Effect of Zn Content on Microstructure and Propereties of Ternary Co-cemented Magnesium

以锌铝等混合粉为扩渗源,通过热扩渗方法对纯镁进行了Zn-Al-RE三元共渗.通过氧化铈的催渗作用得到了成分不同的渗层,分析渗层中锌含量对渗层耐磨、耐蚀等性能的影响.结果表明:渗层中含有5％锌的渗层具有较好的综合性能.     

The effect of solute on discontinuous dynamic recrystallization

A series of Cu–Sn alloys (pure Cu, Cu–0.2Sn, Cu–2Sn and Cu–5Sn) has been prepared to experimentally test the effect of solute on discontinuous dynamic recrystallization (DDRX) as a function of both temperature and strain rate. Hot compression tests were performed and the microstructure was characterized using optical and scanning electron microscopy. Solute additions tend to broaden the peak in the flow stress curve and increase the peak stress, peak strain and steady-state stress. A reduction in the DRX grain size and a retardation of the kinetics of recrystallization are observed with solute additions, although the effect saturates at 2Sn. A recently published, physically based model for DDRX of pure Cu has been extended to include the effect of solute. The effect on the plastic response of the material and the mobility of high-angle grain boundaries was incorporated and, through comparisons between experiment and simulated DRX phenomena, it is concluded that solute must also significantly affect the nucleation stage of DDRX. A model is developed for the effect of solute on the nucleation of DDRX in Cu–Sn alloys and comparisons with experiment indicate that the principal effects are well captured. Important areas for future work are discussed.     

三辊穿孔和轧管所产生的钢管壁厚极差和波浪形内螺纹

定量描述了实际生产过程中三辊斜轧穿孔所产生的钢管壁厚极差和波浪形内螺纹，初步探讨了三辊轧管机对钢管壁厚极差和波浪形内螺纹的影响。     

铸造工艺方案的评价模型及其应用

利用系统工程理论和模糊数学的法则提出了一个定量评价铸造工艺方案的方法。详细介绍了铸造工艺方案评价模型和铸造工艺方案评价指数的计算式，并结合铸造工艺设计的程序和长期积累的经验详细讨论了评价的方法步骤、指标体系的确定、评价标准的制定、评价框图、数据处理方法以及结果分析。     

比值-导数分光光度法测定含苯胺废水中氨氮的含量

在测定含苯胺废水中的氨氮含量时,由于苯胺和氨氮与纳氏试剂形成的络合物的吸收光谱彼此重叠.因此在采用国标法测定该类废水的氨氮含量时,苯胺对其干扰严重,需采用预处理法消除干扰.根据吸光度比值一导数光谱法的原理,定量分析测定了含苯胺废水中氨氮的浓度,且省去了混凝沉淀、蒸馏等复杂的预处理步骤.实验表明,当氨氮质量浓度<2.4 mg/L,时,吸光度比值的的导数值与相应的氨氮浓度呈良好的线性关系.     

水溶液中4-(2-羟基-苯甲酸酯基)-2-环戊烯砜的合成

以3,4-二溴环戊砜(1)为原料,在无水吡啶作用下发生消除反应,得到反应中间体4-溴-2-环戊烯砜(2),再与水杨酸钠(3)在水溶液和DMF中发生酯化反应,合成水杨酸酯环戊烯砜衍生物(4),用IR,1H NMR,MS,元素分析表征了它们的结构,并讨论了酯化反应在在水溶液和DMF中的最佳反应条件。结果表明:水溶液中的酯化反应后处理更加简单,产率最高。     

HIPS熔融插层蒙脱土复合材料的阻燃性

将钠基蒙脱士(Na -MMT)有机化改性制成有机蒙脱土(OMMT),分别采用静态和动态熔融法制备高抗冲聚苯乙烯/有机蒙脱土(HIPS/OMMT)和高抗冲聚苯乙烯/钠基蒙脱土(HIPS/Na -MMT).X射线衍射和扫描电镜研究表明,层间距由处理前的1.52 nm增加为2.25 nm,OMMT具有明显的分层现象;透射电镜研究表明,静态熔融插层HIPS/OM-MT形成了插层复合结构,动态熔融插层HIPS/OMMT中的OMMT片层被剥离开来,形成了剥离的HIPS/OMMT;锥形量热仪测试结果表明,静态和动态熔融插层HIPS/OMMT的阻燃性能均有所提高,但提高幅度随OMMT添加量的增加而降低;氧指数测试结果表明,HIPS/OMMT的氧指数比纯HIPS有所提高.     

CeO2 Nanocrystalline-Supported Palladium Chloride: An Effective Catalyst for Selective Oxidation of Alcohols by Oxygen

The present paper reports on the use of CeO₂ materials supported palladium chloride catalyst for selectively oxidising organic alcohols into aldehydes. Spherical, microsized rod-shaped and spindle-like CeO₂ particles are synthesised and characterised by SEM. The catalysts are prepared by loading palladium chloride onto the CeO₂ support matrix. A complete characterization of the catalysts is performed. The activity of catalysts is studied by the selective oxidation of various alcohols. The results show that (1) the catalytic activities prepared by spherical cerium are superior to the catalysts prepared by spindle-like or rod-shaped cerium and (2) the catalyst PdCl₂/CeO₂ (nanospheres) show good activity, high yield, and good stability.     

High yield synthesis of diverse well‐defined end‐functionalized polymers by combination of anionic polymerization and “click” chemistry

Well‐defined poly(methyl methacrylate) (M_n = 3630 g mol^?1, PDI = 1.06) with a primary benzylic bromide prepared using anionic polymerization was successfully transformed into diverse end‐functionalities (ω‐carboxyl, ω‐hydroxy, ω‐methyl‐vinyl, ω‐trimethylsilane, and ω‐glycidyl‐ether) via “click” reaction. The bromine end‐terminated poly(methyl methacrylate) was first substituted by an azide function and sequentially was reacted with various functional alkynes (propiolic acid, propargyl alcohol, 2‐methyl‐1‐buten‐3‐yne, propargyl trimethylsilane, and propargyl glycidylether). In all the cases, ¹H‐NMR, ¹³C NMR, FT‐IR, and GPC measurements show qualitative and quantitative transformation of the chain‐end poly(methyl methacrylate) into the desired functionalities with high conversion (above 99%). © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Considerable Enhancement of Field Emission of SnO2 Nanowires by Post-Annealing Process in Oxygen at High Temperature

The field emission properties of SnO₂ nanowires fabricated by chemical vapor deposition with metallic catalyst-assistance were investigated. For the as-fabricated SnO₂ nanowires, the turn-on and threshold field were 4.03 and 5.4 V/μm, respectively. Considerable enhancement of field emission of SnO₂ nanowires was obtained by a post-annealing process in oxygen at high temperature. When the SnO₂ nanowires were post-annealed at 1,000 °C in oxygen, the turn-on and threshold field were decreased to 3.77 and 4.4 V/μm, respectively, and the current density was increased to 6.58 from 0.3 mA/cm² at the same applied electric field of 5.0 V/μm.