熔融石英耐火材料

阐述了熔融石英耐火材料的主要性能与应用领域。     

The influence of F doping on the activity of PbO2 film electrodes in oxygen evolution reaction

The PbO₂ and F⁻-doped PbO₂ (F-PbO₂) film electrodes have been prepared by an electrodeposition process onto platinum substrate. The changes of their electrochemical activity for oxygen evolution (OE) reaction with accelerated electrolysis time have been studied. The results show that the activity of the electrodes decreases with increasing electrolysis time. This can be attributed to the conductivity variations, which are caused by the decrease of the oxygen vacancy concentration in PbO₂ films during OE. The mechanism of the decrease of the oxygen vacancies has been investigated. For F-PbO₂ film electrodes, though its electrochemical activity is somewhat lower than that of undoped one, its activity stability is much higher in comparison with that of PbO₂. The influence of F⁻ doping on the activity of PbO₂ film electrodes has been also discussed.     

Rapid pyrolysis of brown coal and oil shale

A brown coal, peat and oil shale were subjected to a rapid pyrolysis process and medium-heat-value gases together with tar were collected. The char residue was of high activity and suitable for gasification to create a two-stage gasification system. The coal-tar is used for manufacturing liquid fuels and chemicals.     

喷动床反应模型的研究进展

喷动床是一种可实现热量重复循环的高效反应器 .介绍了目前喷动床研究中出现的各种反应模型 ,从等温和非等温两个方面讨论了一维轴向、流管、半分割和流动反应耦合等各类模型的基本思想和理论及各自的特点 ,并提出了进一步发展的方向 .     

应用WCA微扰理论推算非极性液体比热容的新方法

本文首次将统计热力学的Ｗｅｅｋｓ－Ｃｈａｎｄｌｅｒ－Ａｎｄｅｒｓｏｎ（简称ＷＣＡ）微扰理论应用于非极性液体定容比热容和定压比热容的推算，用一些液体的ｐ－ｖ－Ｔ实验数据拟合了理论中所用ＬＪ势能函数的势能参数，并提出一个通用关联式。本文方法具有通用性，在编制的计算程序中只需输入物质的临界温度、临界比容、偏心因子等就能算出相应的比热容，工程应用十分方便。     

Fabrication and amplification of Rhodamine B‐doped step‐index polymer optical fiber

A step‐index polymer optical fiber (SI POF) containing Rhodamine B in poly(methyl methacrylate) (PMMA) has been fabricated by a preform technique. Fluorescence of different fiber lengths were observed and discussed. A high gain (23 dB) for a SI POF with 60‐cm length, 400‐μm diameter was obtained. The Rhodamine B content of the doped SI POF is 5 ppm‐wt. The signal wavelength providing the highest gain for a 60 cm SI POF is around 630 nm, and the optimum fiber length is about 60 cm at 10 kW launched pump power. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 681–685, 2004     

真空辅助成型工艺(VARI)研究

VARI在低成本成型工艺中起着很重要的作用，本文将介绍它的特点、制造、性能以及在国内外的应用。     

Determination and correlation solubility of 4-nitroimidazole in twelve pure solvents from 278.15 K to 323.15 K

In this paper, the solubility of 4-nitroimidazole in twelve pure solvents (toluene, benzene, 1,4-dioxane, acetonitrile, ethyl acetate, acetone, GBL, ethanol, methanol, n-butanol, DMF and NMP) were determined by using the laser monitoring system from 278.15 K to 323.15 K under 101.1 kPa, which are 0.00018-0.00070, 0.00021-0.00073, 0.00034-0.00092, 0.00038-0.00142, 0.00047-0.00120, 0.00126-0.00303, 0.00225-0.00517, 0.00310-0.00724, 0.00467-0.00982, 0.00453-0.01940, 0.01947-0.04652, and 0.04670-0.07452, respectively. At constant temperature, the mole fraction solubility of 4-nitroimidazole were increased as the following order: toluene < benzene < 1,4-dioxane < (ethyl acetate or acetonitrile) < acetone < GBL < ethanol < (methanol or nbutanol) < DMF < NMP, and the solubility of 4-nitroimidazole in (ethyl acetate, acetonitrile) and (methanol, n-butanol) had an intersection point at 297.55 K and 281.85 K, respectively. The solubility of 4-nitroimidazole could be increased with increasing temperature in twelve pure solvents. The ideal model, modified Apelblat equation, polynomial empirical equation, and λh equation were used to correlate the experimental values. The experimental solubility values were employed to calculate the standard dissolution enthalpy, standard dissolution entropy and Gibbs energy. The dissolution of 4-nitroimidazole could be an endothermic process in twelve pure solvents. The determination and fitting solubility of 4-nitroimidazole have important guiding significance for the purification and crystallization of its preparation process.     

新型单组分聚氨酯防水涂料的研制

由异氰酸酯、聚醚多元醇和各种助剂制成不含焦油、不含溶剂的单组分湿固化聚氨酯(PU)防水涂料。讨论了聚醚配比、体系中水份及酸碱度等影响因素。该涂料具有性能优良、使用方便、对环境无污染等优点。经济效益和社会效益显著 ,具有广阔的发展前景     

[Cu_2(Gly—GlyO)_2(OH)_2(4,4—bpy)]·9H_2O配合物合成、晶体结构研究

采用Gly—GlyOH,4,4＇—联吡啶与Cu(NO_3)_2·H_2O在二次水溶液中反应,合成出以4,4＇—bpy为中继基,Gly—Glyo为螯环新型双核铜配合物。经X射线单晶结构分析确定该配合物品体的化学结构式:[(H_2NCH_2CONHCH_2COO) Cu(OH) (C_(10)H_8N_2)Cu(OH) (H_2NCH_2CONHCH_2COO)]·9H_2O.晶体属于三斜晶系,P_空间群,晶胞参数a=1.1412nm,b=1.2298nm,C=1.4269nm,α=113.82°,β=101.91°,y=103.64°,V=1.6747nm~3,Z=2。衍射数据是在Nicolet XRD R3型四圆衍射仪上收集,结构参数经块矩阵最小二乘法精修后,最终一致性因子R值为0.068,RW值为0.057。