浅析原子荧光法测定水中汞

介绍了用原子荧光光度计测定水中汞的方法。对检测结果进行分析,发现相较于双硫腙分光光度法和冷原子吸收法测定汞,荧光法有快速、简便、灵敏度高、干扰少、线性范围宽、检测限低等优点。     

液压支架矸石充填捣实机构的结构分析

矸石充填是当前煤矿生产中常用的一种充填方式,用于液压支架后部的矸石捣实机构是充填工作的关键设备。矸石捣实机构有单级捣实机构和双级捣实机构,其支撑方式有下部推拉及上部吊挂等多种形式。根据现场使用经验,对结构进行了分析,并对充填开采方法提出一点建议。     

Formation of TiC hexagonal platelets and their growth mechanism

A large amount of TiC hexagonal platelets has formed on the surface of the sample made of Ti/Si/TiC/Al_0.2 after sintering at above 1450 °C in an Ar atmosphere. The basal plane of TiC platelets is (111) facet confirmed by X-ray diffraction. Small amounts of Si and Al elements dissolved in the TiC crystal structure, influencing the structure of TiC. The detailed structure and growth mechanism of the TiC platelets have been observed and analyzed. A model has been proposed to understand the formation of TiC hexagonal platelets.     

Novel methods for synthesis of high‐impact polystyrene with bimodal distribution of rubber particle size

By using in situ prepolymerization and radiation curing, high‐impact polystyrene (HIPS) with a bimodal distribution of the size of the rubber particles (bimodal HIPS) was synthesized in the presence of ultrafine full‐vulcanized powdered styrene–butadiene rubber (UFPSBR) and polybutadiene rubber (BR). TEM photographs indicated that UFPSBR was dispersed uniformly as a single particle with a diameter of about 100 nm. On the other hand, bimodal HIPS with different rubber particle size distributions could also be obtained by blending HIPS and UFPSBR grafting styrene (UFPSBR‐g‐St) with different grafting yields. The bimodal HIPS with the smallest rubber particle size, at about 100 nm, could be prepared by blending the monomodal HIPS containing big rubber particles with polystyrene/UFPSBR. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Comparative study of three lignin fractions isolated from mild ball‐milled Tamarix austromogoliac and Caragana sepium

Six lignin fractions from mild ball‐milled Tamarix austromogoliac (TA) and Caragana sepium (CS) were sequentially isolated with 80% dioxane containing 0.05M HCl at 75°C for 4 h, 50% aqueous ethanol containing 1M triethylamine at 70°C for 4 h, and 8% aqueous NaOH at 45°C for 3 h. The results showed that the successive treatments made it possible to isolate lignin from wood with a high yield and purity, in which 89.4 and 90.6% of the original lignin from TA and CS were released, respectively. The lignin fractions isolated with the three‐step method were analyzed with Fourier transform infrared, ¹H‐ and ¹³C‐NMR, alkaline nitrobenzene oxidation, and gel permeation chromatography. It was found that the three lignin fractions isolated from TA were rich in syringyl units, and the molar ratio of the relatively total moles of vanillin, vanillic acid, and acetovanillin to the relatively total moles of syringaldehyde, syringic acid, and acetosyringone decreased from 1: 2.6 to 1 : 3.2 to 1: 3.6 in the lignin preparations, whereas this ratio in the corresponding lignin fractions isolated from CS was found to be 1.4 : 1, 1.1 : 1, and 1 : 1.4, respectively. More importantly, the results revealed that the sequential extractions of the mild ball‐milled TA and CS with 80% acidic dioxane, 50% alkaline ethanol, and 8% aqueous NaOH under the conditions used did not significantly cleave the β–O‐4 and α–O‐4 linkages in lignin macromolecules. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

彩涂卷钢涂层厚度对耐老化性能的影响

分析了目前国内外彩涂卷钢市场需求的现状,通过紫外人工加速老化试验,从涂层表面光泽保持率、色差以及表面粉化、开裂的角度,着重研究了彩板的不同面漆涂层厚度对彩板耐老化等相关性能的影响.用减薄涂层来降低彩板生产成本的方法,必然带来严重的质昔问题.     

茶树油的分子蒸馏精制及其GC/MS分析

利用新型、特殊分离技术——分子蒸馏对茶树油进行精制,并对精制后的茶树油进行GC/MS定性分析及其总离子流图的面积归一法定量分析。结果从粗茶树油中分离出了61种化合物,鉴定出36种组分,占总量的98.67%,其中4-松油醇高达49.56%,并且精制的茶树油符合国际标准(ISO 4730-1996)。     

Electrochemical behavior of magnesium alloys AZ91D,AZCe2, and AZLa1 in chloride and sulfate solutions

The influence of Cl⁻ and SO₄²⁻ on the electrochemical behavior of AZ91D, AZCe2, and AZLa1 was studied. For all alloys, there was a current plateau in the anodic polarization curves in Na₂SO₄ solutions. In 0.5% NaCl solution, there was a small current plateau, whereas there was none in the 3.5% and 5% NaCl solutions. This indicated that SO₄²⁻ is less aggressive than Cl⁻. The range of the current plateau decreased with increasing SO₄²⁻ concentration. For all alloys, the high frequency capacitive loop in the Nyquist plots decreased with increasing concentration consistent with the decrease in corrosion resistance with increasing Cl⁻ and SO₄²⁻ concentration.     

ZrO2颗粒对Si3N4/SiO2陶瓷复合材料性能的影响

通过加入ZrO2颗粒作为增强相,利用ZrO2的相变微裂纹增韧来改善Si2M4/SiO2陶瓷材料的力学性能.当ZrO2含量为15%时,材料的抗弯强度最高,达194.8 MPa.     

因势利导 疏管结合——淄博市“美食街”地段影响流动商贩分布的因素研究

该文从实地调查淄博市“美食街”地段中的流动商贩入手,对流动商贩的经营商品和辅助工具的种类、地段中的用地性质、消费者购买路线、地段中的道路宽度四个影响流动商贩分布的因素进行了研究和分析,从而寻找和总结出流动商贩存在的必要性以及其在哪些层面影响了我们的城市,以便对流动商贩提出合理的规划布局原则和人性化的管理建议。