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131.
Propagation of a crack from the tensile face of a beam causes postpeak softening, i.e., the bending moment decreases at increasing rotation of the hinge. Examples are unreinforced concrete beams and plates, foundations plinths, retaining walls, tunnel linings, or arch dams. Softening in an inelastic hinge is also caused by compression crushing of concrete. This happens in reinforced concrete beams that are prestressed, overreinforced, retrofitted by laminates, or subjected to a large enough axial compressive force, which is typical of columns as well as frames or arches with a large enough horizontal thrust. Hinge softening may also be caused by plastic buckling of flanges in deep thin-wall steel beams. An inevitable consequence of inelastic hinge softening in statically indeterminate structures requiring more than one inelastic hinge to fail is a size effect. Although finite element solutions are possible, general analytical formulas for the size effect in such structures do not exist, because of the complexity of response. The idea of this two-part paper is to exploit the technique of asymptotic matching in order to derive approximate formulas for the entire size range. Exact analytical solutions of the nominal strength of structure are derived for the large-size asymptotic case, for which the hinges soften one by one rather than simultaneously, and for the small-size asymptotic case, for which the classical plastic limit analysis applies. Matching these asymptotic solutions by a smooth formula then yields simple, yet general, size effect laws for the peaks and troughs of the load-deflection diagram through the entire size range. The size effect found is very different from the classical size effect in quasibrittle structures failing due to a single dominant crack. The theory is developed in the present Part I, and analysis of its implications is relegated to Part II.  相似文献   
132.
The collapse of the World Trade Center towers was initiated by the impact of the upper falling part onto the underlying intact story. At the moment of impact, the velocity of the upper part must have decreased. The fact that no velocity decrease can be discerned in the videos of the early motion of the tower top has been recently exploited to claim that the collapse explanation generally accepted within the structural mechanics community was invalid. This claim is here shown to be groundless. Calculations show that the velocity drop is far too small to be perceptible in amateur video records and is much smaller than the inevitable error of such video records.  相似文献   
133.
Despite impressive advances, the existing constitutive and fracture models for fiber-reinforced concrete (FRC) are essentially limited to uniaxial loading. The microplane modeling approach, which has already been successful for concrete, rock, clay, sand, and foam, is shown capable of describing the nonlinear hardening–softening behavior and fracturing of FRC under not only uniaxial but also general multiaxial loading. The present work generalizes model M5 for concrete without fibers, the distinguishing feature of which is a series coupling of kinematically and statically constrained microplane systems. This feature allows simulating the evolution of dense narrow cracks of many orientations into wide cracks of one distinct orientation. The crack opening on a statically constrained microplane is used to determine the resistance of fibers normal to the microplane. An effective iterative algorithm suitable for each loading step of finite element analysis is developed, and a simple sequential procedure for identifying the model parameters from test data is formulated. The model allows a close match of published test data on uniaxial and multiaxial stress–strain curves, and on multiaxial failure envelopes.  相似文献   
134.
The size effect on structural strength is an important phenomenon with a very old history. Unfortunately, despite abundant experimental evidence, this phenomenon is still not taken into account in most specifications of the design codes for concrete structures, as well as the design practices for polymer composites, rock masses and timber. The main reason appears to be a controversy between two different theories of size effect, namely the theory based on energetic-statistical scaling and the theory based on ideas from fractal geometry. This paper aims to critically analyze these two theories, examine their hypotheses and point out the limitations, in order to help code-writing committees choose a rational basis for their work. The paper begins by reviewing the theory of energetic size effect and the efforts to explain the size effect by fractal geometry. The advantages and disadvantages in modeling the structural size effect by fractals are pointed out. Certain flaws in the fractal theory of size effect are illuminated and it is shown that various aspects of this theory lack a sound physical or mathematical basis, or both. The paper ends by recommending how engineering designers and code writers should take the size effect into account.  相似文献   
135.
The development of a model CNT-brittle matrix composite system, based on SiO2 glass containing well-dispersed CNTs at up to 15 wt%, allows a direct assessment of the effect of the nanoscale filler on fracture toughness (K IC). Samples were prepared by colloidal heterocoagulation followed by spark plasma sintering. Detailed K IC measurements, using both indentation and notched beam techniques, show a linear improvement with CNT content, with up to a twofold increase of fracture toughness at maximum loading. The results from the two methods used in this study show equivalent trends but differing absolute values; the relative merits of these two approaches to measuring nanocomposite toughness are compared. Possible toughening mechanisms associated with CNT pull-out, crack bridging, and crack deflection are identified, and discussed quantitatively, drawing on conventional short-fibre composite theory and the potential effects of scaling fibre diameter.  相似文献   
136.
Summary Macrocyclic diamides 2, 3 and 4 of 4,4,5,5-tetramethyl-3,6-dioxaoctanedioic acid were prepared. These compounds incorporated in poly (vinyl chloride) membranes show a remarkable selectivity for lithium ions.  相似文献   
137.
Simple formulae for the components of the added-mass coefficient tensor of a sphere moving near a wall with variable velocity in an ideal fluid bounded by a solid surface are derived. The added mass is calculated numerically as a function of the dimensionless distance between the sphere and the wall for both perpendicular and parallel motions. The calculation is performed by the method of successive images. The velocity field is computed as the sum of the velocity fields of sequences of dipoles located along the axis. The obtained dependences of the added-mass tensor components are fitted by simple continuous functions with high accuracy.  相似文献   
138.
    
Photoactivation of aspartic acid-based carbon dots (Asp-CDs) induces the generation of spin-separated species, including electron/hole (e/h+) polarons and spin-coupled triplet states, as uniquely confirmed by the light-induced electron paramagnetic resonance spectroscopy. The relative population of the e/h+ pairs and triplet species depends on the solvent polarity, featuring a substantial stabilization of the triplet state in a non-polar environment (benzene). The electronic properties of the photoexcited Asp-CDs emerge from their spatial organization being interpreted as multi-layer assemblies containing a hydrophobic carbonaceous core and a hydrophilic oxygen and nitrogen functionalized surface. The system properties are dissected theoretically by density functional theory in combination with molecular dynamics simulations on quasi-spherical assemblies of size-variant flakelike model systems, revealing the importance of size dependence and interlayer effects. The formation of the spin-separated states in Asp-CDs enables the photoproduction of hydrogen peroxide (H2O2) from water and water/2-propanol mixture via a water oxidation reaction.  相似文献   
139.
    
Considerable improvements in the electrocatalytic activity of 2D metal phosphorous trichalcogenides (M2P2X6) have been achieved for water electrolysis, mostly with MII2[P2X6]4− as catalysts for hydrogen evolution reaction (HER). Herein, MIMIIIP2S6 (MI = Cu, Ag; MIII = Sc, V, Cr, In) are synthesized and tested for the first time as electrocatalysts in alkaline media, towards oxygen reduction reaction (ORR) and HER. AgScP2S6 follows a 4 e pathway for the ORR at 0.74 V versus reversible hydrogen electrode; CuScP2S6 is active for HER, exhibiting an overpotential of 407 mV and a Tafel slope of 90 mV dec−1. Density functional theory models reveal that bulk AgScP2S6 and CuScP2S6 are both semiconductors with computed bandgaps of 2.42 and 2.23 eV, respectively and overall similar electronic properties. Besides composition, the largest difference in both materials is in their molecular structure, as Ag atoms sit at the midpoint of each layer alongside Sc atoms, while Cu atoms are raised to a similar height to S atoms, in the external segment of the 2D layers. This structural difference probably plays a fundamental role in the different catalytic performances of these materials. These findings show that MI(Cu, Ag) together with Sc(MIII) leads to promising achievements in MIMIIIP2S6 materials as electrocatalysts.  相似文献   
140.
    
Bulletin of Engineering Geology and the Environment - The alkali silica reaction (ASR), which originates in highly alkaline conditions in concrete where reactive forms of silica are available,...  相似文献   
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