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111.
Hazrat Ali Azim Khan Tauqeer Ahmad Athanasia Dervisi Ian Fallis Ibrahim O. Shoetan Abbas Khan Arshad Hussain Peter Griffiths 《Journal of surfactants and detergents》2022,25(3):341-350
Zwitterionic surfactants based on 3-(1-alkyl-3-imidazolio) propane-sulfonate ([ImS3-R] where R is octyl or dodecyl) is an emerging and important class of amphiphile due to their relevance as nano reactors for the synthesis of metallic nanoparticles and accelerated acid hydrolysis. The physicochemical properties of such synthesized imidazolium ring-containing zwitterionic surfactants have been characterized by surface tension and small-angle neutron scattering (SANS) techniques. Surface tension measurements were used to calculate several thermodynamic parameters over a range of concentrations and temperatures (298–313 K). The results obtained showed a weak signature representing the critical micelle concentration (CMC) for ImS3-8, however, by increasing the alkyl length of the hydrophobic group to dodecyl, that is, ImS3-8 to ImS3-12, the signature of the CMC was much more evident. As expected, the CMC for ImS3-12 shifted to a lower concentration. An increase in temperature increased the surface activity and decreased the CMC of both zwitterionic surfactants, although the changes were small. Compared to classical surfactants, that is, sodium dodecyl sulfate and dodecyl trimethylammonium bromide, the CMC of ImS3-12 is much lower. Modeling of SANS data demonstrated that the morphology of the micelles formed by these amphiphiles may be described by the “classical” model, a central hydrophobic core, with a shell of hydrated headgroups. Due to their widespread applications in colloidal and interfacial science, the present study adds new insight to the fundamental understanding of these interesting imidazolium-based surface-active ionic liquids (ImS3-R). 相似文献
112.
Farman Muhammad Nawaz Fahim Majeed Sadia Javeed Hafiz Muhammad Rashad Ahsan Muhammad Ahmad Khawaja Shafique Aurangzaib Muhammad Bukhari Muhammad Adnan Shehzad Muhammad Asif Hussain Muhammad Baqir 《SILICON》2022,14(13):7901-7917
Silicon - The present study evaluated the effect of silicon (Si) seed priming and sulfur (S) foliar spray on drought tolerance of two contrasting maize hybrids viz. drought tolerant Hi-Corn 11 and... 相似文献
113.
Laraib A. Khan Ayesha Kausar Syed Tajammul Hussain Zafar Iqbal Richard J. Day Ahmed Shuja Syed Zaffar M. Khan 《Polymer Engineering and Science》2014,54(4):887-898
In this effort, Quickstep, a relatively a new technique, have been employed for manufacturing of composite materials. The cure schedule provided by a prepreg manufacturer is usually designed for autoclave or other traditional processing techniques and thermosetting resin systems are formulated for ramp rate curing 2–3 K min?1. While in case of Quickstep processing, ramp rates of 15 K min?1 can be achieved, thus changing the chemorheology of resin. The cure process of 977‐2A carbon/epoxy composites was evaluated for Quickstep processing using differential scanning calorimetry (DSC), dynamic mechanical and thermal analysis, and Fourier transformed infrared and results were compared with cure cycle employed for autoclave curing. Optimum hold time for Quickstep processing at upper curing temperature (180°C) was determined using DSC. The hold time of 120 min at 180°C was found to be suitable for Quickstep cure cycle, producing a panel of similar degree of cure to that achieved through autoclave processing schedule. Final degree of cure was dependent on time spent at upper cure temperature and slightly on initial steps of the cure cycle which was used to control the resin flow, fiber wetting, and void removal. Quickstep processed samples exhibited higher Tg and crosslink density and similar molecular network structure to the autoclave cured samples. POLYM. ENG. SCI., 54:887–898, 2014. © 2013 Society of Plastics Engineers 相似文献
114.
Mohammad Anwar Hosen Mohd Azlan Hussain Farouq Sabri Mjalli Abbas Khosravi Douglas Creighton Saeid Nahavandi 《Chemical Engineering Research and Design》2014
The performances of three advanced non-linear controllers are analyzed for the optimal set point tracking of styrene free radical polymerization (FRP) in batch reactors. The three controllers are the artificial neural network-based MPC (NN-MPC), the artificial fuzzy logic controller (FLC) as well as the generic model controller (GMC). A recently developed hybrid model (Hosen et al., 2011a. Asia-Pac. J. Chem. Eng. 6(2), 274) is utilized in the control study to design and tune the proposed controllers. The optimal minimum temperature profiles are determined using the Hamiltonian maximum principle. Different types of disturbances are introduced and applied to examine the stability of controller performance. The experimental studies revealed that the performance of the NN-MPC is superior to that of FLC and GMC. 相似文献
115.
Planktonic, epipelic and epiphytic algae were studied monthly, during the period from January to December 1985 in the Garmat ali river, a naturally regulated river draining to the al-Hammar marsh, Iraq. Chlorophyll-a, primary productivity and water quality variables were also measured. High light penetration was noticed during the winter and spring. The water is oligohaline, alkaline and very hard. Reactive nitrate was found in higher concentrations than nitrite, and there were low concentrations of reactive phosphate. Two peaks were noticed for chlorophyll-a concentrations during spring and autumn, whereas only one occurred during autumn for primary productivity. The study area may be characterized as typically mesotrophic. A total of 154 species of algae was identified, including 65, 89, 98 and 77 species of plankton, epipelic and epiphytic algae on Potamogeton lucens and on Ceratophyllum demersum, respectively. Only 25 species were common to all the different communities. Diatoms were the dominant group in the epipelic and epiphytic algae during the study period, as well as in the plankton during spring and autumn. Seasonal variations were clear in the total cell numbers of algae from different habitats. 相似文献
116.
117.
Goli Nagaraju SChandra Sekhar Bhimanaboina Ramulu SkKhaja Hussain DNarsimulu Jae Su Yu 《纳微快报(英文)》2021,(1):319-336
Designing rationally combined metal-organic frameworks(MOFs)with multifunctional nanogeometries is of significant research interest to enable the electrochemical properties in advanced energy storage devices.Herein,we explored a new class of binderfree dual-layered Ni-Co-Mn-based MOFs(NCM-based MOFs)with three-dimensional(3D)-on-2D nanoarchitectures through a polarityinduced solution-phase method for high-performance supercapatteries.The hierarchical NCM-based MOFs having grown on nickel foam exhibit a battery-type charge storage mechanism with superior areal capacity(1311.4μAh cm^−2 at 5 mA cm^−2),good rate capability(61.8%;811.67μAh cm^−2 at 50 mA cm^−2),and an excellent cycling durability.The superior charge storage properties are ascribed to the synergistic features,higher accessible active sites of dual-layered nanogeometries,and exalted redox chemistry of multi metallic guest species,respectively.The bilayered NCM-based MOFs are further employed as a battery-type electrode for the fabrication of supercapattery paradigm with biomass-derived nitrogen/oxygen doped porous carbon as a negative electrode,which demonstrates excellent capacity of 1.6 mAh cm^−2 along with high energy and power densities of 1.21 mWh cm^−2 and 32.49 mW cm^−2,respectively.Following,the MOF-based supercapattery was further assembled with a renewable solar power harvester to use as a self-charging station for various portable electronic applications. 相似文献
118.
Uzma Arif Nawaz M. Rana Shafia Qureshi Imran Haider Elmasry Yasser Hussain Shafiq 《Theoretical Foundations of Chemical Engineering》2020,54(6):1327-1339
Theoretical Foundations of Chemical Engineering - In this study, the simulations for first-order chemical reactions (constructive and destructive) in the flow of the Casson fluid with... 相似文献
119.
Rou Wan Arif Hussain Atta Behfar Steven L. Moran Chunfeng Zhao 《International journal of molecular sciences》2022,23(7)
Soft tissue defects are common following trauma and tumor extirpation. These injuries can result in poor functional recovery and lead to a diminished quality of life. The healing of skin and muscle is a complex process that, at present, leads to incomplete recovery and scarring. Regenerative medicine may offer the opportunity to improve the healing process and functional outcomes. Barriers to regenerative strategies have included cost, regulatory hurdles, and the need for cell-based therapies. In recent years, exosomes, or extracellular vesicles, have gained tremendous attention in the field of soft tissue repair and regeneration. These nanosized extracellular particles (30–140 nm) can break the cellular boundaries, as well as facilitate intracellular signal delivery in various regenerative physiologic and pathologic processes. Existing studies have established the potential of exosomes in regenerating tendons, skeletal muscles, and peripheral nerves through different mechanisms, including promoting myogenesis, increasing tenocyte differentiation and enhancing neurite outgrowth, and the proliferation of Schwann cells. These exosomes can be stored for immediate use in the operating room, and can be produced cost efficiently. In this article, we critically review the current advances of exosomes in soft tissue (tendons, skeletal muscles, and peripheral nerves) healing. Additionally, new directions for clinical applications in the future will be discussed. 相似文献