Impedance spectroscopy of ultrafine-grain SnO2 ceramics with a variable grain size

The impedance spectra of nanocrystalline SnO₂ ceramics with an average grain size d ranging from 3 to 43 nm were investigated in the frequency range 1–10⁶ Hz at temperatures from 25 to 300°C in a dry oxygen atmosphere. Analysis of the experimental data by the graphoanalytical method made it possible to separate the contributions of grain bulk and grain boundaries to the conductivity. It is shown that the samples investigated can be arbitrarily divided into two groups with respect to the character of their conductivity. For the samples with an average grain size d < 25 nm, the charge transfer processes are almost completely determined by the grain boundaries. In samples with a larger grain size, the contribution of grain bulk to the conductivity is comparable with that of grain boundaries.     

Uncertain fuzzy models and their applications: III. Optimal estimation

The quality-estimation and decision-making criteria based on the values of error possibility likelihood measures, error necessity likelihood, error possibility confidence, and error necessity confidence are considered. The criteria are formulated for the adequacy of an uncertain fuzzy (UF) model and conclusions based on the UF model for the object under investigation and the UF observation model.     

Hydrogen reduction kinetics of electrometallurgical slime

The interaction of hydrogen with the zinc-containing electrometallurgical slime of the Severstal’ metallurgical works has been studied. The sequence of transformations in the slime heated to 1100°C in hydrogen or air has been established. The experimental and calculated weight losses coincide. Some of the carbonates are shown to decompose in the temperature range 300–700°C, and most iron and zinc oxides are reduced to a metal. In the temperature range 650–850°C, zinc is almost completely sublimated. At temperatures above 800°C, complex oxides are reduced and calcium and magnesium carbonates and sulfates are likely to decompose. Experimental digital data on the zinc sublimation rate are processed by the least squares method with approximating equations used in thermal analysis. The kinetics of nonisothermal zinc sublimation is comprehensively analyzed using a unique procedure developed for taking into account the background of a peak and the effect of accompanying processes. An equation for the calculation of the zinc sublimation rate under experimental conditions (fluidized bed) is given and tested.     

Characteristics of tunneling and impact ionization in ZnS:Mn-based thin-film electroluminescent structures

A method for measuring the characteristics of tunneling and impact ionization in thin-film electroluminescent emitters is suggested. This method makes it possible to find time dependences of the space-charge layer thickness near the anode and the length of the impact ionization region, to determine more exactly the time dependence of the field in the potential barrier at the cathode interface, the maximum depth of the surface states from which electron tunneling occurs, the minimum thickness of the barrier, and the electron tunneling probability, as well as the impact ionization rate for the deep centers related to structural defects of the phosphor layer.     

Internal nonlinear four-mode interactions of capillary oscillations of a charged drop

Analytical expressions for the shape of a charged drop of an incompressible liquid nonlinearly oscillating upon multimode initial deformation have been obtained for the first time to within the third order of smallness. The second-order corrections to oscillation frequencies are calculated depending on the spectrum of modes determining the initial deformation. The third-order calculations show that the fundamental mode amplitude may increase due to the energy exchange with higher modes in a large number of possible four-mode resonance interactions.     

The effect of charge relaxation on the electromagnetic radiation of an oscillating charged viscous drop

A dispersion equation for the capillary oscillations of a charged drop of incompressible liquid possessing a finite electric conductivity is derived with an allowance for the energy lost as a result of the electromagnetic wave emission. The magnitude of the electromagnetic radiation losses of the oscillating drop linearly increases with the electric conductivity and the surface mobility of charge carriers.     

Morphological compression of grayscale images of text

A new method for compression of grayscale images containing a small number of graphical elements is proposed. The method is characterized by high compression ratios, small losses, and good readability of the processed images. It is based on morphological methods of image analysis and could be used to store images of documents produced by fax machines, scanners, etc. Igor I. Falomkin. Born 1979. Graduated from the Faculty of Physics, Moscow State University, in 2001. Scientific interests: image analysis and recognition, analysis and interpretation of experimental data.