Simulation of Nonstationary Spring Discharge Using Time Series Models

We present a detailed analysis and comparison of two time series models, i.e., ARIMA and ARIMA-GARCH, to simulate the discharge of a karst spring (Niangziguan Springs (NS) complex) in the northern China. Statistical tests for the residuals are applied to examine the reasonability of the models. Statistically, both models are reasonably good to simulate the mean value of the discharge of the NS complex. The statistical test shows that the residual discharge data have conditional time-varying variance and volatility clustering, known as heteroscedasticity of the data. Calibration test shows that the ARIMA-GARCH model gives a varying confidence interval, which can more effectively capture the heteroscedasticity of the data, comparing with a constant confidence interval in the ARIMA model. In the validation and application process, we applied two approaches to simulate the discharge data: (1) fixed models, and (2) evolving models. The confidence interval width monotonically increases in both fixed models, and the fixed ARIMA-GARCH model has faster increasing confidence interval width than the fixed ARIMA model. This suggests that the fixed time series models are only suitable for short-term prediction. However, we found that this drawback can be compensated by updating the model once new data become available. Our evolving models show more reasonable confidence interval width for both models. In addition, the application shows that the ARIMA-GARCH model is very sensitive to the data fluctuation. We also found the evolving ARIMA-GARCH model was able to return to the narrow confidence interval width once the fluctuation diminished. Hence, we conclude that the ARIMA-GARCH model is more suitable for the sequences with strong heteroscedasticity.     

PEN/PTT共混聚酯的熔融行为

利用差示扫描量热仪对不同配比的聚萘二甲酸乙二醇酯/聚对苯二甲酸丙二醇酯(PEN/PTT)共混体系的熔融行为进行了分析,发现在共混体系中两组分形成各自的晶体,PEN和PTT的熔点均随另一组分含量的增加而下降。根据Nishi-Wang方程,按300℃计算,由PEN/PTT共混体系中PEN熔点下降计算所得到的相互作用能密度为-0．214 2 J/cm~3,相互作用参数为-0．006 8,表明PEN/PTY共混体系在熔融态是热力学性质稳定的相容体系。     

Racking focus and tracking focus on live video streams: a stereo solution

The ability to produce dynamic Depth of Field effects in live video streams was until recently a quality unique to movie cameras. In this paper, we present a computational camera solution coupled with real-time GPU processing to produce runtime dynamic Depth of Field effects. We first construct a hybrid-resolution stereo camera with a high-res/low-res camera pair. We recover a low-res disparity map of the scene using GPU-based Belief Propagation, and subsequently upsample it via fast Cross/Joint Bilateral Upsampling. With the recovered high-resolution disparity map, we warp the high-resolution video stream to nearby viewpoints to synthesize a light field toward the scene. We exploit parallel processing and atomic operations on the GPU to resolve visibility when multiple pixels warp to the same image location. Finally, we generate racking focus and tracking focus effects from the synthesized light field rendering. All processing stages are mapped onto NVIDIA’s CUDA architecture. Our system can produce racking and tracking focus effects for the resolution of 640×480 at 15 fps.     

双电层电容器用沥青焦基活性炭的制备工艺条件对其孔结构及电化学性能的影响

以沥青焦为原料，KOH为活化剂在不同的工艺条件下制备了双层电容器用活性炭电极材料。分别考察了活化剂用量、活化时间、以及加入Cu、Ni催化活化等工艺条件对活性炭孔结构及作为双电层电容器电极的电化学性能的影响。结果表明：在实验范围内增加KOH用量及活化时间，活性炭的比表面积和比电容增加，比电容最高达到247F／g。添加Cu、Ni催化活化后活性炭的比表面积及比电容增加，高功率放电性能明显改善。     

元明青花红绿彩的研究与考证

青花红绿彩作为加彩器的一种,比传统的观点早一个朝代,根据明中青花红绿彩盖罐结合最新的窑址考古成果,得出元代的窑炉设计和釉面配方的缺陷,使元代青花红绿彩的生产和存世极少,明官窑中由于斗彩的出现,青花红绿彩在民间一直沿烧。与元代风格相近,只是到了后期风格才大变。     

非晶态NiB配位催化2-亚丁基环己酮的选择加氢动力学研究

以超细非晶态NiB为催化剂、乙醇为溶剂 ,研究了常压条件下 2 -亚丁基环己酮的选择催化氢化反应。确定了反应对 2 -亚丁基环己酮的反应级数n =1,80℃下准一级反应的速率常数为k =3.4× 10 -3 min-1。同时考察了氢化过程中外扩散的影响以及温度、催化剂用量对反应的影响。求得反应的活化能Ea =16 .391kJ/mol。     

Two-dimensional bilinear preserving projections for image feature extraction and classification

Two-dimensional locality preserving projections (2DLPP) was recently proposed to extract features directly from image matrices based on locality preserving criterion. A significant drawback of 2DLPP is that it only works on one direction (left or right) to reduce the dimensionality of the image matrices and thus too many coefficients are needed for image representation in low-dimensional subspace. In this paper, we propose a novel method called two-dimensional bilinear preserving projections (2DBPP) for image feature extraction. We generalized the image-based (2D-based) feature extraction techniques into bilinear cases, in which 2DLPP is a special case of our proposed method. In order to obtain the bilinear projections, we proposed an iteration method by solving the corresponding generalized eigen-equations. Moreover, analyses show that 2DBPP has stronger locality preserving abilities than 2DLPP. By using the label information and defining different local neighborhood graphs, the proposed framework is further extended to supervised case. Experiments on three databases show that 2DBPP and its supervised extension are superior to some other image-based state-of-the-art techniques.     

高分子铁盐絮凝剂制备及其应用研究

研究了以废铁屑和工业硫酸亚铁为原料,在常压和加热条件下,用氯酸钾作为氧化剂制取聚合硫酸铁(PFS)的工艺条件,并在PFS制备的基础上,合成了聚磷硫酸铁(PPFS)和聚氯硫酸铁(PFCS)。将所制备的聚铁用于污水处理实验,结果表明:用该方法制备的聚铁絮凝剂对实际水样具有较好的混凝处理效果,且制备工艺简单、速度快,从根本上消除了用NaNO_2催化氧化法制备聚铁对环境造成的二次污染。     

The adsorption of dyes from aqueous solution using diatomite

Raw diatomite was calcined at 450 °C for dyes removal from aqueous solution. SEM and FTIR analysis show that the raw diatomite contains organic impurities, which are removed after the calcination. The impurities removal decreases the specific surface area and increases the average pore diameter of raw diatomite, while improves its adsorption capability of dyes. The adsorption isotherm and kinetics experiments of methylene blue onto calcined diatomite were then carried out to investigate the adsorption property. It shows that the adsorption capacity of methylene blue is about 50 mg/g. The adsorption isotherm was fitted by the Langmuir, Freundlich and Redlich-Peterson models, which reveals that the Redlich-Peterson isotherm is the best one. Two kinetic models, pseudo-first order and pseudo-second order, were rearranged for expediently investigating the adsortpion mechanisms. Fitting results show that the pseudo-first-order model is better in describing the adsorption process.     

邻氟苯甲腈的合成研究

以邻甲苯胺为原料 ,采用四步反应法合成邻氟苯甲腈。 (1)邻甲苯胺经西曼反应合成邻氟甲苯 ,收率 6 5 % ;(2 )邻氟甲苯经氯化、水解得到邻氟苯甲醛 ,以过氧化苯甲酰为氯化引发剂 ,氧化锌为水解催化剂 ,收率 80 % ;(3)邻氟苯甲醛经肟化反应得到邻氟苯甲醛肟 ,收率 87% ;(4)肟用乙酸酐脱水合成出邻氟苯甲腈 ,收率 76 % ,产品质量分数大于 99%。