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11.
研究了Al2O3、Al2o3/TiB2和Al2O3/TiB2/SiCW三处陶瓷材料在不同条件下的擦靡损特性。结果表明:三种陶瓷材料与硬质合金摩擦副的摩擦系数随温度温度的增加有不同的变化规律,摩擦表面的X射线衍射分析表明,摩擦系数的变化与陶瓷物膜的和结构有关,在高温下Al2O3/TiB2陶瓷材料摩擦表面形成了具有优良的高温润性的TiO2氧化膜,因而TiB2的加入明显改善了Al2O3陶瓷材料 摩擦磨损 相似文献
12.
分析了WTG420铁路罐车用钢的组织结构和力学性能。提出了冶炼与轧制的技术关键,其一,添加稀土元素改善钢中夹杂物;其二,采用控轧控冷使铁素体晶粒细化。 相似文献
13.
桐油改性酚醛树脂的结构及固化过程的研究 总被引:8,自引:0,他引:8
通过桐油与苯酚在酸性催化剂存在下反应,然后再在碱性催化剂存在与甲醛反应制得了一种热固性桐油改性酚醛树脂。利用红外光谱,差示扫描量热法分析技术对改性树脂的结构及固化反应过程进行了研究。 相似文献
14.
机电排灌工程是丘陵、滨湖地区的主要灌溉设施,必须建立适应市场经济的管理新机制,确保工程良性运行和巩固发展,满足不断发展的工农业生产需要。 相似文献
15.
In-situ composites based on dispersed poly (ethylene terephthalate) (PET) or polyamide (PA),and continuous Polyethylene (PE) were prepared through a single screw extruder of Haake rheometer system with a rod-die relatively small in diameter.The extrudate was drawn at a drawing ratio of 3.1,and then quickly cooled in cold water.The specimens were obtained by injection molding at processing temperatures less than 190℃,far below the melting temperature of PET (265℃) and PA (230℃),which can maintain the solid state of PET and PA microfiber phase in the composites.Morphological observation with scanning electron microscopy (SEM) indicated that PET and PA can more or less form in-situ microfibers at compositions studied (0-20 wt pct PET or PA),and especially,PET and PA were almost deformed into fibers at the concentration of 15wt pct.Eensile strength and especially.PET and PA were almost deformed into fibers at the concentration of 15wt pct.Tensile strength and modulus of the blends reinforced by PET or PA microfibers showed to be increased from the tensile test results.The most noticeable improvement of the tensile properties occurred at 15wt pct of PET in PET/PE system,corresponding to the highest microfiber content,where the tensile strength reached 32.5 MPa,whereas only 19.5 MPa for the pure PE. 相似文献
16.
The electrorheological (ER) fluids are colloidal suspension of highly polarizable particles in a non-conducting solvent.Chains of submicron-sized particles formed along an applied DC electric field by the so-called electrorheological effect.According to the obvious change of transmittance of the ER fluids in a DC electric field when the polarized particles arranged along the field,the model of smart window was proposed by sandwiching the ER fluids based on titania particles coated with silica between a pair of In-Sn oxide (ITO) coated glasses.The solar transmittance change as much as 48.0% was obtained with the wavelength of 500 nm at the maximum on applying and removing the electric field of 500V/mm. 相似文献
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Sodium sulfonate‐terminated dendritic poly(ester‐amine) (SPEA) was synthesized by sulfonation of acrylic double bond‐terminated dendritic poly(ester‐amine) (APEA) with sodium hydrogen sulfite (NaHSO3) in mixture of diglycol and 2‐butanone under normal pressure. The structure of SPEA was characterized by IR, 1H‐NMR, and elemental analysis. SPEA was water‐soluble. 1.0–40.0% (mass) SPEA aqueous solutions appeared as dilatant fluid. When pH value varied from 1.5 to 12.0, the viscosity of 1–5% (mass) SPEA aqueous solutions changed very small, and the electric conductivity almost kept stable within pH 3.0–10.0. The relationship between the viscosity and the concentration of SPEA water solutions was similar to that of NaCl water solutions. The surface tension of SPEA water solutions was lower than that of polyethylene glycol 2000 water solutions with the same concentration. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
20.
The crystalline morphology of poly(phenylene sulfide) (PPS) isothermally crystallized from the melt under shear has been observed by polarized optical microscope (POM) equipped with a CSS450 hot-stage. The shish–kebab-like fibrillar crystal structure is formed at a higher shear rate or for a longer shear time, which is ascribed to the tight aggregation of numerous oriented nuclei in the direction of shear. The crystallization induction time of PPS decreases with the shear time, indicating that the shear accelerates the formation of stable crystal nuclei. Under shear, the increase of spherulite growth rate results from highly oriented chains. The melting behavior of shear-induced crystallized PPS performed by differential scanning calorimetry (DSC) shows multiple melting peaks. The lower melting peak corresponds to melting of imperfect crystal, and the degree of crystal perfection decreases as the shear rate increases. The higher melting peak is related to the orientation of molecular chains. These oriented molecular chains form the orientation nuclei which have higher thermal stability than the kebab-like lamellae that are developed later. A new model based on the above observation has been proposed to explain the mechanism of shish–kebab-like fibrillar crystal formation under shear flow. 相似文献