AgBiVMo oxide catalytic membrane for selective oxidation of propane to acrolein

A metal ions (Ag, Bi, V, Mo) modified sol–gel method was used to prepare a mesoporous Ag_0.01Bi_0.85V_0.54Mo_0.45O₄ catalytic membrane which was used in the selective oxidation of propane to acrolein. By optimizing the preparation parameters, a thin and perfect catalytically active membrane was successfully prepared. SEM results showed that the membrane thickness is 5 μm. XRD results revealed that Ag_0.01Bi_0.85V_0.54Mo_0.45O₄ with a Scheelite structure, which is catalytically active for the selective oxidation of propane to acrolein, was formed in the catalytic membrane only when AgBiVMoO concentrations were higher than 40%. Catalytic reaction results demonstrated that the selective oxidation of propane could be controlled to a certain degree, such as to acrolein, in the catalytic membrane reactor (CMR) compared to the fixed bed reactor (FBR). For example, a selectivity of 54.85% for acrolein in the liquid phase was obtained in the CMR, while only 8.31% was achieved in the FBR.     

An efficient mode decision algorithm for H.264/AVC intra prediction

Multimedia Tools and Applications - Rate distortion optimization technique is adopted by H.264/AVC to select the best intra and inter prediction modes. It achieves remarkable improvement in...     

关于中压电缆网双环接线方式供电能力的分析

结合北京地区现阶段对相关技术的规定,以实际供用电方案为例,对中压电缆网双环接线方式的供电能力进行深入讨论。通过设计环网单元划分,发现某些条件下双环网供电能力可以得到进一步提升。     

国产软硬件环境下图像组织浏览构件设计

针对在国产软硬件环境下,应用系统读取、浏览大量图像数据的速度慢问题,设计了图像组织浏览构件。通过改进图像组织方式,将基础影像和目标对象图像分开组织管理,并对目标对象图像的属性和分层、分类进行探讨,实现图像信息的快速展现。对图像组织浏览构件进行了插件化设计与实现,利用QT跨平台开发工具,实现了应用集成框架,并通过实现统一集成接口,进行各业务插件的集成。     

Feeding pure docosahexaenoate or arachidonate decreases plasma triacylglycerol secretion in rats

Essential fatty acid (EFA)-deficient rats were fed highly purified methyl esters of docosahexaenoate (22∶6n−3), arachidonate (20∶4n−6), alpha-linolenate (18∶3n−3) or oleate (18∶1n−9) (100 mg/day, tube fed for 3–10 days), and their plasma triacylglycerol (TG) secretion rates were measured. Secretion rates of TG into plasma were reduced by tube-feeding 22∶6n−3, 20∶4n−6, 18∶3n−3, but not 18∶1n−9, to EFA-deficient rats. A significant reduction occurred after feeding 22∶6n−3 for only three days. Feeding 22∶6n−3 or 18∶3n−3 to EFA-deficient rats for three days also reduced the activities of liver lipogenic enzymes and sharply increased the proportions of 22∶6n−3 and 20∶5n−3 in liver phospholipid fractions. Mechanisms by which these EFA may reduce lipogenesis are discussed.     

试议港口集卡调度算法模型分析

随着我国集装箱吞吐量的快速增长,集装箱港口对作业效率的要求也越来越高。在现有作业技术水平和硬件设备、设施的基础上实现作业效率的提高,已经成为集装箱港口发展所面临的重要问题。从集装箱港口作业的一个环节——集卡作业入手,分析提高集卡利用率,进而带动整个港口作业效率的提高。     

N—氯代丁二酰亚胺8—羟基喹哪啶分光光度法测定水中苯胺类化合物的方法研究

本文提出一种能够方便、快速、灵敏地检测水质中苯胺在化合物的新方法。这种方法是先用 N-氯代丁二酰亚胺氧化苯胺 ,再用 8-羟基喹哪啶作为偶联显色剂 ,在 p H9- 1 1的碱性介质中 1进行显色。显色反应所得蓝色化合物的最大吸收波长为 62 0 nm,摩尔吸光系数为 1 .1× 1 0 4 L· mol- 1· cm- 1,在苯胺为 0 .2～ 1 0 mg/l的浓度范围内符和比尔定律 ,最低检出限为 0 .0 3mg/l,测定的重现性在± 5 %以内。该方法成功地用于环境水样的分析 ,并获得满意的分析结果     

基于线性动态系统稀疏编码的异常事件检测

线性动态系统模型结合稀疏编码实现异常事件检测。线性动态系统可有效地捕捉动态纹理在时间和空间的转移信息,描述视频的时空小块。然而,线性动态系统属于非欧氏空间,无法直接用传统的稀疏编码进行异常检测。基于约束凸优化公式,将相似性变换与稀疏编码结合,可实现线性动态系统稀疏编码的优化求解。实验表明,所提出的方法具有更好的性能。     

Effects of the reinforcement and toughening of acrylate resin/CaCO3 nanoparticles on rigid poly(vinyl chloride)

Novel composite particles based on nanoscale calcium carbonate (nano‐CaCO₃) as the core and polyacrylates as the shell were first synthesized by in situ encapsulating emulsion polymerization in the presence of the fresh slush pulp of calcium carbonate (CaCO₃) nanoparticles. Subsequently, these modified nanoparticles were compounded with rigid poly(vinyl chloride) (RPVC) to prepare RPVC/CaCO₃ nanocomposites. At the same time, the effects of the reinforcement and toughening of these modified nanoparticles on RPVC were investigated, and the synergistic effect of modified nanoparticles with chlorinated polyethylene (CPE) was also studied. The results showed that in the presence of nano‐CaCO₃ particles, the in situ emulsion polymerization of acrylates was carried out smoothly, and polyacrylates successfully encapsulated on the surface of nano‐CaCO₃ to prepare the modified nanoparticles, breaking down nano‐CaCO₃ particle agglomerates, improving their dispersion in the matrix, and also increasing the particle–matrix interfacial adhesion. Thus, the effects of the reinforcement and toughening of these modified nanoparticles on RPVC were very significant, and the cooperative effect of the nanoparticles with CPE occurred in the united modification system. Scanning electron microscopy analyses indicated that large‐fiber drawing and network morphologies coexisted in the system of joint modification of nanoparticles with CPE. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3940–3949, 2007