Provisioning for interdomain quality of service: the MESCAL approach

This article presents an architecture for supporting interdomain QoS across the multi-provider global Internet. While most research to date has focused on supporting QoS within a single administrative domain, mature solutions are not yet available for the provision of QoS across multiple domains administered by different organizations. The architecture described in this article encompasses the full set of functions required in the management (service and resource), control and data planes for the provision of end-to-end QoS-based IP connectivity services. We use the concept of QoS classes and show how these can be cascaded using service level specifications (SLSs) agreed between BGP peer domains to construct a defined end-to-end QoS. We illustrate the architecture by describing a typical operational scenario.     

Novel application of PEG/SDS interaction as a wettability modifier of hydrophobic carbonate surfaces

Wettability alteration of carbonate reservoirs from oil-wet to water-wet is an important method to increase the efficiency of oil recovery. Interaction between surfactants and polymers can enhance the effectiveness of surfactants in EOR applications. In this study, the interaction of polyethylene glycol (PEG) with an ionic surfactant, sodium dodecyl sulphate (SDS), is evaluated on an oil-wet carbonate rock surface by using contact angle measurements. The results reveal that wettability alteration of carbonate rocks is achieved through PEG/SDS interaction on the rock surface above a critical aggregation concentration (CAC). The behaviour of PEG/SDS aqueous solutions is evaluated using surface and interfacial tension measurements. Furthermore, the effect of PEG and SDS concentrations and impact of electrolyte addition on PEG/SDS interaction are investigated. It is shown that electrolyte (NaCl) can effectively decrease the CAC values and accordingly initiate the wettability alteration of rocks. Moreover, in a constant SDS concentration, the addition of NaCl leads to a reduction in the contact angle, which can also be obtained by increasing the aging time, temperature and pre-adsorption of PEG on the rock surface.     

The influences of collector diameter,spinneret rotational speed,voltage, and polymer concentration on the degree of nanofibers alignment generated by electrocentrifugal spinning method : Modeling and optimization by response surface methodology

We studied the capability of electrocentrifuge-spinning (ECS) method for generating highly aligned nanofiber. First, the degree of nanofiber alignment (DNA) produced by ECS was compared with that of rotating drum (RD) method and ECS superiority was demonstrated. Then central composite design (CCD) and response surface methodology (RSM) was used for optimization of operating conditions. The critical factors selected for the examination were voltage, polymer concentration, collector diameter and spinneret rotational speed. To design the required experiments at the settings of independent parameters, RSM was applied. A total of 30 experiments were accomplished towards the construction of a quadratic model for target variable. Using this quadratic model, the influence of aforementioned variables was discussed on DNA. The best operating condition for attaining the maximum value of DNA was the applied voltage of 20.19 kV, polymer concentration of 17.44wt%, collector diameter of 40.76 cm, and rotational speed of 2680.10 rpm.     

Synthesis,characterization, and drug‐release behavior of novel PEGylated bovine serum albumin as a carrier for anticancer agents

To develop a novel pH‐sensitive PEGylated carrier for protein‐based anticancer agents, we modified bovine serum albumin (BSA) with poly(ethylene glycol) citrate ester (PEG–CA) through amidation with its amino groups. Increasing the mixing ratio of albumin from 3 to 6 with respect to PEG–CA resulted in a 2‐fold increase in the degree of albumin modification. Adriamycin (ADR)‐loaded PEG–CA–BSA hydrogels and microparticles were prepared, and the cumulative amounts of ADR released from the PEG–CA–BSA hydrogels (phosphate‐buffered saline, pH 7.4) showed that all the PEG‐CA‐BSA_(x) (x represents degree of substitution of PEG to amino group of albumin, i.e. 26%, 28%, 31% and 49%) hydrogels had lower ADR release rates with a slight initial burst release. During the first 24 h, the cumulative releases were 15.5% for PEG–CA–BSA₍₄₉₎, 24% for PEG–CA–BSA₍₃₁₎, 31% for PEG–CA–BSA₍₂₈₎, and 38% for PEG–CA–BSA₍₂₆₎. Afterward, all the release rates slowed, and they were almost in the following order: PEG–CA–BSA₍₂₆₎ > PEG–CA–BSA₍₂₈₎ > PEG–CA–BSA₍₃₁₎ > PEG–CA–BSA₍₄₉₎. The release rates of ADR from the microparticles were dependent on the amount of glutaraldehyde. According to our findings, a higher PEG–CA/BSA molar ratio led to a reduced cumulative amount of ADR released from the hydrogels, whereas higher release rates were observed for microparticles with a lower amount of BSA in the conjugates in a pH‐dependent manner. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Synthesis of BaCO3 Nano-particles Through a Polymer-Assisted Precipitation Method

BaCO₃ powders with different morphologies have been synthesized by a simple polymer-assisted precipitation method. The influence of diethylene glycol (DEG) as a modifier on the powder particle characteristics has been investigated using XRD, FESEM, FT-IR, and VSM techniques. It is revealed that both crystallinity and crystallite size of particles can be greatly affected through the change in DEG:water ratio. The crystallite size decreases from 32 nm for water solution to 20 nm for DEG’s solution. The FESEM images also show that DEG:water volume ratio causes the shape of particle to change greatly. While particle synthesized in presence of water solution has rodlike shape with 900 nm in length and 276 nm in width, particle synthesized in DEG solution has completely spherical shape with a mean particle size of 93 nm. Finally, the performance of barium carbonate nano-particles produced in this work has been examined in the processing of barium hexaferrite magnetic phase.     

The Effect of Multiple Surface Treatments on Biological Properties of Ti-6Al-4V Alloy

In this research, the effect of various surface treatments including laser processing, grit blasting and anodizing on chemical structure, surface topography, and bioactivity of Ti-6Al-4V was investigated. Six groups of samples were prepared by a combination of two alternative laser processes, grit blasting and anodizing. Selected samples were first evaluated using microanalysis techniques and contact roughness testing and were then exposed to in vitro environment. Scanning electron microscopy was used to characterize the corresponding final surface morphologies. Weight measurement and atomic absorption tests were employed for determination of bioactivity limits of different surface conditions. Based on the data obtained in this study, low-energy laser processing generally yields a better biological response. The maximum bioactivity was attained in those samples exposed to a three step treatment including low-energy laser treatment followed by grit blasting and anodizing.     

Orientation Relationships and Texture of the Iron-Nitride Phase Constituents in Pulsed Plasma Nitriding

Electron backscattered diffraction study was used to determine the preferred orientations of the crystals and texture evolution as a consequence of nitrogen diffusion. In the current study, the nitrided layer on a steel substrate was selected as a model material to investigate the distribution of different phases as well as their crystallographic relationships. Possible phase orientation relationships between the constituents were found based on which a phase transformation mechanism was proposed. The investigation of coincidence site lattice revealed that Σ9 and Σ25 types of grain boundaries are separating the elongated ε-phase grains. It was also presented how the phase constituents’ distribution affects the mechanical properties using nanomechanical indentation technique. Moreover, it was found that the ε-phase exists in three distinguished orientations across the matrix each of which representing a definite phase transformation phenomenon.     

Thermal modeling of gas engine driven air to water heat pump systems in heating mode using genetic algorithm and Artificial Neural Network methods

The gas-engine driven air-to-water heat pump, type air conditioning system, is composed of two major thermodynamic cycles (including the vapor compression refrigeration cycle and the internal combustion gas engine cycle) as well as a refrigerant-water plate heat exchanger. The thermal modeling of gas engine driven air-to-water heat pump system with engine heat recovery heat exchangers was performed here for the heating mode of operation (in which it was required to model engine heat recovery heat exchanger). The modeling was performed using typical thermodynamic characteristics of system components, Artificial Neural Network and the multi-objective genetic algorithm optimization method. The comparison of modeling results with experimental ones showed average differences of 5.08%, 5.93%, 5.21%, 2.88% and 6.2% which shows acceptable agreement for operating pressure, gas engine fuel consumption, outlet water temperature, engine rotational speed, and system primary energy ratio.     

Microstructural studies and wear assessments of Ti/TiC surface composite coatings on commercial pure Ti produced by titanium cored wires and TIG process

Tungsten Inert Gas (TIG) process and titanium cored wires filled with micro size TiC particles were employed to produce surface composite coatings on commercial pure Ti substrate for wear resistance improvement. Wire drawing process was utilized to produce several cored wires from titanium strips and titanium carbide powders. Subsequently, these cored wires were melted and coated on commercial pure Ti using TIG process. This procedure was repeated at different current intensities and welding travel speeds. Composite coating tracks were found to be affected by TIG heat input. The microstructural studies using optical and scanning electron microscopy supported by X-ray diffraction showed that the surface composite coatings consisted of α′-Ti, spherical and dendritic TiC particles. Also, greater volume fractions of TiC particles in the coatings were found at lower heat input. A maximum microhardness value of about 1100 HV was measured which is more than 7 times higher than the substrate material. Pin-on-disk wear tests exhibited a better performance of the surface composite coatings than the untreated material which was attributed to the presence of TiC particles in the microstructure.