Size effect on compression strength of fiber composites failing by kink band propagation

The effect of structure size on the nominal strength of unidirectional fiber-polymer composites, failing by propagation of a kink band with fiber microbuckling, is analyzed experimentally and theoretically. Tests of novel geometrically similar carbon–PEEK specimens, with notches slanted so as to lead to a pure kink band (not accompanied by shear or splitting cracks), are conducted. They confirm the possibility of stable growth of long kind bands before the peak load, and reveal the existence of a strong (deterministic, non-statistical) size effect. The bi-logarithmic plot of the nominal strength (load divided by size and thickness) versus the characteristic size agrees with the approximate size effect law proposed for quasibrittle failures in 1983 by Bažant. The plot exhibits a gradual transition from a horizontal asymptote, representing the case of no size effect (characteristic of plasticity or strength criteria), to an asymptote of slope -1/2 (characteristic of linear elastic fracture mechanics, LEFM). A new derivation of this law by approximate (asymptotically correct) J-integral analysis of the energy release, as well as by the recently proposed nonlocal fracture mechanics, is given. The size effect law is further generalized to notch-free specimens attaining the maximum load after a stable growth of a kink band transmitting a uniform residual stress, and the generalized law is verified by Soutis, Curtis and Fleck's recent compression tests of specimens with holes of different diameters. The nominal strength of specimens failing at the initiation of a kink band from a smooth surface is predicted to also exhibit a (deterministic) size effect if there is a nonzero stress gradient at the surface. A different size effect law is derived for this case by analyzing the stress redistribution. The size effect law for notched specimens permits the fracture energy of the kink band and the length of the fracture process zone at the front of the band to be identified solely from the measurements of maximum loads. The results indicate that the current design practice, which relies on the strength criteria or plasticity and thus inevitably misses the size effect, is acceptable only for small structural parts and, in the interest of safety, should be revised in the case of large structural parts. This revised version was published online in July 2006 with corrections to the Cover Date.     

Swelling of acrylic microgels in aliphatic ketones

The paper deals with the swelling behaviour of hydroxyl-functionalised microgels in the presence of aliphatic ketones. The copolymer microgels with different cross-linking densities were synthesized by the semi-batch emulsion copolymerisation of methyl methacrylate, butyl methacrylate, 2-hydroxyethyl methacrylate and allyl methacrylate. The extent of microgel particles swelling was evaluated using the dynamic light scattering, the potentiometric titration of accessible hydroxyl groups and the solvent-uptake measurements. It was found that the swelling ability of microgels decreased with growing degree of cross-linking. Microgels comprising copolymerised butyl methacrylate swelled less in utilised aliphatic ketones than microgels without this comonomer. Among all the investigated solvents, acetone was found to be the strongest solvent, while 5-methyl-2-hexanone (methyl isopentyl ketone) was shown to be the weakest one. Further, the microgels were investigated as reactive network precursors in a commercial thermosetting solvent-borne acrylic binder. It was shown that the application of functionalised microgels that were redispersed in acetone did not affect the surface appearance and transparency of coatings. Moreover, the presence of microgel network precursors accelerated film curing at ambient temperature and improved final hardness of coatings.     

RBS, XPS, and TEM study of metal and polymer interface modified by plasma treatment

We performed a study of the diffusion of Ag and Au atoms in polyethyleneterephtalate (PET). Thin metal layers were deposited using a diode-sputtering technique on polymer foils at room temperature. Simultaneous post-deposition annealing and plasma treatments were used to induce metal-polymer intermixing. Rutherford back-scattering spectrometry and X-ray photoelectron spectroscopy were used to determine the integral amount of metal and chemical structure in the surface layer. After plasma treatment Ag thin films exhibit dramatic changes of chemical composition and an integral amount of metal compared to Au thin films. Transmission Electron Microscopy shows the differences in the size and the depth distribution of metal particles, depending on the annealing temperature at the metal-polymer interface.     

NO – oxygen scavenger or reaction intermediate in the decomposition of N2O?

Nitric oxide and nitrogen dioxide were found during the thermal desorption of surface species left on Fe-ferrierites after the decomposition of nitrous oxide. This demonstrates the formation of surface NOx species during N₂O decomposition. Repeated decomposition and subsequent desorption of surface species confirm the active role of surface NOx species. Addition of NO up to a fraction of 0.1 times the amount of N₂O increased the decomposition of nitrous oxide as well as the amount of surface NOx species. The use of nitrous oxide labeled with ¹⁸O demonstrated that the zeolite oxygens participate in the reaction and that the presence of NO enhances this participation.     

Temperature of connections during fire on steel framed building

To study the global structural and thermal behaviour of buildings in fire, a research project was conducted including a fullscale test on a three storey steel frame building at Mittal Steel Ostrava before demolition. The main goal of the experiment was to verify the method for predicting joint temperatures and to improve it for the cooling phase. The fire compartment extending over a floor area of 24 m² was built on the second floor. The fire load was 140 kg/m² of wood and the ventilation was limited to an opening of 1,400 × 1,970 mm. This paper presents the time-temperature curves showing the development of the fire in the compartment and in the primary and secondary beams and its header plate connections. Comparisons are made between the test results and the temperatures predicted by the structural Eurocodes. The sensitivity of the connection behaviour to the estimated temperatures and associated degradation in material properties during the fire is demonstrated.     

Ternary polymer electrolytes with 1-methylimidazole based ionic liquids and aprotic solvents

New polymer gel electrolytes containing ionic liquids were developed for modern chemical power sources—supercapacitors and lithium-ion batteries. Ternary systems polymer-ionic liquid-aprotic solvent as well as materials containing also lithium salts (LiClO₄ or LiPF₆) were prepared by direct, thermally initiated polymerisation. Poly(2-ethoxyethyl methacrylate) PEOEMA was combined with various ionic liquids based on 1-methylimidazole. Only 1-butyl-3-methylimidazolium hexafluorophosphate BMIPF₆ formed a homogenous and slightly translucent polymer electrolyte, where aprotic solvents—propylene carbonate and ethylene carbonates were used as plasticisers. Materials were studied using the electrochemical and thermogravimetric methods and exhibit high ionic conductivity up to 0.94 mS cm⁻¹ at 25 °C together with high electrochemical stability: the accessible potential window on the glassy carbon was found ca. 4.3 V. Prepared non-volatile materials are long-term and thermally stable up to 150 °C.