post-processing, and simultaneously achieve good performance as a neural electrode. In this study, parameters of sputtering were researched and developed to achieve a balance between mechanical stability and good electrochemical characteristics of iridium oxide film on electrode. Iridium oxide fabricating process combined with fabrication flow of silicon electrodes, at wafer-level, is introduced to produce silicon based planar iridium oxide neural electrodes. Compared with bare gold electrodes, iridium oxide electrodes fabricated with this method exhibit particularly good electrochemical stability, low impedance of 386 kΩ at 1 kHz, high safe charge storage capacity of 3.2 mC/cm², and good impedance consistency of less than 25% fluctuation.     

钢曲杆在高温（火灾）下的力学特征数值分析

高温(火灾)环境下钢曲杆的受力和变形将会产生较大变化,对结构的力学特征影响较大。本文根据结构稳定理论和热力学原理,应用有限元分析方法,结合三种不同工况,分别探讨了高温(火灾)环境下不同支座形式、杆截面形式等因素对钢曲杆力学特征的影响,并对三种工况下钢曲杆力学特征进行了数值分析与对比,得出了H型钢截面无铰钢曲杆更加符合建筑安全要求的结论,研究成果可为钢曲杆抗火研究提供参考。     

基于投影及优势度的不确定语言群决策方法

针对属性权重信息不完全的多粒度不确定语言多属性群决策问题,提出一种基于投影及优势度的群决策方法.该方法采用连续区间二元语义的有序加权调和平均(ITC-OWH)算子将多粒度不确定语言评价矩阵转化为二元语义决策矩阵,基于投影法构建目标规划模型,从而确定单个决策者的属性权重向量.在每个决策者之下,计算任意2个方案之间比较的综合属性优势度,根据综合优势度矩阵及决策者权重向量获得群体综合优势度矩阵,由各方案的总优势度获取方案的排序结果.最后,将提出的群决策方法应用到潜艇研制方案遴选问题中,验证了该方法的可行性与有效性.