Physico-chemical,morphological and thermal analysis for the combined pozzolanic activities of minerals additives

The research was aimed to evaluate the physico-chemical, morphological and thermal analysis of combined pozzolanic activities of minerals additives. Fly ash and ground granulated blast furnace slag were added, separately and collectively, as mineral replacement in ordinary Portland cement. Tests carried out on specimens cured at different ages were: compressive strength, ultrasonic pulse velocity, X-ray diffraction (XRD) analysis, scanning electron microscopic (SEM) studies, differential thermal analysis (DTA) and thermo-gravimetric analysis (TGA), etc. The results indicated that the compressive strength and ultrasonic pulse velocity development rate of concrete specimens were significantly influenced by the addition of mineral additives. SEM data showed that the fly ash particles were more embedded and surrounded by slag. XRD analysis and DTA/TGA investigation have revealed different reaction kinetics of paste. The peak intensity of calcium hydroxide was significantly retarded by the addition of fly ash and slag, especially in combination, attributed to the dilution effect and calcium hydroxide consumption by pozzolanic reaction.     

Reliability improvement of distribution systems using SSVR

This paper presents a reliability assessment algorithm for distribution systems using a Static Series Voltage Regulator (SSVR). Furthermore, this algorithm considers the effects of Distributed Generation (DG) units, alternative sources, system reconfiguration, load shedding and load adding on distribution system reliability indices. In this algorithm, load points are classified into 8 types and separated restoration times are considered for each class. Comparative studies are conducted to investigate the impacts of DG and alternative source unavailability on the distribution system reliability. For reliability assessment, the customer-oriented reliability indices such as SAIFI, SAIDI, CAIDI ASUI and also load- and energy-oriented indices such as ENS and AENS are evaluated. The effectiveness of the proposed algorithm is examined on the two standard distribution systems consisting of 33 and 69 nodes. The best location of the SSVR in distribution systems is determined based on different reliability indices, separately. Results show that the proposed algorithm is efficient for large-scale radial distribution systems and can accommodate the effects of fault isolation and load restoration.     

Production of low cost self compacting concrete using bagasse ash

Self compacting concrete (SCC) is a development of conventional concrete, in which the use of vibrator for compaction is no more required. This property of self compacting concrete has made its use more attractive all over the world. But its initial higher supply cost over conventional concrete, has hindered its application to general construction. Therefore, for producing low cost SCC, it is prudent to look at the alternates to help reducing the SSC cost. This research is aimed at evaluating the usage of bagasse ash as viscosity modifying agent in SCC, and to study the relative costs of the materials used in SCC.In this research, the main variables are the proportion of bagasse ash, dosage of superplasticizer for flowability and water/binder ratio. The parameters kept constant are the amount of cement and water content.Test results substantiate the feasibility to develop low cost self compacting concrete using bagasse ash. In the fresh state of concrete, the different mixes of concrete have slump flow in the range of 333 mm to 815 mm, L-box ratio ranging from 0 to 1 and flow time ranging from 1.8 s to no flow (stucked). Out of twenty five different mixes, five mixes were found to satisfy the requirements suggested by European federation of national trade associations representing producers and applicators of specialist building products (EFNARC) guide for making self compacting concrete. The compressive strengths developed by the self compacting concrete mixes with bagasse ash at 28 days were comparable to the control concrete. Cost analysis showed that the cost of ingredients of specific self compacting concrete mix is 35.63% less than that of control concrete, both having compressive strength above 34 MPa.     

Characterizing single-walled carbon nanotubes by pressure probe

We compare the behavior of bond lengths, cross sectional shape and bulk modulus at ambient conditions and under hydrostatic pressure of all the three kinds of long uncapped single-walled carbon nanotubes. Results show that two bond lengths completely describe the structure of armchair and zigzag tubes (non-chiral), whereas only one bond length is required to define structure of chiral tubes. In armchair tubes, one bond length is found to be larger and the other smaller than the value for graphene, while in zigzag tubes one of the bond lengths remains equal to and the other larger than graphene bond length. In chiral tubes, three bond lengths are found to be equal to each other and their value depends on the chirality. At some critical pressure values depending on radius, both bond lengths become equal to each other in non-chiral tubes. Above these critical pressure values, the cross section shape changes from circular to oval and the pattern of bond lengths becomes different and dependent on the chirality of the tubes.     

Kinetic and morphological study of a magnesium ethoxide‐based Ziegler–Natta catalyst for propylene polymerization

BACKGROUND: Kinetic and morphological aspects of slurry propylene polymerization using a MgCl₂‐supported Ziegler–Natta catalyst synthesized from a Mg(OEt)₂ precursor are investigated in comparison with a ball‐milled Ziegler–Natta catalyst. RESULTS: The two types of catalyst show completely different polymerization profiles: mild activation and long‐standing activity with good replication of the catalyst particles for the Mg(OEt)₂‐based catalyst, and rapid activation and deactivation with severe fragmentation of the catalyst particles for the ball‐milled catalyst. The observed differences are discussed in relation to spatial distribution of TiCl₄ on the outermost part and inside of the catalyst particles. CONCLUSION: The Mg(OEt)₂‐based Ziegler–Natta catalyst is believed to show highly stable polymerization activity and good replication because of the uniform titanium distribution all over the catalyst particles. Copyright © 2008 Society of Chemical Industry     

Effect of silanized silica nanofiller on tack and green strength of selected filled rubbers

BACKGROUND: Tack and green strength of filled and gum (unfilled) natural rubber (NR), poly(styrene‐co‐butadiene) rubber (SBR), polybutadiene rubber (BR) and (SBR‐BR) blend with different loadings of reinforcement agent, silanized silica nanofiller (Coupsil 8113), were studied and the results compared and discussed. RESULTS: It was found that silica was fully dispersed in rubber matrix after 13 min of mixing. In addition, with some exceptions for NR and (SBR‐BR) blend, filler loading decreased the tack strength of the studied filled rubbers. Green strength and Mooney viscosity increased with filler loading for all studied filled rubbers but with different rates and amounts. The optimum filler loadings for NR and (SBR‐BR) filled blend were 30 and 10 phr, respectively. Tacks of NR filled rubbers were much higher than those of synthetic filled rubbers. CONCLUSION: It was concluded that filler loading alters substantially the tack and green strength of the rubbers under investigation. Copyright © 2009 Society of Chemical Industry     

Chemical desulfurization of petroleum fractions for ultra-low sulfur fuels

An improved desulfurization process for removing sulfur from hydro treated diesel oil based on the oxidation of thiophenic type sulfur-containing compounds with H₂O₂ and acetic acid (AcOH) using H₂SO₄ as catalyst has been studied. The experimental results show that the sulfone content in the oxidation product increased rapidly with an increase in acetic acid and sulfuric acid ratios from 1:0 to 2:1 mole ratios. The maximum DBT conversion (wt.%) was at 2:1 mole ratio of acetic acid/sulfuric acid. This oxidation process is found to be capable of removing up to 90% of the sulfur compounds in hydro treated real fuels and can provide an alternative way to meet the future sulfur environmental requirements.     

Application of pulse detonation technology for boiler slag removal

Pulse detonation technology for removing slag and fouling deposits in coal-fired utility power plant boilers offers great potential. This technology offers a potentially convenient, inexpensive, yet efficient way for on-line slag removal. This paper presents a feasibility study that includes both Computational Fluid Dynamics (CFD) simulations and laboratory experiments. CFD simulations provided visual and quantitative data to study the potential mechanisms for removal of slag. Mechanisms included direct impact, flow scrubbing, wave reflection and negative velocity impact on the back side of the tubes. Several experiments were carried out to verify the potential of the pulse detonation technology. Experiments were done using a pulse detonation engine and heat exchanger tubes with different types of slag placed in different orientations on the tubes. Tubes were placed at various distances from the detonation tube and in different configurations. The results present a strong case for the application of this technology for online slag removal. It is especially effective for removal of slag on the back sides of the tubes where other traditional methods are not very successful. A preliminary cost analysis indicated that the technology can be paid for within the first year itself and provide substantial savings in the subsequent years.     

Microbial conversion of androst‐1,4‐dien‐3,17‐dione by Mucor racemosus to hydroxysteroid‐1,4‐dien‐3‐one derivatives

BACKGROUND: A large number of bacterial, fungal and microalgal species are able to bio‐transform steroid compounds. Among them, fungi from the Mucor genus have been shown to mediate hydroxylation, oxidation, and desaturation by the double bond formation and epoxidation of various steroid substances. Mucor racemocus has not been studied for its ability to modify androst‐1,4‐dien‐3,17‐dione, a pharmaceutically important steroid precursor. RESULTS: The filamentous fungus M. racemosus was applied for bioconversion of androst‐1,4‐dien‐3,17‐dione (ADD, I ) in a 5‐day fermentation. Microbial metabolites were purified chromatographically and identified on the basis of their spectral data as 17β‐hydroxyandrost‐1,4‐dien‐3‐one ( II ), 14α‐hydroxyandrost‐1,4‐dien‐3,17‐dione ( III ), 15α‐hydroxyandrost‐1,4‐dien‐3,17‐dione ( IV ), 15α,17β‐dihydroxyandrost‐1,4‐dien‐3‐one ( V ), 14α,17β‐dihydroxyandrost‐1,4‐dien‐3‐one ( VI ), and 6β,17β‐dihydroxyandrost‐1,4‐dien‐3‐one ( VII ). CONCLUSION: Observed modifications included hydroxylation at C‐6β, C‐14α, C‐15α positions and 17‐carbonyl reduction. The best fermentation conditions for production of hydroxysteroid‐1,4‐dien‐3‐one derivatives were found to be 25 °C at 150 rpm for 5 days with a substrate concentration of 0.5 g L^?1. Copyright © 2009 Society of Chemical Industry     

Biodegradation kinetics of trans‐4‐methyl‐1‐cyclohexane carboxylic acid in continuously stirred tank and immobilized cell bioreactors

BACKGROUND: Naphthenic acids are carboxylic acid compounds of oil sands wastewaters that contribute to aquatic toxicity. Biodegradation kinetics of an individual naphthenic acid compound in two types of continuous‐flow bioreactors were investigated as a means of improving remediation strategies for these compounds. RESULTS: This study evaluates the kinetics of biodegradation of trans‐4‐methy‐1‐cyclohexane carboxylic acid (trans‐4MCHCA) using two bioreactor systems and a microbial culture developed in previous work. Using a feed concentration of 500 mg L^?1 the biodegradation rate of trans‐4MCHCA in the immobilized cell bioreactor was almost two orders of magnitude higher than that in a continuously stirred tank bioreactor. The maximum reaction rates of 230 mg (L d)^?1 at a residence time of 1.6 d (40 h) and 22 000 mg (L d)^?1 at a residence time of 2.6 h were observed in the continuously stirred tank and immobilized cell bioreactors, respectively. In a second immobilized cell system operating with a feed concentration of 250 mg L^?1, a comparable maximum reaction rate (21 800 mg (L d)^?1) was achieved at a residence time of 1.0 h. CONCLUSION: The use of immobilized cell bioreactors can enhance the biodegradation rate of naphthenic acid compounds by two orders of magnitude. Further, biodegradation greatly reduces the toxicity of the effluent wastewater. Copyright © 2009 Society of Chemical Industry