STUDY ON α/γ PHASE EQUILIBRIUM IN Ti-Al-Cr-Fe QUARTERNARY SYSTEM

设计了一种简单的扩散偶,用扩散偶－电子探针法,测定了１２００和１２５０℃Ｔｉ－Ａｌ－Ｃｅ－Ｆｅ四元系中Ｘｃｒ≤４％和ＸＦｅ≤１％范围内的α／γ相平衡关系和相平衡成分,绘出了四元系的局部等温正方形,结果表明,在Ｔｉ－Ａｌ－Ｃｒ－Ｆｅ四元系中,Ｃｒ有提高Ｆｅ在α相中的溶解度的作用,Ｆｅ亦有提高Ｃｒ在α相中的溶解度的趋势。     

钢中碳活度对碳化物覆层扩散处理动力学的影响

本研究选用了几种在扩散温度下为单相奥氏体的钢种,在同样的处理条件下测定了碳化物层的生长速度,并计算了各钢在处理温度下的奥氏体碳活度。结果表明,碳化物层的厚度与奥氏体中的碳活度的平方根成线性关系,从而证明了碳化物层生长动力学的控制因素是钢基体中的碳活度而不是碳浓度。     

Partial phase relationships of Mg-Zn-Ce system at 350℃

The alloys were prepared in Mg-rich corner of Mg-Zn-Ce system. Partial phase equilibrium relationships of these alloys at 350 ℃ were identified by using scanning electron microscopy(SEM), electron probe microanalysis(EPMA), X-ray diffraction(XRD) analysis and selected area electron diffraction(SAED) pattern analysis of transmission electron microscopy(TEM). Partial isothermal section of Mg-Zn-Ce system in Mg-rich corner was identified. The results show that there is one ternary compound (T-phase) in Mg-Zn-Ce system. The T-phase is a linear ternary compound in which the content of Ce is about 7.7% (molar fraction); while the content of Zn is changed from 19.3% to 43.6% (molar fraction). The crystal structure of T-phase is C-centered orthorhombic. In addition, one two-phase region of Mg+T-phase and one three-phase region of Mg+T-phase+MgZn(Ce) exist in the Mg-rich corner of Mg-Zn-Ce system at 350 ℃.     

TiAl基双相合金相变的组织学研究

应用光学显微镜、透射电镜及X射线衍射研究了Ti—42at.—%Al和Ti—45at.—%Al两种合金的固溶处理后的快冷组织,证明其为过饱和的有序α_2单相组织,过饱和单相在1000-1100℃等温转变时,以准连续和不连续的机制分解成为γ+α_2两相。准连续转变中包括γ片析出和胞状化两个阶段,并在原始α_2晶界处形成锯齿形边界。     

集团变分法(CVM)及其在合金相图计算中的应用

介绍了集团变分法的集团概率变量、配置熵等统计分析的理论基础及Helmholtz自由能的描述模型.提出了巨势及相对化学势的几何分析理论.讨论了应用集团变分法和巨势分析理论进行相平衡计算的过程,并分析了同结构平衡相图计算的若干实例.     

Al-Zn(Cu)合金的相变和Al-Zn-Cu系相图

Al-Zn-Cusystemistheimportantbasisfor practicalAlalloysandZnalloys[1].Amiscibility gapofthefccphaseexistsabove277℃inthe Al Znsystem[2].Thealloywhosecompositionis atthetopofthemiscibilitygapiscalledsym metricalalloyAlZn.Thisalloyhasmanytypical properties.Theimportantoneisthatthespi nodaldecompositioneasilytakesplaceinit.In ordertoavoidthedecomposition,Cuhasbeen added,whichiseffective.Additionof2%Cu molefractioncoulddelaythespinodaldecompo sitionfortwogrades[3,4].AlZn 2Cuisanalloy which…     

共析钢中片层状渗碳体冷轧后的形态变化

The pearlitic transformation and the deformation behavior of lamellar cementite after cold rolling in eutectoid steels Fe-0. 76%C-0. 137%Mn (mass fraction) were studied by means of Formastor-F (Full Automatic Transformation Testing Instrument) and field emission scanning electronic microscopy (FESEM) observation. Fine and coarse pearlite were obtained in the eutectoid steels austenitized at 900℃ for 15min, then hold at 620℃ for 90 s and 690℃ for 7 h, respectively. Thedeformation behavior of cold rolled lamellar cementite could be classified as: cleavage fracture, inhomogeneous slip, fragmentation, thinning or necking, and homogeneous bending. The cementite lamellae with the thickness of more than 100 um could be deformed plastically.     

AN ISOBAR-ISOTHERMAL PHASE DIAGRAM OF THE Nd-Fe-B SYSTEM AT ATMOSPHERIC PRESSURE AND 1000℃

An isothermal section of Nd-Fe-B system at 1000℃ and the phase equilibrium relationship in Fe-Ndand Nd-B binary systems were investigated with diffusion couple by means of metallographic observation,electron microprobe analysis and X-ray diffraction.It was shown that there are three stable ternary com-pounds,Nd_2Fe_(14)B,Nd_2Fe_7B_6 and Nd_9Fe_3B_8 in Nd-Fe-B system at 1000℃.None of these phases has solu-bility,that is,they are exactly stoichiometric phases.On the other hand,there exist rather wide two-phaseregions between Nd_2Fe_7B_6 and liquid as well as between Nd_9Fe_3B_8 and liquid.It was identified that there isno NdFe_2 compound in the system under atmospheric pressure.     

ISOTHERMAL SECTION AT 1000 AND 1100℃ OF Fe-Mn-AI SYSTEM PHASE DIAGRAM

利用扩散偶技术和合金法测定了Fe-Mn-Al三元系1000和1100℃等温截面的Fe-Mn侧的相平衡关系,结果表明1000℃有一(α+y+β)三相区,此外,固/气扩散偶被用来测定相平衡成分,表明这种方法对于具有挥发性组元的体系是可行的。