Eddy current measurements of electrical conductivity and magnetic permeability of porous metals

This paper presents a method, which simultaneously estimates the electrical conductivity and magnetic permeability of porous metals. Porous Cu and Fe manufactured by the lost carbonate sintering process have been tested. An air-cored solenoid coil was designed for the measurements of rod-shaped samples when inserted coaxially with the coil. It was theoretically found that the phase-frequency response of the normalised eddy current signal of the coil is virtually independent of the radius, electrical conductivity and magnetic permeability of the test samples. For non-magnetic, conductive porous Cu, the electrical conductivity was measured with a calibration curve of the coil relating the impedance change and the electrical conductivity of the sample. For magnetic porous Fe, the imaginary part of the signal at the lowest frequencies can be used to estimate the permeability. The measured conductivity values of the porous Cu are shown in the paper in comparison with that of bulk materials with known conductivity. The measured permeability values of the porous Fe are given and the sample-length effect on the measurements is also discussed.     

用DSPCF分光光度法测定钯

在室温下以硝酸为介质,钯与DSPCF形成有色络合物,其表观摩尔吸光系数ε_(520)=1.2×10~4,络合物组成为Pd(Ⅱ):DSPCF=1:2。其特点是在室温下发生显色反应,当加入HNO_3使介质达1.75N时,只有Pd(Ⅱ)—DSPCF红色络合物不褪色,可用于铂钯二次精矿等的测定。     

跟踪世界铸造新技术

结合工业先进国家铸造技术发展趋势，总结了东风汽车公司近几年来，在铸造材料、铸铁熔化、造型、制芯、砂处理及清理等跟踪先进技术的几项技术成果。     

试样长度对 13CrMo44钢管力学性能的影响

研究了试样长度对13CrMo44珠光体耐热钢管力学性能的影响，研究结果表明，随着L0升高，该钢管的伸长率下降并满足δ=16.9% 68.2%√F/L0关系，L0较短时，其对钢管的抗拉强度（σb)和屈服强度（σs)没有什么影响；L0较长时，钢管的σb和σs都稍有下降，解释了产生上述现象的原因。     

弧面分度凸轮理论轮廓面的计算

提高凸轮的加工质量是目前弧面分度凸轮研究的一个重点。但无论是其静态几何量测量,还是加工误差分析,首先要解决的是凸轮理论轮廓面的计算。本文在对弧面分度凸轮轮廓面详尽分析的基础上,论述了弧面分度凸轮理论轮廓面的计算以及ＶｉｓｕａｌＣ＋＋５．０开发的面向凸轮加工精度分析的理论轮廓面计算软件包。该软件包可应用于凸轮ＣＡＤ、ＣＡＭ、ＣＡＱ等子系统。     

深过冷Fe76B12Si12超细晶材料的凝固组织与软磁性能

首次采用深过冷加水淬的方法,成功地制备了直径为16 mm的样品,高为15 mm,组织中颗粒平均尺寸约为120nm左右的Fe76B12Si12合金超细晶材料.其磁损耗P1T400和P1T1000分别为普通硅钢片的40%和65%.系统研究了组织类型及Fe2B(Si)相尺度对该合金软磁性能的影响,发现该合金的最佳软磁性能位于Fe2B(Si)相完全粒化的非规则共晶组织区,并且当Fe2B(Si)相尺寸细化至0.36～0.50μm时,其软磁性能随着相尺寸的减小而大幅度改善.对以上结果产生的原因进行了讨论.     

钢结硬质合金材料的研究进展

介绍了钢结硬质合金的性能特点及制备工艺,简述了近年来在钢结硬质合金领域开展的研究与取得的进展,对钢结硬质合金的应用进行了分类归纳,展望了其发展前景。     

碳化硅晶须双重加热合成的研究

双重加热法是低成本、大批量合成碳化硅晶须的新技术，合成温度低、合成时间短、生成率高。对以炭黑和二氧化硅微粉为原料、用双重加热法合成碳化硅晶须的工艺过程进行了研究。观察了不同合成时间、合成温度和催化剂条件下的碳化硅晶须，揭示出不同工艺参数对合成的碳化硅晶须的产出率，微观形貌、直径和长度范围的影响。结果表明，催化剂的使用可以加快反应速度，提高碳化硅晶须的生成率，合成过程为VLS。实验中初步得到的最佳经济工艺参数为：Fe2O3的用量为2％，合成时间为1．5h，合成温度为1250℃。此时的该工艺条件下碳化硅晶须的生成率可达80％，晶须平均直径为0．6μm，平均长度为30μm。     

在纳米压入仪上进行悬臂梁法测量弹性模量的影响因素分析

对在纳米压入仪上进行悬臂梁法测量弹性模量的主要影响因素进行了综合分析,主要包括加载系统悬置弹簧刚度、压头压入、梁沿截面宽度方向挠曲、梁支座附加挠曲等影响。在考虑这些因素的基础上,得到了悬臂梁的有效挠度,利用有效挠度与载荷之间的关系,评价悬臂梁材料的弹性模量。对单晶硅(100)悬臂梁试样进行了实验,得到其弹性模量为155GPa±9.5%GPa,与参考文献值符合较好。表明在纳米压入仪上进行悬臂梁法测量,只有综合这些影响因素后,才能获得有效、准确的弹性模量测量结果。     

Effect of temperature on anodic behavior of 13Cr martensitic steel in CO2 environment

The corrosion behavior of 13Cr martensitic stainless steel in a CO₂ environment in a stimulated oilfield was studied with potentiodynamic polarization and the impedance spectra technique. The results showed that the microstructure of the surface scale clearly changed with temperature. This decreased the sensitivity of pitting corrosion and increased the tendency toward general (or uniform) corrosion. The capacitance, the charge transfer resistance, and the polarization resistance of the corrosion product scale decrease with increasing temperature from 90 to 120 °C, and thus the corrosion is a thermal activation controlled process. Charge transfer through the scale is difficult and the corrosion is controlled by a diffusion process at a temperature of 150 °C. Resistance charge transfer through the corrosion product layer is higher than that in the passive film.