Carbon‐Nanotube–PDMS Composite Coatings on Optical Fibers for All‐Optical Ultrasound Imaging

Polymer–carbon nanotube composite coatings have properties that are desirable for a wide range of applications. However, fabrication of these coatings onto submillimeter structures with the efficient use of nanotubes has been challenging. Polydimethylsiloxane (PDMS)–carbon nanotube composite coatings are of particular interest for optical ultrasound transmission, which shows promise for biomedical imaging and therapeutic applications. In this study, methods for fabricating composite coatings comprising PDMS and multiwalled carbon nanotubes (MWCNTs) with submicrometer thickness are developed and used to coat the distal ends of optical fibers. These methods include creating a MWCNT organogel using two solvents, dip coating of this organogel, and subsequent overcoating with PDMS. These coated fibers are used as all‐optical ultrasound transmitters that achieve high ultrasound pressures (up to 21.5 MPa peak‐to‐peak) and broad frequency bandwidths (up to 39.8 MHz). Their clinical potential is demonstrated with all‐optical pulse‐echo ultrasound imaging of an aorta. The fabrication methods in this paper allow for the creation of thin, uniform carbon nanotube composites on miniature or temperature‐sensitive surfaces, to enable a wide range of advanced sensing capabilities.     

Long Distance Enhancement of Nonlinear Optical Properties Using Low Concentration of Plasmonic Nanostructures in Dye Doped Monolithic Sol–Gel Materials

Monolithic sol–gel silica composites incorporating platinum‐based chromophores and various types of gold nanoparticles (AuNPs) are prepared and polished to high optical quality. Their photophysical properties are investigated. The glass materials show well‐defined localized surface plasmon resonance (SPR) absorbance from the visible to NIR. No redshifts of the AuNP plasmon absorption peaks due to the increase in nanoparticle doping concentration are observed in the glasses, proving that no or very small SPR coupling effects occur between the AuNPs. At 600 nm excitation, but not at 532 nm, the AuNPs improve the nonlinear absorption performance of glasses codoped with 50 × 10^?3 m of a Pt‐acetylide chromophore. The glasses doped with lower concentrations of AuNPs (2–5 μm average distance) and 50 × 10^?3 m in chromophore, show a marked improvement in nonlinear absorption, with no or only small improvement for the more highly AuNP doped glasses. This study shows the importance of excitation wavelength and nanoparticle concentration for composite systems employing AuNPs to improve two‐photon absorption of chromophores.     

Complexity bounds for the rational Newton-Puiseux algorithm over finite fields

We carefully study the number of arithmetic operations required to compute rational Puiseux expansions of a bivariate polynomial F over a finite field. Our approach is based on the rational Newton-Puiseux algorithm introduced by D. Duval. In particular, we prove that coefficients of F may be significantly truncated and that certain complexity upper bounds may be expressed in terms of the output size. These preliminary results lead to a more efficient version of the algorithm with a complexity upper bound that improves previously published results. We also deduce consequences for the complexity of the computation of the genus of an algebraic curve defined over a finite field or an algebraic number field. Our results are practical since they are based on well established subalgorithms, such as fast multiplication of univariate polynomials with coefficients in a finite field.     

Compound Node–Kayles on paths

In his celebrated book [J.H. Conway, On Numbers and Games, Academic Press, New-York, 1976, Second edition (2001), A.K. Peters, Wellesley, MA], J.H. Conway introduced twelve versions of compound games. We analyze these twelve versions for the Node–Kayles game on paths. For usual disjunctive compound, Node–Kayles has been solved for a long time under normal play, while it is still unsolved under misère play. We thus focus on the ten remaining versions, leaving only one of them unsolved.     

Analysis of DNA Replication by Optical Mapping in Nanochannels

DNA replication is essential to maintain genome integrity in S phase of the cell division cycle. Accumulation of stalled replication forks is a major source of genetic instability, and likely constitutes a key driver of tumorigenesis. The mechanisms of regulation of replication fork progression have therefore been extensively investigated, in particular with DNA combing, an optical mapping technique that allows the stretching of single molecules and the mapping of active region for DNA synthesis by fluorescence microscopy. DNA linearization in nanochannels has been successfully used to probe genomic information patterns along single chromosomes, and has been proposed to be a competitive alternative to DNA combing. Yet this conjecture remains to be confirmed experimentally. Here, two complementary techniques are established to detect the genomic distribution of tracks of newly synthesized DNA in human cells by optical mapping in nanochannels. Their respective advantages and limitations are compared, and applied them to detect deregulations of the replication program induced by the antitumor drug hydroxyurea. The developments here thus broaden the field of applications accessible to nanofluidic technologies, and can be used in the future as part for molecular diagnostics in the context of high throughput cancer drug screening.     

Three-stage hybrid-flowshop model for cross-docking

This paper deals with the optimization of a cross-docking system. It is modeled as a three-stage hybrid flowshop, in which shipments and orders are represented as batches. The first stage corresponds to the receiving docks, the second stage corresponds to the sorting stations, and the third stage corresponds to the shipping docks. The objective of the problem is to find a schedule that minimizes the completion time of the latest batch. In order to obtain good quality feasible solutions, we have developed several heuristic schemes depending on the main stage considered, and several rules to order the batches in this stage. Then, we propose a branch-and-bound algorithm that takes into account the decomposition of the problem into three stages. To evaluate the heuristics and to reduce the tree size during the branch-and-bound computation, we also propose lower bounds. Finally, the computational experiments are presented to demonstrate the efficiency of our heuristics. The results show that the exact approach can solve instances containing up to 9–10 batches in each stage (i.e., up to 100 jobs). In addition, our heuristics were evaluated over instances with up to 3000 jobs, and they can provide good quality feasible solutions in a few seconds (i.e., less than 2 s per heuristic).     

Modulated Structures Induced by Phase Transformations

Abstract

Modulated structures can be found in organic, inorganic and even quasicrystalline structures. They are generally detected by diffraction from the presence of satellites surrounding the Bragg reflections. Their positions may vary continuously with temperature or pressure so that the phase can be considered as incommensurately modulated. Incommensurate phases usually transform to a periodic high symmetry phase by increasing temperature and to a commensurate lock-in phase by lowering the temperature. Their domain of stability varies with temperature, pressure and with the type of compound. Examples have been identified where the interval of equilibrium vary from a few tenths to a few hundreds of degrees. Recent progress in the field of incommensurate structure analysis has been greatly favoured by the superspace group approach which is now almost exclusively applied. In many cases, the resolution of the modulated phases by diffraction methods has contributed towards the understanding of the phase changes. In addition, microscopic models for the transition mechanisms have been developed to understand small organic systems. The methods of molecular dynamics have been able to explain the formation of various sequences of commensurate and incommensurate phases observed experimentally.     

Effect of Ba doping on performance of LST as anode in solid oxide fuel cells

The level of barium doping in lanthanum strontium titanate (La_0.4Sr_0.6−xBa_xTiO₃, 0 ≤ x ≤ 0.2; LST, x = 0; LSBT, x > 0), prepared by solid state synthesis, affects its performance as anode in solid oxide fuel cells (SOFCs). Cell structures of LST and all LSBT were similar. The oxidation state of Ti in all compounds was reduced by a comparable amount when LST or LSBT was heated under reducing conditions to form La_0.4Sr_0.6−xBa_xTi_0.59⁴⁺Ti_0.41³⁺O_2.97. All fuel cells using LST or LSBT had high activity for conversion of hydrogen or methane, and the activity increased with the level of substitution by Ba. In addition, performance was enhanced when H₂S was present in either CH₄ or H₂ fuel. There was good contact between YSZ electrolyte and each LSBT or LSB anode.     

The mini-conical slump flow test: Analysis and numerical study

This paper provides a general study on cement paste flow. Both mini-slump and Marsh cone tests are used to evaluate the workability of fresh paste mixtures derived from self compacting concretes. A numerical approach is used to reproduce global flow behavior and to check the accuracy of the obtained viscosity as well as the validity of expressions available in the literature giving yield stress from the final diameter of slumped paste. The computational modeling allows access to local information in order to analyze different regions and corresponding flow types, i.e. falling solid and flowing fresh cementing material mixtures.The limitation of some empirical models allowing the prediction of yield stress τ₀ and plastic viscosity μ from mini-slump tests is underlined, conditions of validity are expressed and a new expression is proposed.