制备Fe_4N磁粉的优化工艺研究

本文是在固定床反应器中由γ-Fe2O3制备Fe4N磁粉优化工艺的实验研究，通过正交试验法得出了获得高质量Fe4N磁粉的优化工艺参数．     

氟硅酸溶液中氟硅酸及氢氟酸含量的测定

基于生成氟硅酸钾沉淀和该沉淀水解均析出不同量酸，用碱滴定完成氟硅酸及氢氟酸的连续测定。该方法用于生产实践，结果令人满意。     

A Spatial Cognitive Model that Integrates the Effects of Endogenous and Exogenous Information on the Hippocampus and Striatum

Machine Intelligence Research - Reproducing the spatial cognition of animals using computational models that make agents navigate autonomously has attracted much attention. Many biologically...     

基于功能覆盖率的MAC的UVM验证

论文基于UVM验证方法学,以及覆盖率驱动的芯片验证指导思想,搭建并分析了高度可重用的以太网控制器IP的验证平台.为了提高验证效率,论文对MAC的工作流程进行了研究,对其功能点进行了划分,针对性地编写了测试用例.在测试用例的驱动下,对MAC的数据收发功能进行了全流程的仿真验证.在大规模随机测试用例和定向测试用例的共同作用下,加快了验证所需要的时间,节省了仿真所需的计算机资源,达到了功能覆盖率100％的目标.     

海相沉积淤泥复合固化强度的试验研究

针对现有淤泥固化试验采用的固化剂相对单一的问题,为了系统研究多材料固化滨海沉积淤泥强度特性,以唐山南堡典型滨海沉积淤泥为研究对象,通过对比单掺、双掺及三掺等固化剪切强度,结合粉煤灰废物利用问题,系统研究了水泥、生石灰及粉煤灰等不同固化剂组合对滨海相沉积淤泥固化强度的影响。结果表明:不同固化剂对滨海相沉积淤泥抗剪强度影响的差异较为明显,抗剪强度基本随掺加固化剂的种类增加而增加,掺加6%生石灰、10%水泥和6%粉煤灰28 d龄期的固化淤泥抗剪强度最高,其黏聚力为238.4 kPa、内摩擦角为32.94°;抗剪强度指标的提高随龄期的变化存在差异,即淤泥单掺生石灰抗剪强度指标的提高主要在养护后期,施工中可适当增加闷料时间以使生石灰和淤泥颗粒反应充分;采用水泥来固化淤泥可在短期内明显提高强度,在高含水率的淤泥材料施工中有更好的工程效果;固化剂掺量相同情况下,抗剪强度随着龄期增长而增加。研究成果对滨海沉积淤泥的固化和工程应用具有参考价值。     

A Hybrid Model Based on Variational Mode Decomposition and Gradient Boosting Regression Tree for Monthly Runoff Forecasting

Water Resources Management - Accurate and reliable monthly runoff forecasting is of great significance for water resource optimization and management. A neoteric hybrid model based on variational...     

Influence of deposition pressure on properties of ZnO: Al films fabricated by RF magnetron sputtering

Transparent conductive aluminum doped zinc oxide(ZnO:Al,AZO) films were prepared on glass substrates by rf(radio frequency) magnetron sputtering from ZnO: 3wt% Al_2O_3 ceramic target. The effect of argon gas pressure(PAr) was investigated with small variations to understand the influence on the electrical, optical and structural properties of the films. Structural examinations using X-ray diffraction(XRD) and scanning electron microscopy(SEM) showed that the ZnO:Al thin films were(002) oriented. The resistivity values were measured by four-point probe with the lowest resistivity of 5.76×10~(-4) Ω?cm(sheet resistance=9.6 Ω/sq. for a thickness=600 nm) obtained at the PAr of 0.3 Pa. The transmittance was achieved from ultravioletvisible(UV-VIS) spectrophotometer, 84% higher than that in the visible region for all AZO thin films. The properties of deposited thin films showed a significant dependence on the PAr.     

洋流干扰下的多自主水面无人船最优覆盖控制

针对洋流干扰下的多自主水面无人船(ASV)对有限海洋环境进行覆盖监控的最优化问题,提出一种基于环境信息密度的分布式控制方法。该控制方法是在考虑洋流因素的情况下,以二阶EulerLagrange模型为控制模型的最优覆盖策略。首先建立基于欠驱动系统的最优覆盖模型,提出时变洋流干扰下的多ASV最优区域分配算法。在此基础上,针对ASV的欠驱动特性,综合应用运动学控制方法与Backstepping技术设计基于二阶Euler-lagrange方程的最优覆盖控制算法,并利用Lyapunov稳定性理论证明其稳定性。最后对多ASV最优覆盖网络进行仿真验证实验,实验结果表明该控制方法能够使多ASV在洋流干扰下从区域Q的任意初始位置收敛到最优覆盖配置。     

Kinetics simulation of propylene epoxidation over different Ti species in TS-1

A thorough experimental investigation on the kinetic behavior of liquid-phase propylene epoxidation over TS-1 and tetrapropylammonium hydroxide (TPAOH) treated TS-1 catalysts was conducted in a fixed-bed reactor. The amounts of different coordinated Ti species in the catalysts were quantified by spectroscopies, and their catalytic performances of the epoxidation and alcoholysis of propylene oxide were measured by kinetic modeling. The study shows that the TPAOH treatment converted some of the tetrahedrally coordinated Ti to octahedrally coordinated Ti, and both species were active for the epoxidation and alcoholysis. The superior catalytic performance observed over the TPAOH treated TS-1 is due to two factors, the increased percentage of active sites, and reduced energy barrier for epoxidation on the octahedrally coordinated Ti. In addition, as the H₂O₂ conversion increases, the adsorption equilibrium constant of propylene oxide plays a more decisive role than the activation energy for the selectivity of propylene glycol monomethyl ethers.     

新型非离子型水性环氧固化剂的合成及性能研究

为提高水性环氧涂料的固化性能和适用期,以自制聚酰胺和生物基戊二胺为起始原料,聚乙二醇二缩水甘油醚（ PEGGE）为亲水链段,双酚 A型环氧树脂（ E-51）为疏水链段,邻甲苯缩水甘油醚（ CGE）为封端剂制备了非离子型低温水性环氧固化剂,并与自制水性环氧乳液复配制得双组分水性环氧涂料。考察了环氧固化剂合成工艺参数及涂膜各项性能。结果表明：该固化剂含有较长的柔性脂肪烃碳链和聚醚链段能够提高涂膜的柔韧性;双酚 A型环氧树脂参与扩链反应能够解决与乳液不兼容等问题;苯环结构增加了涂膜的硬度;涂膜室温固化后性能优异,具有良好的物理机械性能、耐水性、耐酸碱性和耐盐雾性。