用于生产甲基丙烯酸的杂多酸催化剂的研究

以异丁烯为原料的两段直接氧化生产甲基丙烯酸最新工艺有许多优点。其技术关键在于研制出高效的甲基丙烯醛选择性氧化催化剂。本文报道P-Mo-As-Cu杂多化合物催化剂的组成、制备条件对催化剂活性的影响。经优化后获得高选择性、高活性的二段氧化催化剂，其甲基丙烯酸收率达60％以上。     

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本文通过对在用钻机井架的现场实际测试,建立数据库、测评模型,对实测的数据用计算机技术进行分析,提出了初始弯曲应力;数据正态分布检验——x～2检验;建立回归方程;在给定置信度下测评当前承载能力的技术概念。解决了在用钻机A型井架的安全性评估问题,是一种较为合理、可靠、科学的测评技术和方法。     

Inter- and intra-molecular ionic interactions of polyampholyte: Carboxymethyl-2-diethylaminoethylcellulose

Carboxymethyl-2-diethylaminoethylcellulose (CM-DEAE cellulose) was prepared by etherification of carboxymethylcellulose with diethylaminoethyl chloride in a NaOH solution. The behaviour of CM-DEAE cellulose in aqueous solution was studied by viscosity and GPC measurements. The degree of substitution (DS) and existing states of DEAE substituents were examined by the use of proton NMR, and those of the CM substituents were observed with FT-IR. The results reveal that the reduced viscosity and apparent molecular size of CM-DEAE cellulose vary with the concentration of sodium chloride and changes in pH and DS. These phenomena can be explained in terms of inter- and intra-molecular ionic interactions.     

Crystallization behaviour of Ni-Co-base metallic glasses by isochronal and isothermal annealing

The crystallization behaviour of three amorphous alloys, Co₅₀Ni₂₅Si₁₅B₁₀, Ni₅₀Co₂₅Si₁₅B₁₀ and Ni₅₀Co₂₅P₁₅B₁₀, was studied by means of differential thermal analysis in conjunction with scanning transmission electron microscopy. Isochronal annealing showed a strong dependence of crystallization on scan rate over the range of 1.99 to 20.70 K min^–1. At high Co/Ni ratios, a sequential two-stage crystallization process involving primary MS-I phase followed by MS-II phase precipitation was observed. At low Co/Ni ratios MS-I and MS-II crystallization were concurrent and inseparable. Replacement of the metalloid Si with P as the glass-former dramatically reduced the activation energy for crystallization as well as the crystallization temperature. A mechanistic understanding of these findings was pursued in light of TEM/STEM microanalysis     

有扰对称信道平均信息量的计算

照相手机让诺基亚抢了风头，这真是亚洲人的失策。在日本和韩国，内置摄像头的手机早就不是什么值得炫耀的东西了。不过日本人的动作还是很快的，GD88和N8一副后来居上的架势，让人不敢小瞧。     

Exploratory analysis of brain connectivity with ICA.

Covariance-based methods of exploration of functional connectivity of the brain from functional magnetic resonance imaging (fMRI) experiments, such as principal component analysis (PCA) and structural equation modeling (SEM), require a priori knowledge such as an anatomical model to infer functional connectivity. In this research, a hybrid method, combining independent component analysis (ICA) and SEM, which is capable of deriving functional connectivity in an exploratory manner without the need of a prior model is introduced. The spatial ICA (SICA) derives independent neural systems or sources involved in task-related brain activation, while an automated method based on the SEM finds the structure of the connectivity among the elements in independent neural systems. Unlike second-order approaches used in earlier studies, the task-related neural systems derived from the ICA provide brain connectivity in the complete statistical sense. The use and efficacy of this approach is illustrated on two fMRI datasets obtained from a visual task and a language reading task.     

Comparisons of PWM and one-cycle control for power amplifier with multilevel converter

Based on the concepts of cascade multilevel converters and one-cycle technique, comparisons are conducted to characterize the distortion of the pulsewidth modulation (PWM) and one-cycle control methods that were applied to converters. Simulation results for the different control schemes are obtained in PSIM software initially to see the effect of one-cycle control different from that of PWM control. Through the comparisons, the advantages and disadvantages are identified for each method. The one-cycle scheme is better than PWM control in reducing undesirable harmonics and tracing dynamic waveforms. Simulation and experimental results are also provided to verify the conclusions.     

27keV Ar~+斜入射时的Cu-Au合金溅射实验角分布

用27keV Ar~+分别在垂直和倾斜入射情况下,轰击了Cu-Au(30wt％)合金样品,测量了Cu和Au原子的溅射角分布。角分布是用卢瑟福背散射(RBS)技术分析Al捕获膜上的Cu-Au沉积成分而定量得到的。结果表明:(1)在Ar~+倾斜(θ=40°)入射时,Cu原子择优发射,且程度比垂直入射(θ_r=O°)时增强:(2)倾斜入射时,Cu原子的角分布显示出在接近于样品表面法线方向的发射角范围内(θ<45°),发射机率比垂直入射时减小。