Application of multisine impedance spectroscopy, FE-AES and FE-SEM to study the early stages of copper corrosion

During the first 24 h of immersion of a pure copper surface in a NaCl containing solution, this surface is in constant evolution. The reactions going on the surface are still not known; discrepancies are found between different published studies. This study resolves these discrepancies using broadband impedance spectroscopy, field emission Auger spectroscopy and field emission electron microscopy. The surface evolution was studied using time series of impedance spectra. Also the experimental variables convection and electrolyte concentration were varied. Parameter evolutions were obtained by fitting the obtained impedance spectra to an equivalent circuit. Combining the calculated parameter values and their evolution with the spectroscopic data led to the identification or replacement of the elements present in the very general equivalent circuit found in the literature: a double layer, two circuit films in parallel and mass transfer.     

Methodology for the large-scale assessment of small hydroelectric potential: Application to the Province of New Brunswick (Canada)

The mapping of the small hydropower (SHP) resource over a given territory is indispensable to identify suitable sites for the development of SHP renewable energy projects. In this study, a straightforward method to map the SHP potential over a large territory is presented. The methodology uses a synthetic hydro network (SHN) created from digital elevation models (DEM) to ensure precise hydro head estimations. From the SHN, hydro heads are calculated by subtracting the minimum from the maximum elevation of synthetic stream segments. Subsequently, stream segments with low hydro heads over a specified maximum distance are removed. Finally, the method uses regional regression models to estimate the annual baseflow for all drainage areas in the study area. The technical SHP potential can then be estimated as a function of the hydro head and maximum penstock length. An application of the method is made to the province of New Brunswick, Canada, where SHP maps have been developed to promote the development of the SHP energy sector in the province. In terms of the SHP opportunity, it is shown that the province of New Brunswick (71,450 km²) has a good SHP resource. Using a representative hydro head (10 m) and penstock length (3000 m) for the region, 696 potential sites have been identified over the territory. Results show that the technical SHP potential for New Brunswick is 368 MW for the conventional hydroelectric reservoir SHP configuration, while for the run-of-river SHP configuration, the technical SHP potential is 58 MW.     

What Currently Limits Charge Carrier Mobility in Crystals of Molecular Semiconductors?

Charge carrier mobility is a central property that characterizes the performances of organic semiconductors and is mostly measured in field-effect transistors. High mobility values are sought by many research teams. This article, that provides an overview of best performing molecular semiconductors is constructed on the question: What currently limits charge carrier mobility in crystals of molecular semiconductors? With this in mind, we confront, in a critical way, the current theoretical understanding to the most salient experimental results with the hope to reach a deeper understanding based on first principles and order of magnitudes of the main physical parameters.     

Electrically controlled fluorescence in a nematic liquid crystal doped by a chiral fluorophore

We have discovered a strong electric field sensitivity of the fluorescence intensity while studying the diffusion processes of a chiral fluorescent molecule (CFM) in a nematic liquid crystal (NLC) host. The experimental and theoretical study of this phenomenon indicates that the alignment of the CFM along two privileged orientation directions (with asymmetric distribution with respect to the NLC’s optical axis) is in the origin of this phenomenon. As a result, the obtained guest–host system demonstrates noticeable dichroism. Thus, the application of an electric field allows the reorientation of the anisotropy axis of the host, the change of CFM’s absorption (at the wavelength of excitation) and the dynamic electric control of its fluorescence intensity. The study of these phenomena allows also the identification of the angular distribution of guest CFMs suggesting that the elastic energy of orientation of the host molecules might be in the origin of the asymmetric angular distribution of CFM.     

Prediction of the goat milk fatty acids by near infrared reflectance spectroscopy

Near infrared reflectance spectroscopy (NIRS) was used to predict the goat milk fatty acid (FA) profile. The ability of cow milk broad‐based calibration equations to predict the goat milk FA profile was assessed. Three hundred twenty‐eight samples in the calibration set and 108 in the validation set were analyzed. We showed that the bias and unexplained error were significant for most of the FA despite an adequate standardized Mahalanobis distance (index to establish the boundaries of a population of samples) which allowed us to test the ability of bovine models to predict goat milk FA profiles. To better predict the goat milk FA composition, a specific goat model was investigated. The cross‐validation coefficient of determination (R²CV; proportion of variance explained by the model in cross‐validation) and residual predictive deviation (RPD; index which allows to standardize the standard error of prediction (SEP)) were >0.90 and 3, for saturated, monounsaturated, and unsaturated FA, total trans FA, isomer cis9trans11 of CLA, cis9‐, trans10‐, and trans11‐C18:1, respectively. Monitoring of the equation performance of milk FA included the calculation of the bias and unexplained error. Practical applications: In this work, we evaluated the ability of NIRS to predict FA composition of goat milk and tested the ability of using broad‐based cow milk calibration equations to monitor an independent set of goat milk samples. We tested the hypothesis that the calibration equations obtained for FA from cow milk could be applied on goat milk. As the spectra of goat milk are similar to those of cow milk when they are measured by the standardized Mahalanobis distance (index to establish the boundaries of a population of samples), we can accept the hypothesis. It will be possible to use the existing calibration equations for predicting FA profile on spectra of milk of a different specie. However, the rejection of the hypothesis would put in doubt the use of Mahalanobis distance as the unique index for testing the performance of calibration equations on different milk populations for predicting FA.     

<Emphasis Type="Italic">Nosema</Emphasis> spp. Infection Alters Pheromone Production in Honey Bees (<Emphasis Type="Italic">Apis mellifera</Emphasis>)

Pheromones in social insects play a key role in the regulation of group homoeostasis. It is well-established that parasites can modify hormone signaling of their host, but less is known about the effect of parasites on pheromone signaling in insect societies. We, thus, tested in honey bees (Apis mellifera) the effect of the widespread parasite Nosema spp. on the production of ethyl oleate (EO), the only identified primer pheromone in honey bee workers. Since environmental stressors like pesticides also can weaken honey bees, we also analyzed the effect of imidacloprid, a neonicotinoid widely used in agriculture, on EO production. We show that, contrary to imidacloprid, Nosema spp. significantly altered EO production. In addition, the level of Nosema infection was correlated positively with the level of EO production. Since EO is involved in the regulation of division of labor among workers, our result suggests that the changes in EO signaling induced by parasitism have the potential to disturb the colony homoeostasis.     

Molecular modeling of particle reinforcement in elastomers: Effect of particle radius and volume fraction

Monte-Carlo simulations of the configurations of polymer chains in reinforced elastomers reveal extensive wrapping of the chains around particle clusters. The resulting increase in chain entanglement density leads to a 3.5 power law dependence of modulus on particle loading, in perfect agreement with experimental observation. Our model also gives a consistent molecular explanation of the Payne effect and the associated energy dissipation in strained reinforced elastomers.     

Evidence of sidewall covalent functionalization of single-walled carbon nanotubes and its advantages for composite processing

Single-walled carbon nanotubes (SWCNTs) were functionalized in a three-step procedure. The first step is a radical reaction creating a covalent bond between the carbon nanotube surface and grafted p-methoxyphenyl functional groups. In a second step, a deprotection of the methoxy functions generates free alcohol groups and in the final step an esterification is done in order to install a double bond for further polymerization. Evidence that functionalization has actually occurred on the SWCNT sidewalls is furnished through investigations involving several complementary techniques (visual dispersion tests, transmission electron microscopy, thermal gravimetric analysis and adsorption volumetry). We show that surface properties of SWCNTs are changed throughout the chemical treatments and that the obtained level of functionalization is low. Incorporation of functionalized SWCNTs in a polymer (poly(methyl methacrylate)) matrix was done through an in situ polymerization process. Observations of the obtained composites using scanning and transmission electron microscopy illustrate that interactions between the SWCNT surface and the polymer matrix are improved.