RP—HPLC流动相组成优化方法的研究及其专家系统的建造

本文提出了一种既便于自动求值,又不致产生歧义的色谱分离优化目标函数。对于反相高效液相色谱RP-HPLC流动相组成优化问题,提出了新的高效迭代方法,并建立了组成优化专家系统。该系统包括优化搜索区域确定、实验谱图辨识、保留特性关系的自适应回归和最优目标预测等功能。经实验验证,该系统具有较高的迭代搜索效率。     

不同肟类N－甲基氨基甲酸酯的杀虫活性和离体胆碱酯酶抑制作用的研究

文中测定了一系列α－氰基甲酮肟和三氟甲基苯基甲酮肟类Ｎ－甲基氨基甲酸酯的杀虫活性和抑制胆碱酯酶活性。α－氰基烷基甲酮肟类Ｎ－甲基氨基甲酸酯具有极好的杀虫活性和抑制胆碱酯酶活性，而α－氰基苯基甲酮肟类衍生物仅仅呈现抑制胆碱酯酶活性。三氟甲基苯基甲酮肟类Ｎ－甲基氨基甲酸酯具有有力的杀虫活性和胆碱酯酶抑制活性。     

辛硫磷合成的工艺改进

本文介绍了辛硫磷的中间体α－氰基苯甲肟钠及其原油合成的工艺改进，总收率达到８４％，该方法操作简单，成本低，适合于工业化生产。     

水利对粮食生产贡献率的认识与思考

针对目前很多人对农业科技进步贡献率和水利对粮食生产贡献率的不同认识,从发展历程、概念内涵、测算思路方法等方面,剖析了二者差异,认为二者在测算范围上存在大口径与小口径的差异,在测算对象上存在增量与总量的差异,在测算指标上存在产值与产量的差异,在测算方法上存在余值法与有无对比法的差异,为正确认识这两个指标提供了参考。     

无线传感器网络中基于树的动态多路径容错路由协议

多路径路由对无线传感器网络的负载均衡和容错能力等方面都有一定改善作用。在研究一些多路径路由算法的基础上,对分层的无线传感器网络路由进行探索,提出了一种基于树的动态多路径路由的生成方法,快速获得当前节点的主路径与备用路径。仿真结果表明,该方法可有效地均衡网络负载、减少时延、提高网络的可靠性。     

Acoustic emission from gas-filled coal under triaxial compression

Acoustic emission (AE) experiments have been performed on gas-saturated coal specimens under conventional triaxial compression. The AE characteristics were investigated for a methane gas flow through the coal specimen. One AE parameter, AE count, when normalized by the total count number was used to represent the damage evolution in the gassy coal. It is shown that this AE parameter is a reasonable indicator for damage occurring within the coal specimen since its envelope has almost the same shape as the complete stress–strain curve, except for a short time delay. In addition, the change in AE count is highly consistent with the change in coal permeability. Test results also show that methane containing coal emits a small number of AE events before entering the yield stage. AE activity gradually increases during the yield process up to the peak stress. The lowest permeability corresponds to the highest AE activity, implying failure will soon occur. An AE based constitutive model was constructed and the theoretical results agree well with those of experiments.     

Temporal scale effect of loading data on instream nitrate-nitrogen load computation

The temporal scale effect of loading data on nitrate-nitrogen load computation was examined using outputs of watershed modeling tool Hydrologic Simulation Program-FORTRAN (HSPF) for the Amite River in Louisiana, USA. The daily nitrate-nitrogen concentrations simulated using the HSPF were employed first to obtain daily, weekly, bi-weekly, and monthly average data and then to develop load duration curves for the data with four different temporal scales. The duration curves exhibited high variability in the load estimated using daily data as compared with those based on bi-weekly and monthly data. According to daily data, the nitrate-nitrogen load in the winter was found to be 2,780 kg. The nitrate-nitrogen load decreased with increasing temporal (daily, weekly, bi-weekly, and monthly) scale (commonly used in water quality monitoring) of the data. The coefficient of variation, used to quantify the effect of temporal scale on the load, was found to be linearly and inversely correlated with the logarithm of the time scale. Based on the finding, empirical equations were proposed to extrapolate near real-time data for flow and nitrate-nitrogen, greatly simplifying nutrient monitoring and reducing the cost involved in water quality monitoring.     

Compound stabilization/solidification of MSWI fly ash with trimercapto-s-triazine and cement

A new treatment technology of municipal solid waste incineration (MSWI) fly ash is presented in this paper. Feasibility of solidification/stabilization treatment of MSWI by successively adding trimercapto-s-triazine and cement, and the effect of addition, fly ash size and curing time were studied by batch tests. The results showed that MSWI posed a huge environmental risk, the partial distribution showed normal distribution approximately. Treatment of fly ash with trimercapto-s-triazine and cement showed a good effect, the leaching toxicity of treated fly ash solidified blocks with 2% trimercapto-s-triazine and 20% cement could meet the standard for pollution control on the landfill site of MSW in China after curing for 7 days, and the flexural strength of solidified blocks could reach 2.4 MPa. Ground fly ash had a positive effect on both leaching toxicity and strength.     

移动台车栏板辅助浇筑系统的设计与应用

蒲石河工程下水库大坝顶部混凝土护栏位于坝顶临空边沿,钢筋绑扎和模板支立作业难度大,施工时存在安全隐患。为此,蒲石河工程设计了移动台车栏板辅助浇筑系统并成功应用。实践表明,作业台车设计可靠、安全稳定、操作简便、定位准确、移动方便,保障了施工人员人身安全,节约了成本,加快了工期,提高了模板支立质量,值得类似工程借鉴并推广使用。     

机载电缆作战损毁后智能化诊断系统

从技战术实际需要出发,给出了某型飞机作战损毁后机载电缆的智能化诊断系统的硬件结构框图。根据硬件系统模拟开关组件的原理,定义了电缆的连接矩阵、测量矩阵以及断口的映像矩阵运算,给出了断头查找的算法。计算表明,系统可在20 min内完成一个循环的断头查找并给出故障定位。