Facile modifications of polyimide via chloromethylation: II. Synthesis and characterization of thermocurable transparent polyimide having methylene acrylate side groups

From chloromethylated polyimide, a useful starting material for modification of aromatic polyimides, a thermocurable transparent polyimide having acrylate side groups was prepared. In the presence of 1,8‐diazabicyclo[5,4,0]undec‐7‐ene, chloromethylated polyimide was esterified with acrylic acid to synthesize poly(imide methylene acrylate). The polymer was soluble in organic solvent, which makes it possible to prepare a planar film by spin coating. The polymer film became insoluble after thermal treatment at 230 °C for 30 min. Optical transparency of the film at 400 nm (for 1 µm thickness) was higher than 98 % and not affected by further heating at 230 °C for 250 min. Adhesion properties measured by the ASTM D3359‐B method ranged from 4B to 5B. Preliminary results of planarization testing showed a high degree of planarization (DOP) value (>0.53). These properties demonstrate that poly(imide methylene acrylate) could be utilized as a thermocurable transparent material in fabricating display devices such as TFT‐LCD. Copyright © 2004 Society of Chemical Industry     

电力负荷削峰减载系统在珠钢电炉的应用

借助现场采集装置,在计算机上获取每一分钟的冶炼工艺电能需求量,显示当前15分钟时段已发生的电耗量,调整用户设定,实现需量自动刷新、报警和专家分析推荐后续用量;实现平稳用电并减少对电网冲击,同时降低电能最大需用量以减少成本。     

Behaviors of concrete-filled steel tubular members subjected to combined loading

The present study is an investigation on the behaviors of concrete-filled thin-walled steel tubular members subjected to combined loading, such as compression and torsion, bending and torsion, compression, bending and torsion. ABAQUS software is used in this paper for the finite element analysis (FEA). A comparison of results calculated using this modeling shows generally good agreement with test results. The FEA modeling is then used to investigate the influence of important parameters that determine the ultimate strength of the composite members under combined loading, such as compression and torsion, bending and torsion, compression, bending and torsion. The parametric studies provide information for the development of formulae for calculating the ultimate strength of the composite members subjected to combined loading.     

有机羧酸钠盐对PET结晶和熔融行为的影响

采用差示扫描量热仪研究了5种具有不同取代基的苯甲酸钠盐作为结晶成核剂对聚对苯二甲酸乙二醇酯（HET）结晶和熔融行为的影响，并同滑石粉进行了对比。结果表明，成核剂的加入能明显改变PET的结晶和熔融行为。苯甲酸钠、对苯二甲酸甲酯单羧酸钠和对羟基苯甲酸钠提高既汀的熔融结晶温度（Tc）分别达22．93、21．7和19．37℃，但使PET降解严重；对苯酚钠甲酸钠能够提高Tc达17．75℃且对PET相对分子质量影响很小；对苯二甲酸二钠成核作用最差。低于滑石粉。此外，成核剂的成核能力越强，PET双熔融峰中的低温峰顶温度就越高。     

Image denoising based on wavelets and multifractals for singularity detection.

This paper presents a very efficient algorithm for image denoising based on wavelets and multifractals for singularity detection. A challenge of image denoising is how to preserve the edges of an image when reducing noise. By modeling the intensity surface of a noisy image as statistically self-similar multifractal processes and taking advantage of the multiresolution analysis with wavelet transform to exploit the local statistical self-similarity at different scales, the pointwise singularity strength value characterizing the local singularity at each scale was calculated. By thresholding the singularity strength, wavelet coefficients at each scale were classified into two categories: the edge-related and regular wavelet coefficients and the irregular coefficients. The irregular coefficients were denoised using an approximate minimum mean-squared error (MMSE) estimation method, while the edge-related and regular wavelet coefficients were smoothed using the fuzzy weighted mean (FWM) filter aiming at preserving the edges and details when reducing noise. Furthermore, to make the FWM-based filtering more efficient for noise reduction at the lowest decomposition level, the MMSE-based filtering was performed as the first pass of denoising followed by performing the FWM-based filtering. Experimental results demonstrated that this algorithm could achieve both good visual quality and high PSNR for the denoised images.     

Frequency domain solution to delay-type Nehari problem

This paper generalizes the frequency-domain results on the delay-type Nehari problem in the stable case to the unstable case. The solvability condition of the delay-type Nehari problem is formulated in terms of the nonsingularity of three matrices. The optimal value γ_opt is the maximal γ∈(0,∞) such that one of the three matrices becomes singular. All sub-optimal compensators are parameterized in a transparent structure incorporating a modified Smith predictor.     

新型复合弹簧的研究

提出一种金属圆锥弹簧与橡胶圆锥弹簧复合而成的弹簧．分析表明：它可以应用于弹性耦合激励振动筛和座式直线振动筛。     

新疆三塘湖盆地侏罗系煤有机地球化学特征

有机地球化学和有机岩石学研究结果表明，新疆三塘湖盆地侏罗系煤中富集孢子体和角质体（３．０％～６．０％，全岩体积百分比），对煤中氯仿沥青“Ａ”组成中较高的总烃馏分（３０％～５０％）和饱芳比（０．６～３．０）产生了影响。煤的聚集环境是影响煤的显微组分组成及生油特性的关键因素。三塘湖盆地侏罗系煤属于“晚生晚排”叠加有“早生早排”类型的烃源岩。     

制革用水乳型聚氨酯涂饰剂行业标准的制定

本文概述了制定该标准的背景，对标准的主要内容加以科学的阐述。