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11.
Amphiphilic block copolymers have been investigated for their utilization in emulsion polymerization of butyl methacrylate. Special attention has been paid to the adsorption mechanism of the block copolymers from systematic measurements of equilibrium adsorption isotherms. A series of well-defined water-soluble amphiphilic block copolymers, composed of poly(butyl methacrylate) and poly(sodium methacrylate) blocks, were synthesized by anionic polymerization of butyl methacrylate and tert-butyl methacrylate followed by the thermal deprotection of the tert-butyl ester groups and final hydrolysis. The number density of emulsion polymer particles NP varied as [copolymer]α, α lying between 0.44 and 0.73 according to the hydrophilic content of the copolymers. In contrast with SDS taken as a reference emulsifier, the adsorption of the copolymers was very strong and this provided quite an efficient stabilization of the polymer particles during emulsion polymerization, even at low concentrations (<10−4 mol L−1) and low coverages (<10% of the interfacial area). 相似文献
12.
Interaction between dietary protein and fat in triglyceride metabolism in the rat: Effects of soy protein and menhaden oil 总被引:4,自引:0,他引:4
The objective of the present study was to determine the mechanisms by which dietary proteins interact with dietary lipids
in the regulation of triglyceridemia in rats. Male Sprague-Dawley rats (n=56) were subjected to 28-d experimental diets containing different combinations of proteins (20% w/w) and lipid sources (14%
w/w): (i) casein-menhaden oil, (ii) casein-beef tallow, (iii) soy protein-menhaden oil, and (iv) soy protein-beef tallow.
Significant protein-lipid interactions were observed on triglyceridemia and hepatic cholesterol in fasted rats. The combination
of casein and beef tallow was associated with high plasma TG and hepatic cholesterol concentrations, which were reduced by
substitution either of soy for casein or of menhaden oil for beef tallow. Therefore, triglyceridemia and liver cholesterol
remained low with soy protein feeding, independently of the lipid source, as well as with menhaden oil feeding, regardless
of the protein source. The menhaden oil diets reduced plasma cholesterol, hepatic TG, and TG secretion compared with beef
tallow diets independently of the dietary protein source. Modifying the source of dietary proteins and lipids had no effect
on post-heparin plasma lipoprotein lipase activity. These results demonstrate that soy protein can lower rat triglyceridemia
relative to casein when associated with beef tallow consumption, whereas menhaden oil can attenuate hypertriglyceridemia when
rats are fed casein. The data further suggest that part of the hypotriglyceridemic effect of soy protein in the rat may be
mediated by reduced hepatic lipid synthesis, as is the case for menhaden oil. 相似文献
13.
NH_3 Plasma Surface Treatments of Engineering Fluoropolymers: A Way to Enhance Adhesion of Ni or Cu Thin Films Deposited by Electroless Plating 总被引:4,自引:0,他引:4
FLUOROPOLYMERS(FPs)are thermoplasticmaterials which exhibit a number of unique chemicaland physical characteristics that no other man-madeplastic product gets together.For example,FPs showvery good resistance to almost all chemicals,excellentwater vapor barrier properties,high thermal stability,outstanding electrical insulation properties(lowdielectric constant and dissipation factors),extremelylow frictional coefficient giving them high auto-lubrication properties,high resistance to rad… 相似文献
14.
Katalin Friedl Gábor Ivanyos Miklos Santha Yves F. Verhoeven 《Theory of Computing Systems》2009,45(3):629-646
We present several results on the complexity of various forms of Sperner’s Lemma in the black-box model of computing. We give
a deterministic algorithm for Sperner problems over pseudo-manifolds of arbitrary dimension. The query complexity of our algorithm
is linear in the separation number of the skeleton graph of the manifold and the size of its boundary. As a corollary we get
an
deterministic query algorithm for the black-box version of the problem 2D-SPERNER, a well studied member of Papadimitriou’s complexity class PPAD. This upper bound matches the
deterministic lower bound of Crescenzi and Silvestri. The tightness of this bound was not known before. In another result
we prove for the same problem an
lower bound for its probabilistic, and an
lower bound for its quantum query complexity, showing that all these measures are polynomially related.
Research supported by the European Commission IST Integrated Project Qubit Application (QAP) 015848, the OTKA grants T42559
and T46234, and by the ANR Blanc AlgoQP grant of the French Research Ministry. 相似文献
15.
Jeanne Volatron Florent Carn Jelena Kolosnjaj‐Tabi Yasir Javed Quoc Lam Vuong Yves Gossuin Christine Ménager Nathalie Luciani Gaëlle Charron Miryana Hémadi Damien Alloyeau Florence Gazeau 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(2)
Proteins implicated in iron homeostasis are assumed to be also involved in the cellular processing of iron oxide nanoparticles. In this work, the role of an endogenous iron storage protein—namely the ferritin—is examined in the remediation and biodegradation of magnetic iron oxide nanoparticles. Previous in vivo studies suggest the intracellular transfer of the iron ions released during the degradation of nanoparticles to endogenous protein cages within lysosomal compartments. Here, the capacity of ferritin cages to accommodate and store the degradation products of nanoparticles is investigated in vitro in the physiological acidic environment of the lysosomes. Moreover, it is questioned whether ferritin proteins can play an active role in the degradation of the nanoparticles. The magnetic, colloidal, and structural follow‐up of iron oxide nanoparticles and proteins in lysosome‐like medium confirms the efficient remediation of potentially harmful iron ions generated by nanoparticles within ferritins. The presence of ferritins, however, delays the degradation of particles due to a complex colloidal behavior of the mixture in acidic medium. This study exemplifies the important implications of intracellular proteins in processes of degradation and metabolization of iron oxide nanoparticles. 相似文献
16.
Unraveling Unprecedented Charge Carrier Mobility through Structure Property Relationship of Four Isomers of Didodecyl[1]benzothieno[3,2‐b][1]benzothiophene 下载免费PDF全文
Yusuke Tsutsui Guillaume Schweicher Basab Chattopadhyay Tsuneaki Sakurai Jean‐Baptiste Arlin Christian Ruzié Almaz Aliev Artur Ciesielski Alan R. Kennedy Vincent Lemaur Yoann Olivier Rachid Hadji Lionel Sanguinet Frédéric Castet Silvio Osella Dmytro Dudenko David Beljonne Jérôme Cornil Paolo Samorì Shu Seki Yves H. Geerts 《Advanced materials (Deerfield Beach, Fla.)》2016,28(33):7106-7114
17.
In this study, a two-machine flowshop producing identical parts is considered. Each of the identical parts is assumed to require
a number of manufacturing operations, and the machines are assumed to be flexible enough to perform different operations.
Due to economical or technological constraints, some specific operations are preassigned to one of the machines. The remaining
operations, called flexible operations, can be performed on either one of the machines, so that the same flexible operation
can be performed on different machines for different parts. The problem is to determine the assignment of the flexible operations
to the machines for each part, with the objective of maximizing the throughput rate. We consider various cases regarding the
number of parts to be produced and the capacity of the buffer between the machines. We present solution methods for each variant
of the problem. 相似文献
18.
The subgraph isomorphism problem consists in deciding if there exists a copy of a pattern graph in a target graph. We introduce
in this paper a global constraint and an associated filtering algorithm to solve this problem within the context of constraint
programming. The main idea of the filtering algorithm is to label every node with respect to its relationships with other
nodes of the graph, and to define a partial order on these labels in order to express compatibility of labels for subgraph
isomorphism. This partial order over labels is used to filter domains. Labelings can also be strengthened by adding information
from the labels of neighbors. Such a strengthening can be applied iteratively until a fixpoint is reached. Practical experiments
illustrate that our new filtering approach is more effective on difficult instances of scale free graphs than state-of-the-art
algorithms and other constraint programming approaches. 相似文献
19.
Jordan Navarro Elsa Yousfi Jonathan Deniel Christophe Jallais Mercedes Bueno Alexandra Fort 《Ergonomics》2016,59(12):1553-1564
In the past, lane departure warnings (LDWs) were demonstrated to improve driving behaviours during lane departures but little is known about the effects of unreliable warnings. This experiment focused on the influence of false warnings alone or in combination with missed warnings and warning onset on assistance effectiveness and acceptance. Two assistance unreliability levels (33 and 17%) and two warning onsets (partial and full lane departure) were manipulated in order to investigate interaction. Results showed that assistance, regardless unreliability levels and warning onsets, improved driving behaviours during lane departure episodes and outside of these episodes by favouring better lane-keeping performances. Full lane departure and highly unreliable warnings, however, reduced assistance efficiency. Drivers’ assistance acceptance was better for the most reliable warnings and for the subsequent warnings. The data indicate that imperfect LDWs (false warnings or false and missed warnings) further improve driving behaviours compared to no assistance.
Practitioner Summary: This study revealed that imperfect lane departure warnings are able to significantly improve driving performances and that warning onset is a key element for assistance effectiveness and acceptance. The conclusion may be of particular interest for lane departure warning designers. 相似文献
20.
François Galasso Yves Ducq Matthieu Lauras Didier Gourc Mamadou Camara 《Journal of Intelligent Manufacturing》2016,27(1):217-229
Enterprise applications and software systems need to be interoperable in order to achieve seamless business across organizational boundaries and thus realize virtual networked organizations. Our proposition can be considered as an interoperability project selection approach and is based on three steps: (1) Modelling both collaborative business processes and potential related interoperability projects; (2) Evaluating the accessibility of each project regarding the current state of the organization; (3) Simulating each project and assessing the associated performance. These results are finally projected on a comparison matrix used as a decision support to select the most appropriate interoperability solution. An application case extracted from the French aerospace sector demonstrates the applicability and the benefits of the proposition. 相似文献