新型捕收剂N—十二烷基—1，3—丙二胺浮选铝硅酸盐类矿物的机理

以十二胺和丙烯腈为原料,常压下合成了阳离子捕收剂N-十二烷基-1,3-丙二胺(DN12),考察了其对高岭石、叶蜡石、伊利石的浮选行为.结果表明DN12的捕收性能优于十二胺;DN12的浓度为3×10-4mol@L-1时,对3种铝硅酸盐矿物的浮选回收率均超过80%,对3种铝硅酸盐矿物的捕收能力顺序为高岭石＞叶蜡石＞伊利石;浮选pH范围为5～8.动电位和红外光谱说明DN12与铝硅酸盐类矿物形成了氢键并产生静电吸附,且作用较强.     

河口海岸全沙模型相似理论

在讨论潮流和波浪的基本方程式及其相似条件之后，阐述了本文作者 近年来的潮流和波浪作用 下泥沙运动 基本规律方面取得的 研究成果。在此基础上，提出了悬沙和底沙物理模型的相似理论，特别是全沙变态模型的相似理论，按此相似理论，可在一个模型中进行潮流与波浪共同作用下的全沙试验。     

风洞边壁对挟沙气流流速分布的影响

鉴于现有挟沙气流流速分布研究中对风洞边壁影响的认识不足，本文通过改变风洞宽度的方法对风洞边壁的影响进行了探索性实验研究。在五种宽高比条件下，对风洞断面挟沙气流流速分布进行了测量。发现风洞边壁对挟沙气流流速分布有较为明显的影响。在风洞宽度比相同的条件下，断面内中垂线上的有效粗糙度系数大于其它垂线上对应的系数。从靠近边壁的垂线到断面中垂线，各垂线对应的跃移层内区及外区流速分布的上界高度、气流摩阻速度均逐渐增大。随着风洞宽高比的减小，断面内中垂直线上的气流摩阻速度与自由流速的比值以及受风洞边壁影响的气流厚度均增大。     

遥感和GIS在干旱和半干旱地区水资源管理中的应用

介绍遥感、GIS(地理信息系统 )等高新技术在干旱和半干旱地区水资源管理中的应用 ,包括水资源调查 ,旱情与墒情的监测管理和预警 ,沙漠化的动态监测以及治沙止漠效益评价 ,生态的动态监测和生态需水量估算 ,退耕还林还草的遥感调查 ,灌溉面积调查与灌区发展规划 ,土地盐渍化监测 ,水环境监测 ,水利工程的规划、建设与管理 ,以及水资源实时监测管理系统等 .     

Microwave assisted click chemistry on a conductive polymer film

Microwave (MW) irradiation has been used to accelerate the functionalization of an azide functional poly(3,4-ethylenedioxythiophene) film by click chemistry. The absorption of MW energy by the conductive polymer has been exploited for localized activation of the reaction on the polymer surface. By use of an alkyne modified fluorescein derivative the reaction conditions have been optimized in a conventional MW oven, enabling the use of different sizes of substrates. The optimization resulted in a reduction of reaction times of approximately 20 h to only 2 min for bulk film functionalization. The method has been applied for anchoring of the chelating agent nitrilotriacetic acid (NTA) on the conductive polymer. The chelating linkage ability of NTA on the surface was investigated through a sandwich ELISA study confirming the selective bonding of a histidine tagged protein.     

Container loading with multi-drop constraints

In this paper, an algorithm for the container-loading problem (CLP) with multi-drop constraints is presented. When adding multi-drop constraints, we demand that the relevant boxes must be available, without rearranging others, when each drop-off point is reached. To make the solutions feasible in the real world, it is further demanded that all boxes are placed in a feasible manner with respect to load-bearing strength and with proper support from below. This makes it possible to load consignments originating from builder merchants. A heuristic based on a tree search framework is proposed. It uses greedy solutions to evaluate each choice taken. To make the framework more generic, a dynamic breadth is proposed. Based on problem characteristics and the time limit imposed, it will choose the breadth of the tree, making sure that the time is utilised most profitably. The algorithm is tested on new real-world data from a Danish company distributing construction products. For the solutions to these problems to be feasible in a real-world setting, both multi-drop and load-bearing strength constraints are essential. The obtained results show that the proposed model and algorithm are able to solve the new real-world problems in fractions of a second. Furthermore, results obtained on benchmark problems indicate that the algorithm performs comparably with other more specialised methods.     

Mathematical modeling of photoinitiated coating degradation: Effects of coating glass transition temperature and light stabilizers

A mathematical model, describing coating degradation mechanisms of thermoset coatings exposed to ultraviolet radiation and humidity at constant temperature, was extended to simulate the behavior of a coating with a low glass transition temperature. The effects of adding light stabilizers (a UV absorber and a radical scavenger) to the coating were also explored. The extended model includes photoinitiated oxidation reactions, intrafilm oxygen permeability, water absorption and diffusion, reduction of crosslink density, absorption of ultraviolet radiation, a radical scavenger reaction, and simulates the transient development of an oxidation zone. Simulations are in good agreement with experimental data for a fast degrading epoxy-amine coating with a glass transition temperature of −50 °C. It was found that the degradation rate of the non-stabilized coating was influenced significantly by the diffusion rate of oxygen in the oxidation zone, whereas light absorption by the photoproducts formed was only a secondary effect. On the other hand, the degradation rate of the stabilized coating was mainly influenced by the light absorption capability of the coating and in this case there was no oxygen diffusion resistance. Finally, simulations showed that the rate constants of the photoinitiating and oxidation reactions, taking place within the epoxy-amine family of coatings, are strong functions of the specific crosslinker used and must be estimated, in each case, by calibration of the model against adequate experimental data series.     

Effect of the initial dose of foot-and-mouth disease virus on the early viral dynamics within pigs

This paper investigates the early viral dynamics of foot-and-mouth disease (FMD) within infected pigs. Using an existing within-host model, we investigate whether individual variation can be explained by the effect of the initial dose of FMD virus. To do this, we consider the experimental data on the concentration of FMD virus genomes in the blood (viral load). In this experiment, 12 pigs were inoculated with one of three different doses of FMD virus: low; medium; or high. Measurements of the viral load were recorded over a time course of approximately 11 days for every 8 hours. The model is a set of deterministic differential equations with the following variables: viral load; virus in the interstitial space; and the proportion of epithelial cells available for infection, infected and uninfected. The model was fitted to the data for each animal individually and also simultaneously over all animals varying only the initial dose. We show that the general trend in the data can be explained by varying only the initial dose. The higher the initial dose the earlier the development of a detectable viral load.     

横置螺旋簧隔振器非线性弹性参数的计算

针对横置螺旋簧隔振器的大位移小形变问题,在Mottershead线性螺旋杆单元和牛顿-拉斐逊带动坐标迭代法的基础上,计算拟合了隔振器位移与载荷的关系式.结果表明,隔振器主工作方向上刚度是受压时变软受拉时变硬明确了二次非线性的存在.并与直杆单元的计算结果和实验结果进行了比较