Study on esterification of acrylic phenolic resin by maleic anhydride and photocrosslinking properties of the alkali‐soluble product

An alkali‐soluble, photocrosslinkable polymer was synthesized by esterification of OH groups of acrylic phenolic resin with maleic anhydride. The OH groups were formed by the ring‐opening reaction of epoxy groups of epoxy phenolic resin with acrylic acid. The esterification conditions were studied. The results showed that it is better to use tetramethyl ammonium bromide as catalyst than N,N‐dimethylbenzylamine. The conversion of maleic anhydride in acetone can reach about 80% at 56°C for 4 h. The purified product was characterized by IR, DSC, and TGA. The product containing acrylate and maleic acid monoester groups, above a certain content, can be dissolved in 1% Na₂CO₃ solution. The photocrosslinkable properties of the product were investigated through selection of photoinitiator, accelarator, crosslinkable diluent monomer, etc. The acrylate and maleic acid monoester group‐containing phenolic resin exhibited very good photocrosslinking behavior, since it contains double bonds from both acrylate groups and maleic acid monoester groups. The activity of photoinitiator decreases in the order: isopropylthioanthraquinone > benzoin ethyl ether (BE) > anthraquinone (AQ) > benzophenone > Michel ketone (MK) > 2,2‐diethoxyacetophenone. The combination of some photoinitiators showed synergistic effects. The order of increasing activity for the accelerator is as follows: MK > ethyl p‐(dimethylamino)benzoate > N,N‐dimethylaniline > triethanolamine. The optimum diluent monomer is trimethylolpropane trimethacrylate. The gel content of the mixture of the resin and trimethylolpropane trimethacrylate could reach 85% using the combined photoinitiators of BE and AQ under UV exposure for 120 s. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 1607–1614, 2005     

提高φ5m×11.5m生料磨产量的措施

针对粘土资源枯竭问题,江苏巨龙水泥集团实施了以粉煤灰和硅石代替粘土的技改工程。但改造后因原料的变更,导致入房物料易磨性变差而影响了φ5m×11.5m生料磨的产质量,并进一步影响察系统的运行。因此该厂在工艺分析的基础上,采取了调整钢球级配、用高铬球替代合金刚球、改造选粉机、加强石灰石二破的管理和减少系统是否是“漏风”等技术措施,效果显著。改造后的生料磨台时产量比调整前提高了12t/h,且节电效果显著。     

Surface Modification of Titania Nanoparticles Using Ultrathin Ceramic Films

Surface modification of titania nanoparticles was achieved by coating them with ultrathin alumina films using atomic layer deposition. The coating process was performed in a fluidized bed reactor at low pressure and under mechanical vibration. Films were deposited using self-limiting, sequential surface reactions of trimethylaluminum and water. The composition of alumina-coated particles was verified using infrared spectroscopy. The deposited films had an average growth rate of 0.2 nm/coating cycle and were highly uniform and conformal as demonstrated by transmission electron microscopy and X-ray spectroscopy. Deposited alumina films were amorphous as verified through X-ray diffraction and high-resolution electron microscopy. The coating process did not promote particle sintering as validated via particle size and surface area analysis.     

Preparation and properties of T300 carbon fiber‐reinforced thermoplastic polyimide composites

In this study, a series of T300 carbon fiber‐reinforced polyimide (CFRPI) composites were prepared by laminating premolding polyimide (PI) films with unidirectional carbon fiber (CF) layers. On the basis of PI systems design, the effect of CF volume fraction, processing conditions, and PI molecular structure on the properties of CFRPI composites was studied in detail. In addition, two kinds of nano‐particles, including carbon nano‐tube (CNT) and SiO₂ were filled into the premolding PI films with different concentrations. And the effect of nano‐particles on the properties of CFRPI composites was also investigated. The surface characteristic of T300 CF was measured by X‐ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR). The properties of premolding PI film and CFRPI composites were measured by dynamic mechanical analysis (DMTA), SANS testing machine, scanning electron microscopy (SEM), and so forth. These experimental results showed that the properties of CFRPI composites were mainly affected by the premolding PI film and molding condition. The change of CF volume fraction from 55% to 65% took little effect on the mechanical properties of CFRPI composites. In addition, the incorporation of nano‐particle SiO₂ could further improve the properties of CFRPI composites, but CNT hardly improved the properties of CFRPI composites. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 646–654, 2006     

千年前的求爱诗：震旦之恋·扶桑之情——《关雎》与《天皇御制歌》之比较研究

从主题、内容、形式结构、语言特色、视点、表现手法、诗歌风格等方面比较<关雎>与<天皇御制歌>的异同,探寻产生其异同的原因以及由此给日本文学发展带来的影响.     

化学教学与思想教育的融汇

本文阐述了在化学教学中要进行辩证唯物主义和爱国主义教育,要关注社会问题,要融汇政治思想教育。思想教育融汇在化学教学环节中首先要求我们对学生进行科学素养的培养;思想教育融汇在化学教学环节中要求我们的教学要与工农业生产相结合;思想教育融汇在化学教学环节中还要求我们的教学要与思想道德教育相结合,要与法制教育相结合;思想教育融汇在化学教学环节中还要求我们的教学要与现代教育技术相结合。     

A recognition method of vibration parameter image based on improved immune negative selection algorithm for rotating machinery

To overcome the limitations of traditional monitoring methods, based on vibration parameter image of rotating machinery, this paper presents an abnormality online monitoring method suitable for rotating machinery using the negative selection mechanism of biology immune system. This method uses techniques of biology clone and learning mechanism to improve the negative selection algorithm to generate detectors possessing different monitoring radius, covers the abnormality space effectively, and avoids such problems as the low efficiency of generating detectors, etc. The result of an example applying the presented monitoring method shows that this method can solve the difficulty of obtaining fault samples preferably and extract the turbine state character effectively, it also can detect abnormality by causing various fault of the turbine and obtain the degree of abnormality accurately. The exact monitoring precision of abnormality indicates that this method is feasible and has better on-line quality, accuracy and robustness.     

地域性水系与人居环境的和谐发展——以威海石岛河景观改造工程为例

通过对山东威海石岛河的景观改造设计工作的分析,展示了如何在针对水系的景观设计工作中解决自然生态保护与人居环境之间的矛盾;在探索寻求人居生活环境与自然生态保护之间的平衡点方面进行了初步的研究.总结了对于地域性、区域性、功能性较强的水系进行景观设计时,围绕保护居民生命财产安全、保护自然环境、提高人居环境质量三方面内容而进行景观设计的一些经验和方法.     

高新技术公司的营销战略及案例分析

根据市场营销理论和公司经营战略,研究了高新技术公司营销的特点.通过对中国光谷高科技公司营销战略的实证分析,阐明了高科技公司在不同的时间和空间,面对不同的竞争对手,只有采取差异化营销策略,才能在市场中站稳脚跟和保持竞争优势.     

Theoretical investigation on cyclic reciprocal derivative chronopotentiometry: Kinetic study of totally irreversible electrode processes

Theoretical expressions and mathematical analysis in cyclic reciprocal derivative chronopotentiometry (CRDCP) are presented for totally irreversible electrode processes corresponding to the application of symmetrical and unsymmetrical programmed currents. For two successive unsymmetrical programmed currents, the effect of the currents ratio b (b = |I₂(t)/I₁(t)|) on the (dt/dE)–E curves is discussed. The electrochemical behavior of totally irreversible electrode processes has been studied corresponding to the application of the unique unsymmetrical programmed Φ^m(I₀) proposed recently. CRDCP characteristic parameters obtained for totally irreversible electrode processes are different from those of reversible electrode processes. Therefore, a comparison of CRDCP between both mechanisms is presented. Based on the mathematical derivation, alternative methods for kinetic measuring are described. It is prospected that CRDCP is convenient and applicable for studying the reversibility of the electrode processes in form of CRDCP characteristic parameters.