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排序方式: 共有2119条查询结果,搜索用时 46 毫秒
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Muhammad Ashraf Bajeer Muhammad Ali Mallah Syed Tufail Hussain Sherazi Muhammad Iqbal Bhanger Shafi Muhammad Nizamani 《Polycyclic Aromatic Compounds》2016,36(3):229-241
This study concerns the investigation of dissipation, adsorption, and degradation of triazophos in different soils from Pakistan. These processes help in the disappearance of pesticide from the environment. Gas chromatography was used for dissipation and adsorption analysis while for degradation study mass spectrometer was used in addition of gas chromatography (GC-MS). The dissipation rate of triazophos in three different soils was 90% over 30 days with average half-life of 9.059 days. From dissipation study it was inferred that rate is variable in each soil due to climatic changes, soil nature and soil-pesticide interactions. Adsorption experiment has revealed that the adsorption of this pesticide to soil follows the pseudo first order kinetic model with rate constant value of 0.479/h and Freundlich isotherm with adsorption capacity of 1.832 mol/g. Degradation study has displayed two major metabolites, one is phosphorothioic acid, S-[2-[(1-cyano-1-methylethyl) amino]-2-oxoethyl] O,O-diethyl ester at retention time of 9.136 and the other is sulfotep at 14.304 min. The leaching potential of triazophos was also calculated from its half-life and organic carbon content present in soil which was 1.688 representing it as non leacher pesticide. 相似文献
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D. V. Modenov V. N. Dokutovich V. A. Khokhlov B. D. Antonov V. A. Kochedykov I. D. Zakir’yanova 《Russian Metallurgy (Metally)》2013,2013(2):86-89
A new method for the synthesis of lithium cobaltate LiCoo2 in salt melts is proposed and tested. The method is based on the oxidation of halide ions with molecular oxygen in LiX-CoCl2 mixtures (X = Cl, Br, I). The chemical and phase compositions of the prepared powders and the crystal structure of the synthesized compound are studied by Fourier transform infrared spectroscopy and X-ray diffraction analysis. The average size of LiCoO2 crystallites is estimated from the X-ray diffraction data. 相似文献
87.
A multi‐objective evolutionary optimization of fuzzy controller for energy conservation in air conditioning systems 下载免费PDF全文
This paper presents the use of evolutionary optimization approach to design and tune smart fuzzy controllers for heating, ventilation, and air conditioning systems or HVAC. The objective is to optimize energy consumption while accounting for user comfort requirements. The problem of energy conservation in air conditioning systems becomes a multi‐objective optimization constrained problem, which enlarges the solution search space. To solve this problem, a multi‐objective evolutionary optimization technique based on genetic algorithm (GA) is proposed. A physical experimental setup is constructed for data collection and formulation of mathematical model. A fuzzy controller is initially designed through expert knowledge, and GA is then used to tune the rules and membership functions of the fuzzy controller in order to optimize multiple objectives. Simulations and real experiments are compared to determine the effectiveness of the proposed strategy. As compared to the controller present in the real experimental air conditioner, approximately 15% energy is successfully saved with no increase in average individual dissatisfaction or discomfort index. Also, a decrease in peak individual dissatisfaction or discomfort index from 91% to 62% is observed. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
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In a recent paper by Zhang et al. in 2012, a Mach number-invariant scaling was proposed to account for the effect of variation of free-stream Mach number in supersonic turbulent boundary layers. The present work focuses on the effect of variation of wall temperature with strong heating and cooling at the wall. Direct numerical simulation is used to study scaling and turbulence structure of a spatially evolving Mach 2 supersonic boundary layer at a friction Reynolds number of 500. A new scaling law is proposed to account for temperature-dependent fluid-property variations. This universal scaling appears superior to the existing models with the novelty that it applies not only for the mean-velocity profile but also extends to the turbulent transport, production, and dissipation terms in the budget of the turbulent kinetic energy. 相似文献
89.
The effective tire-pavement contact area affects the relative damage of asphalt pavement and should be incorporated in both mechanistic and empirical response analyses of pavements. A new machine called ROTOCOM Wheel Tracker (RCWT) was designed and fabricated to capture the effective tire contact area apart from slab compacting, and conducting simulative laboratory wheel tracking tests. The main focus of this paper is laboratory measurement of effective tire contact areas for various tread patterns. Seven tire treads were selected for the footprint image analyses at five tire loads and four tire inflation pressures. An image processing MATLAB-based program was coded to calculate the contact areas of the 280 imprints obtained from both sides of the RCWT. Factorial analysis indicated significant effects of tire tread, tire load, and inflation pressure on the resulting contact area. Comparison between effective and traditional contact areas indicated that the current pavement design procedure with traditional circular contact area extremely overestimates the actual tire-pavement contact area up to 92%. 相似文献
90.
Enhancement of electroconductivity of polyaniline/graphene oxide nanocomposites through in situ emulsion polymerization 总被引:1,自引:0,他引:1
Syed Muhammad Imran YouNa Kim Godlisten N. Shao Manwar Hussain Yong-ho Choa Hee Taik Kim 《Journal of Materials Science》2014,49(3):1328-1335
The present study introduces a systematic approach to disperse graphene oxide (GO) during emulsion polymerization (EP) of Polyaniline (PANI) to form nanocomposites with improved electrical conductivities. PANI/GO samples were fabricated by loading different weight percents (wt%) of GO through modified in situ EP of the aniline monomer. The polymerization process was carried out in the presence of a functionalized protonic acid such as dodecyl benzene sulfonic acid, which acts both as an emulsifier and protonating agent. The microstructure of the PANI/GO nanocomposites was studied by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, UV–Vis spectrometry, Fourier transform infrared, differential thermal, and thermogravimetric analyses. The formed nanocomposites exhibited superior morphology and thermal stability. Meanwhile, the electrical conductivities of the nanocomposite pellets pressed at different applied pressures were determined using the four-probe analyzer. It was observed that the addition of GO was an essential component to improving the thermal stability and electrical conductivities of the PANI/GO nanocomposites. The electrical conductivities of the nanocomposites were considerably enhanced as compared to those of the individual PANI samples pressed at the same pressures. An enhanced conductivity of 474 S/m was observed at 5 wt% GO loading and an applied pressure of 6 t. Therefore, PANI/GO composites with desirable properties for various semiconductor applications can be obtained by in situ addition of GO during the polymerization process. 相似文献