Mechanism of Thermal Decomposition of Rare Earth Acetate Hydrates

The mechanism of thermal decomposition of rare earth acetate hydrates(Ln(Ac)_3·nH_2O,n=5,forLn=La;n=4,for Ln=Pr→Lu,Y,except Pm)has been studied by TG-DTG,DSC,infrared spectra,X-raydiffraction and chemical analysis.The thermal decomposition reaction consists of two stages,one is dehydrationand the other one is decompostion.The final product is oxide.It has been found that the temperature of pro-ducing anhydrous acetates decreases with increasing atomic number of rare earth elements.The activation ener-gies for dehydration and decomposition reaction of rare earth acetate hydrates have been calculated byFreeman-Carroll and Kissinger method.The dependence of activation energy Jor dehydration reaction on theatomic number of rare earth elements shows“inclined‘W’effect”.The enthalpy changes for dehydration anddecomposition reaction have been determined.     

基于GPRS+WEB分散点工业数据采集与监控

探讨在分散式工业采集现场,如何将各种类型的传感器数据采用统一有效的数据形式,通过GSM网络的GPRS业务,传递至INTERNET上具有固定IP地址的服务器中,进行统一的数据库管理。终端授权用户可以通过WEB页浏览的方式,方便快捷地浏览数据库中的内容。完成一套实现对小数据量分散数据采集点的有效监控方案。重点讨论数据采集部分(RTU)的数据协议规划和针对恶劣工业环境下具有GPRS退出机制的服务流程。对附着于GSM网络上的GPRS业务也做相关的介绍。     

Integration of Biomolecules with Metal–Organic Frameworks

Owing to the progressive development of metal–organic‐frameworks (MOFs) synthetic processes and considerable potential applications in last decade, integrating biomolecules into MOFs has recently gain considerable attention. Biomolecules, including lipids, oligopeptides, nucleic acids, and proteins have been readily incorporated into MOF systems via versatile formulation methods. The formed biomolecule‐MOF hybrid structures have shown promising prospects in various fields, such as antitumor treatment, gene delivery, biomolecular sensing, and nanomotor device. By optimizing biomolecule integration methods while overcoming existing challenges, biomolecule‐integrated MOF platforms are very promising to generate more practical applications.     

ICP—AES法测定硼酸钆铝激光晶体中Nd的含量

应用 ICP—AES 法测定硼酸钆铝激光晶体中的 Nd。在石英坩埚650℃用 KHSO_4分解样品,Tm 被选择作内标元素。回收率为97—102%,相对标准偏差为2.4%。方法简便,可获得满意的分析结果。     

新型氨基化磁性树状分子纳米颗粒的制备与表征

采用化学共沉淀法,以FeC13.6H2O和FeSO4·7H2O为原料制备磁性Fe3O4纳米颗粒,采用3-氨丙基三乙氧基硅烷(APTES)、丙烯酸丁酯(BA)和无水乙二胺(EDA)对其进行修饰,制备了三代表面氨基化的磁性Fe3O4树状分子纳米颗粒,并对其进行结构表征与性能测试.结果表明:树状分子逐代修饰在磁性颗粒表面,氨基含量逐代增加,分别为0.41、0.69和0.87mmol/g; Fe3O4纳米颗粒平均尺寸在12nm左右,修饰后的三代磁性纳米颗粒的粒径逐代增加,分别为14、27和40nm左右;三代产品仍具备较高的饱和磁化强度,展现出了典型的超顺磁性.这种氨基功能化的磁性纳米粒子在细胞分选、固定化酶和靶向药物等诸多领域有着巨大应用潜力.     

表面沉积铜纳米颗粒的细菌纤维素/壳聚糖交联复合膜的制备及其抗菌性能研究

通过戊二醛交联制备了细菌纤维素/壳聚糖复合材料,并采用磁控溅射技术在交联复合膜表面沉积铜(Cu)纳米颗粒。利用扫描电子显微镜观察纳米纤维膜表面形貌,采用傅里叶红外光谱仪、热重分析仪和X射线衍射仪比较交联复合前后以及镀铜前后复合膜基本化学结构、热稳定性和晶面结构的变化。通过能量色散X射线光谱对壳聚糖和铜在复合膜表面的分布情况进行表征。同时借助抗菌实验探究复合膜对金黄色葡萄球菌和大肠杆菌的抗菌能力。结果表明:壳聚糖与细菌纤维素发生了有效交联,改变了细菌纤维素的基本形貌、化学结构、晶体形态以及热学性能,并且镀铜后交联复合膜的抗菌性能得到了明显的提升(膜与细菌接触20min,对金黄色葡萄球菌和大肠杆菌的抗菌效果均达到了99.999%)。     

A novel low-complexity power allocation algorithm based on the NOMA system in a low-speed environment

For future wireless communication systems, Power Domain Non-Orthogonal Multiple Access (PD-NOMA) using an advanced receiver has been considered as a promising radio access technology candidate. Power allocation plays an important role in the PD-NOMA system because it considerably affects the total throughput and Geometric Mean User Throughput (GMUT) performance. However, most existing studies have not completely accounted for the computational complexity of the power allocation process when the User Terminals (UTs) move in a slow fading channel environment. To resolve such problems, a power allocation method is proposed to considerably reduce the search space of a Full Search Power (FSP) allocation algorithm. The initial power reallocation coefficients will be set to start with former optimal values by the proposed Lemma before searching for optimal power reallocation coefficients based on total throughput performance. Step size and correction granularity will be adjusted within a much narrower power search range while invalid power combinations may be reasonably discarded during the search process. The simulation results show that the proposed power reallocation scheme can greatly reduce computational complexity while the total throughput and GMUT performance loss are not greater than 1.5% compared with the FSP algorithm.     

粉煤灰/二氧化硅活性剂在Q235钢A-TIG焊中的应用

为了探究粉煤灰作为A-TIG焊活性剂的可行性,以粉煤灰和不同含量的二氧化硅制备复合活性剂在Q235钢基体表面进行A-TIG焊,研究了复合活性剂成分含量对焊缝截面形貌、显微组织和元素分布的影响.结果表明:采用粉煤灰-40%SiO_2作为复合活性剂进行A-TIG焊时,可将6 mm厚Q235钢板一次性焊透,焊缝深宽比可达到0.85;焊缝出现明显的中间收缩倾向,呈"深口杯"状,可实现单道焊双面成型的效果;其焊缝柱状晶数目较多、组织排列规则且具有方向性,熔合区和热影响区组织均匀细小,可降低焊接母材的过热倾向;相对于100%SiO_2活性剂,Si元素的溶入量和溶入深度显著增加,这说明粉煤灰中其他成分的存在对Si元素溶入焊缝、进而增加焊缝熔深起到促进作用.采用粉煤灰-40%SiO_2为活性剂进行A-TIG焊时焊缝熔深的增加机理可能是以电弧收缩理论为主,但考虑到Al元素溶入较深且溶入量较多,粉煤灰中其他物相又十分复杂,在高温电弧作用下各物相之间相互反应放热致使电弧热输入增加、其他组分在熔池中改变了熔池表面张力温度梯度等均可能致使焊缝熔深增加.     

氮化硅结构研究中的重要发现

在利用高分辨电子显微术研究 Si_3N_4结构过程中,有了新的发现。这些发现包括纳米级裂纹、超结构、纳米畴和辐射损伤等。纳米级裂纹是晶粒中纳米大小的裂纹,它可能是导致穿晶断裂的裂纹。超结构可能影响Si_3N_4晶粒的力学性能,我们在研究中发现了三种超结构。纳米畴是晶粒中一种新的结构缺陷,在研究中我们发现了两种这类畴。也研究了辐射损伤,发现 α-Si_3N_4比β-Si_3N_4更易于受到辐射损伤,这说明β-Si_3N_4比α-Si_3N_4结构更稳定。还仔细地研究了 Si_3N_4陶瓷的晶界,结果指出,晶界工程对于改善 Si_3N_4陶瓷的力学性能是强有力的手段。