Determination of Solvent Contamination and Characterization of Ultrafine HNS Particles after Solvent Recrystallization

Solvent–antisolvent recrystallization employed for size reduction of HNS has been described and the effect of various parameters such as stirring rate, effect of antisolvent type, antisolvent temperature, ultrasonication, etc. was investigated. Purified HNS, produced by hot solvent recrystallization of production grade crude HNS, of mean particle size ∼95 μm was used for preparation of ultrafine particles of HNS. Solvent contamination in terms of residual solvent was determined by ¹H NMR and GC‐MS analysis. In addition, ultrafine HNS has been characterized for purity (HPLC, ¹H NMR), particle size and shape (PSA and SEM), specific surface area (BET analysis), thermal behavior (TGA, DSC), sensitivity (impact, friction), etc. The results have been compared with C‐HNS. UF‐HNS was >99% pure with mean particle size <1 μm. SEM showed submicrometer size rods like particles of HNS as the final material.     

Steady-state creep of orthotropic rotating disks of variable thickness

Creep analysis of orthotropic rotating disks with variable thickness has been carried out for secondary stage of creep. Norton's power law of creep is employed to derive general expressions for stresses and strain rates in the disks. These expressions have been utilized to find stress and strain rate distributions for disks with the following types of thicknesses - (i) constant thickness, (ii) linearly varying thickness, and (iii) hyperbolically varying thickness. The numerical computations to study the effects of anisotropy and the profile of the disks on stresses and strains have been carried out employing the method of successive approximations. Five different cases of anisotropy have been considered. Selecting a certain type of material anisotropy and an optimum profile for the disk may result in a better design for the turbine disks.     

Linearization of Photonic Link Based on Phase-Controlled Dual Drive Dual-Parallel Mach–Zehnder Modulator

Wireless Personal Communications - Wireless sensor network will be the dominating field in the future era. Right now it goes from the transformation phase. It unfolds its capacity and sort out its...     

Differential scanning calorimetry and wide-angle X-ray scattering studies of bread staling

Wide angle X-ray scattering (WAXS) was used to follow the development of crystal size and strain during the staling of bread containing different additives. In this it was observed that one can classify the good anti-staling additives as gelatin, propylene glycol, maltodextrin and anti-staling enzyme corresponding to the order of increasing crystal size for a particular Bragg reflection in all the samples and correlate using DSC (differential scanning calorimetry) studies of all the bread compositions containing different additives. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 67:1597–1603, 1998     

Novel defects in Al–Pd–Fe complex metallic alloys: A micromechanical modelling approach

Transmission electron microscopy investigations have revealed that in the face centred complex metallic alloy of C₂–Al–Pd–Fe, the dislocations mediating plastic flow are decorated by localized regions of body centred structure in the compressive part of their strain field thus forming composite defects. We calculated the properties of these defects using a micromechanical model. The Eshelby method was employed to estimate the energies involved in the formation of such defects in the face-centred C₂ phase. We could reproduce the experimentally observed features of the defects in terms of their size and spatial configuration. The model describes a unique mechanism of a non-equilibrium defect, i.e., a dislocation, being stabilized by the formation and interaction with another non-equilibrium defect, i.e., a nanometre sized inclusion of different structure.     

Development of Low-Oxide MCrAlY Coatings for Gas Turbine Applications

Advanced high-energy plasma systems are being used to achieve the benefits of the high-velocity oxy-fuel (HVOF) system without losing the inherent advantages of plasma for coating of gas turbine parts. MCrAlY coatings play a very important role in the performance and reliability of gas turbine components. One of the important considerations for next generation of gas turbines, which have more demanding conditions and need to withstand ever increasing operating temperatures, is that they should possess very low oxygen content levels in the coating. Low oxygen content coatings are applied by the expensive low-pressure plasma spray (LPPS)/vacuum plasma spray (VPS) technique for critical components in aero- and land-based gas turbines. This work deals with the development of low-cost LPPS equivalent coatings (having low oxygen content) using the high-energy high-velocity plasma spray (HEHVPS) gun and inert gas shroud. A comparison has also been made with CoNiCrAlY coatings by HVOF.     

Dietary fish oil enhances macrophage production of nitric oxide

Melanotic neuroectodermal tumor of infancy (MNTI) is a rare but well-documented lesion of neuroectodermal derivation. Maturation of the neural elements has been reported only occasionally. We report a case of MNTI of the maxilla showing maturation of neural elements to ganglionic cells.     

Cavitation Erosion Behavior of HPDL-Treated TWAS-Coated Ti6Al4V Alloy and Its Similarity with Water Droplet Erosion

Twin wire arc-sprayed (TWAS) coating of commercially available SHS 7170-cored wire was obtained on Ti6AL4V alloy, and to improve its properties, it was further surface treated with high-power diode laser (HPDL). The cavitation erosion (CE) resistance of TWAS-coated samples was evaluated as per ASTM G-32-2003 and it was compared with laser-treated and untreated Ti6Al4V alloys. The CE resistance of TWAS-coated SHS 7170 samples after HPDL treatment has improved significantly. The main reasons for its improvement are elimination of pores, increased fracture toughness, reduced hardness, and brittleness. The CE resistance of HPDL-treated TWAS coating is compared with water droplet erosion resistance. It is observed that there is a similarity in the both the phenomenon.