热处理对粉末注射成形钛合金的组织与性能的影响

采用粉末注射成形方法制备了钛合金坯体,利用溶剂脱脂和热脱脂方法脱除坯体中粘结剂,并在真空气氛下烧结致密钛合金样品.真空烧结后,经960℃和140MPa热等静压处理,在720~760℃进行1~1.5h退火处理获得的样品微观结构为均匀的双态组织,由许多等轴较小的α晶粒和少量尺寸较小的β晶粒组成.XRD分析结果表明,当退火温度高于800℃时,样品存在Ti₃Al杂质相.     

PLGA溶胶对多孔HA材料的填充性能研究

采用聚氨酯海绵作为模板,制备出多孔HA中间层.用溶胶浇铸法,将PLGA溶胶填充入多孔HA中间层里,制备出骨组织工程用PLGA/HA复合支架材料.制得的多孔HA中间层孔隙率高(80%～92%),孔径大(500～1000p.m),且有相互连通的孔结构.对PLGA溶胶填充性能的研究结果表明:溶胶粘度影响PLGA溶胶的填充性能,而粘度与浓度、时间、温度和pH值关系密切.当溶胶粘度为50mPa·s时,PLGA胶体的填充性能最好.     

Ekonol/G/MoS2/PEEK复合材料的制备和正交试验研究

用正交试验设计方法和模压方法制备了Ekonol／G／MoS2／PEEK复合材料，通过方差和极差分析方法对材料的耐磨性能进行了研究，并用扫描电镜对磨损表面形貌进行了观察和分析。结果表明，用模压法制备此复合材料是可行的，复合材料具有优良的耐磨性能，其最优制备方案为A5B3C3D3E3；正交试验设计方法、方差和极差分析方法是行之有效的复合材料研究方法。     

Aging characteristic and mechanical properties of TiC/2618 composite

1　ＩＮＴＲＯＤＵＣＴＩＯＮＸＤｍｅｔｈｏｄｉｓａｌｓｏｃａｌｌｅｄｔｈｅｉｎ ｓｉｔｕｓｙｎｔｈｅｓｉｚｅｄｍｅｔｈｏｄｏｒｉｇｉｎａｔｅｄｆｒｏｍＡｍｅｒｉｃａｉｎｔｈｅ 1980’ｓ[1,2 ] ,ｂｙｗｈｉｃｈａｍｅｔａｌｍａｔｒｉｘｃｏｍｐｏｓｉｔｅｃａｎｂｅｒｅｉｎｆｏｒｃｅｄｂｙｓｅｌｆ ｇｒｏｗｎｃｅｒａｍｉｃｐａｒｔｉｃｌｅｓ .Ｉｔｈａｓｔｈｅｃｈａｒａｃｔｅｒ ｉｓｔｉｃｓａｓｆｉｎｅａｎｄｄｉｓｐｅｒｓｉｏｎｒｅｉｎｆｏｒｃｅｍｅｎｔｉｎｔｈｅｃｏｍ ｐｏｓｉｔｅｇｏｏｄｂｏｕｎｄａｒｙｃｏ…     

MoSi2机械合金化过程的研究

通过ＸＲａｙ衍射分析、扫描电镜（ＳＥＭ）和透射电镜（ＴＥＭ）观察研究了ＭｏＳｉ２的机械合金化过程，指出ＭｏＳｉ２机械合金化过程可分为四个阶段：（１）初期活化性阶段；（２）活化性阶段；（３）合金化阶段；（４）微晶和非晶化阶段     

WSi_2/MoSi_2复合粉末材料的机械合金化合成

通过机械合金化和热处理工艺成功地制备了MoSi2 5 0 % (摩尔分数x)WSi2 复合粉末材料 ,利用X射线衍射手段分析了相的形成过程 ,并从热力学和球磨能量角度比较了MoSi2 和WSi2 相生成的难易程度。球磨 40h后在高于 10 0 0℃热处理可获得 (Mo ,W )Si2 合金 ;因G0(MoSi2 ) 相似文献   

Effect of relative density on cyclic oxidation resistance properties of MoSi2

MoSi2 powders were fabricated respectively by mechanical alloying technique and sintering at different temperatures to prepare materials with different relative densities. The relative oxidation behavior of all MoSi2 materials at 1 473 K was investigated by TGA,SEM and XRD. The results show that the ＂pesting＂ is not found in all materials after being oxidized for 480 h. The density has no essential relation to the ＂pesting＂. The oxidation curve of specimens with lower density shows two-step oxidation kinetics. Both the first stage （0-1 h） and the second stage （1-480 h） nearly obey linear kinetics,but the oxidation rates are obviously different. The oxidation kinetics of MoSi2 with higher relative density nearly follows parabolic law. The mass gains of MoSi2 with the lowest relative density （78.6%） and the highest relative density （94.8%） are increased by 10.390 and 0.135 mg/cm^2,respectively. The oxide scale of materials with lower densities is non-protective and makes the oxygen diffusion easy. A dense scale in the material with higher density is formed,which acts as a diffusion barrier to the oxygen atoms to penetrate into the matrix,showing much better high temperature oxidation resistance. The phases distribution of oxidation scale from the outside to the inside is SiO2→Mo5Si3→MoSi2.     

干摩擦条件下稀土-Mo5Si3/MoSi2复合材料的摩擦磨损性能

采用高温自蔓延合成了含0.8%稀土-5at%Mo5Si3/MoSi2复合材料粉末,经冷压和高温真空烧结成试样.在MRH-5A型环-块摩擦磨损试验机上,考察了其与调质45#钢配对时的摩擦磨损特性.运用带有微探针的JSM-5610LV型扫描电子显微镜,观察与分析了其磨损表面形貌和相的组成,探讨了该材料的磨损机理,结果表明在干摩擦同等条件下,稀土-Mo5Si3/MoSi2复合材料比纯MoSi2材料具有更好的抗磨损性能,其磨损率比纯MoSi2的至少降低了72%.在低pv值时,稀土-Mo5Si3/MoSi2复合材料的主要磨损失效形式为磨粒磨损和轻微粘着磨损而当pv值≥81.12 N·m/s,则主要为粘着磨损和疲劳断裂.     

自蔓延原位合成TiC/MOSi2复合材料及其力学性能

以钼、硅、钛和碳粉为原料,采用自蔓延原位合成技术制备了不同体积分数TiC强韧化的MoSi2基复合材料,研究了TiC颗粒对MoSi2基体材料显微组织和力学性能的影响.结果表明:TiC颗粒均匀分布于MoSi2基体中;TiC体积分数为30%时,TiC/MoSi2复合材料硬度、抗弯强度和断裂韧度分别达到15.02 GPa、366 MPa和6.26 MPa·m1/2,比纯MoSi2分别增加61.5%、26.8%和150%;复合材料的断口表现为沿晶断裂和准解理断裂的混合形式,其强化机制是细晶强化和弥散强化,韧化机制为细晶韧化.     

Dry Friction and Wear Characteristics of Rare-Earth／MoSiz Composite

The dry friction and wear characteristics of rare earth/MoSi2 composite against 45 steel under different loads were investigated by using an M-200 type friction and wear tester. SEM and XRD were used to analyze the morphology of the friction surface and the phase of worn piece in order to reveal the wear mechanism of rare-earth/MoSi2 composite. Results show that the relationships of friction coefficient, μ, or wear rate, W, of MoSi2 and RE/MoSi2 composite to loads,p, can be fitted well with the following function: μ (or W) = a bp cp2 dp3 ep4, where a, b, c, d and e are fitting constants depending on materials and confidence. MoSi2 and rare-earth/MoSi2 composite have excellent wear resis-tance. When load is in the range of 80 - 120 N, the wear rate of RE/MoSi2 composite is lower than that of MoSi2 materialby about 65 %. The main wear mechanism of rare-earth/MoSi2 composite is adhesive wear.