全文获取类型
收费全文 | 73374篇 |
免费 | 7689篇 |
国内免费 | 4734篇 |
专业分类
电工技术 | 5101篇 |
技术理论 | 6篇 |
综合类 | 6868篇 |
化学工业 | 11201篇 |
金属工艺 | 3997篇 |
机械仪表 | 4396篇 |
建筑科学 | 5661篇 |
矿业工程 | 1992篇 |
能源动力 | 1874篇 |
轻工业 | 8661篇 |
水利工程 | 1994篇 |
石油天然气 | 3007篇 |
武器工业 | 750篇 |
无线电 | 8405篇 |
一般工业技术 | 7310篇 |
冶金工业 | 2415篇 |
原子能技术 | 859篇 |
自动化技术 | 11300篇 |
出版年
2024年 | 393篇 |
2023年 | 1288篇 |
2022年 | 2715篇 |
2021年 | 3483篇 |
2020年 | 2762篇 |
2019年 | 2021篇 |
2018年 | 2198篇 |
2017年 | 2484篇 |
2016年 | 2212篇 |
2015年 | 3438篇 |
2014年 | 4410篇 |
2013年 | 5185篇 |
2012年 | 5982篇 |
2011年 | 6418篇 |
2010年 | 5718篇 |
2009年 | 5226篇 |
2008年 | 5217篇 |
2007年 | 4790篇 |
2006年 | 4256篇 |
2005年 | 3364篇 |
2004年 | 2374篇 |
2003年 | 1958篇 |
2002年 | 1989篇 |
2001年 | 1690篇 |
2000年 | 1106篇 |
1999年 | 881篇 |
1998年 | 466篇 |
1997年 | 372篇 |
1996年 | 347篇 |
1995年 | 229篇 |
1994年 | 179篇 |
1993年 | 141篇 |
1992年 | 134篇 |
1991年 | 86篇 |
1990年 | 60篇 |
1989年 | 49篇 |
1988年 | 29篇 |
1987年 | 23篇 |
1986年 | 21篇 |
1985年 | 7篇 |
1984年 | 8篇 |
1983年 | 8篇 |
1982年 | 14篇 |
1981年 | 10篇 |
1980年 | 20篇 |
1979年 | 11篇 |
1977年 | 2篇 |
1973年 | 1篇 |
1959年 | 7篇 |
1951年 | 14篇 |
排序方式: 共有10000条查询结果,搜索用时 62 毫秒
11.
Jieyun Tu Xinghui Shi Yuanrong Jing Huimin Zou Jakub Kadlcak Zhanfu Yong Susu Liu Guangyong Liu 《Polymer Engineering and Science》2021,61(8):2213-2221
Equilibrium swelling and rheological tests were adopted to systematically investigate the effects of softener type and dosage on the crosslink densities. The results turned out that the chemical crosslink density could be distinguished from the physical crosslink density by comparing the results of equilibrium swelling and rheological tests. The liquid butadiene (LB) as a softener leads to the greatest reduction in crosslink density, followed by polyethylene wax (PW) and paraffinic oil (PO). The tensile strength decreases with increasing PO content while shows peak values with increase of LB and PW contents. The dependencies of chemical crosslink density on the aging time under 150°C are quite different for the three softeners, which can be expected from the double crosslinking networks consisting of small softener and large main crosslinking networks. Further investigation has been performed to correlate the tensile strength with chemical crosslink density of ethylene propylene diene monomer elastomer vulcanizates. Three different linear relationships can be obtained for the softeners independent of the aging time. It can now be expected from this study that the role of some new softeners in rubber compounds is not only confined to plasticization but also forms crosslinking networks in the peroxide-cured rubbers. 相似文献
12.
13.
Sheng Mingming Yang Rongkun Gong Hongyu Zhang Yujun Lin Xiao Jing Jie 《Journal of Materials Science》2022,57(10):5805-5824
Journal of Materials Science - With the extensive use of high-power electronic appliances, polymer-based thermal insulation composites with excellent thermal properties are utilized in the field of... 相似文献
14.
Jinshuang Wang Luyao Chen Mengdi Chen Yuyang Wu Yinghui Wang Yongsheng Yu Junbin Sun Bing Liu Qiangshan Jing 《Ceramics International》2021,47(16):22965-22975
In this study, the destabilization resistance of Sc2O3 and CeO2 co-stabilized ZrO2 (SCZ) ceramics was tested in Na2SO4 + V2O5 molten salts at 750°C–1100 °C. The phase structure and microstructure evolution of the samples during the hot corrosion testing were analyzed with X-ray diffraction (XRD), Raman spectra, scanning electron microscopy (SEM), energy dispersive X-ray spectrum (EDS), and X-ray photoelectron spectroscopy (XPS). Results showed that the destabilization of SCZ ceramics at 750 °C was the result of the chemical reaction with V2O5 to produce m-ZrO2 and CeVO4, and little ScVO4 was detected in the Sc2O3-rich SCZ ceramics. The primary corrosion products at 900 °C and 1100 °C were CeO2 and m-ZrO2 due to the mineralization effect. The Sc2O3-rich SCZ ceramics exhibited excellent degradation resistance and phase stability owing to the enhanced bond strength and the decreased size misfit between Zr4+ and Sc3+. The destabilization mechanism of SCZ ceramic under hot corrosion was also discussed. 相似文献
15.
Hongli Liu Peng Wang Bo Zhang Hongyan Li Jing Li Yajing Li Zhong Chen 《Ceramics International》2021,47(5):6487-6495
A novel carbon/m-HNTs composite aerogel was synthesized by introducing the modified halloysite nanotubes (m-HNTs) into phenolic (PR) aerogels through chemical grafting, followed with carbonization treatment. In order to explore the best proportion of HNTs to phenolic, the micromorphology of PR/m-HNTs were investigated by SEM before carbonization, confirming 10 wt% of m-HNTs is most beneficial to the porous network of aerogels. The interaction between PR and HNTs was studied by FTIR spectra, and microstructure evolution of the target product-carbon/m-HNTs composite aerogel were illustrated by SEM and TEM techniques. SEM patterns indicated that the carbon/m-HNTs aerogels maintain a stable porous structure at 1000 °C (carbonization temperature), while a ~20 nm carbon layer was formed around m-HNTs generating an integral unit through TEM analysis. Specific surface area and pore size distribution of composite aerogels were analyzed based on mercury intrusion porosimetry and N2 adsorption–desorption method, the obtained results stayed around 500 m2g?1 and 1.00 cm3g?1 (pore volume) without significant discrepancy, compared with pure aerogel, showing the uniformity of pore size. The weight loss rate (26.76%) decreased greatly compared with pure aerogel, at the same time, the best volumetric shrinkage rate was only 30.83%, contributed by the existence of HNTs supporting the neighbor structure to avoid over-shrinking. The highest compressive strength reached to 4.43 MPa, while the data of pure aerogel was only 1.52 MPa, demonstrating the excellent mechanical property of carbon/m-HNTs aerogels. 相似文献
16.
美军将网络空间视为继陆、海、空、天外的第五大作战域,并将其列为国防部11项现代化优先事项之一,在美国等军事大国推动下,网络空间成为国家安全竞争和军事斗争的新疆域.文中对近年美国联邦政府、各部门及各军种发布的网络空间领域主要战略政策、规划计划进行梳理,研究其主要战略思想;分析美军2022财年国防预算、研究经费投向投量及重点项目的 研发情况.形成的研究成果将对我国网络空间安全领域研究提供技术支撑. 相似文献
17.
Li Qian Chen Yan Sun Shikun Zhu Muyuan Xue Jing Gao Zihan Zhao Jinfeng Tang Yihe 《Water Resources Management》2022,36(12):4799-4817
Water Resources Management - Increasing water consumption in agriculture due to global climate change has posed considerable challenges to food security, thus improving the efficiency of water... 相似文献
18.
Water Resources Management - The low impact development (LID) concept aims to control storm runoff and pollution through decentralized, small-scale source control to bring the development area as... 相似文献
19.
Dr. Qian Wang Xinli Fan Nannan Jing Han Zhao Dr. Lijia Yu Prof. Xinjing Tang 《Chembiochem : a European journal of chemical biology》2021,22(11):1901-1907
Small interfering RNA (siRNA) can effectively silence target genes through Argonate 2 (Ago2)-induced RNA interference (RNAi). It is very important to control siRNA activity in both spatial and temporal modes. Among different masking strategies, photocaging can be used to regulate gene expression through light irradiation with spatiotemporal and dose-dependent resolution. Many different caging strategies and caging groups have been reported for light-activated siRNA gene silencing. Herein, we describe a novel caging strategy that increases the blocking effect of RISC complex formation/process through host/guest (including ligand/receptor) interactions, thereby enhancing the inhibition of caged siRNA activity until light activation. This strategy can be used as a general approach to design caged siRNAs for the photomodulation of gene silencing of exogenous and endogenous genes. 相似文献
20.
Xueru Chen Yin Zhang Dashui Yuan Wu Huang Jing Ding Hui Wan Wei-Lin Dai Guofeng Guan 《材料科学技术学报》2021,71(12):211-220
Porous g-C3N4 nanosheets (PCN) were prepared by the nickel-assisted one-step thermal polymerization method.Hydrogen (H2) which was produced by the reaction between nickel (Ni) foam and ammonia (NH3) defined the structure and properties of PCN.During the formation of PCN,the participation of H2 not only enhanced the spacing between layers but also boosted the specific surface area that more active sites were exposed.Additionally,H2 promoted pores formation in the nanosheets,which was beneficial to the transfer of photons through lamellar structure and improved the absorption efficiency of visible light.Remarkably,the obtained PCN possessed better Cr(Ⅵ) photocatalytic reduction efficiency than pure g-C3N4.The reaction rate constant (k) of PCN (0.013 min-1) was approximately twice that of bare g-C3N4 (0.007 min-1).Furthermore,the effects of original pH and concentration of Cr(Ⅵ)-containing solution on removal efficiency of Cr(Ⅵ) were explored.A possible photocatalytic mechanism was proposed based on the experiments of radical scavengers and photoelectrochemical characterizations. 相似文献