Study of the performance of a transparent and reconfigurablemetropolitan area network

The transport performance of an optically transparent regional-size ring network testbed with circumference of 280 km, based on metro-area optimized optical layer components and fiber, is demonstrated under dynamic traffic conditions. For the longest transmission path, excellent transmission performance is achieved using cost-effective directly modulated signals. Network reconfigurability is achieved using add-drop modules that are commercially available as of this writing. We show that the dynamic nature of the network does not affect the system performance. In particular, we show that electronic gain control of erbium-doped amplifiers is capable of managing switching transients in amplified metro-scale networks     

Convolutional neural network‐based wind‐induced response estimation model for tall buildings

This study presents a convolutional neural network (CNN)‐based response estimation model for structural health monitoring (SHM) of tall buildings subject to wind loads. In this model, the wind‐induced responses are estimated by CNN trained with previously measured sensor signals; this enables the SHM system to operate stably even when a sensor fault or data loss occurs. In the presented model, top‐level wind‐induced displacement in the time and frequency domains, and wind data in the frequency domain are configured into the input map of the CNN to reflect the resisting capacity of a tall building, the change in the dynamic characteristics of the building due to wind loads, and the relationship between wind load and the building. To evaluate stress, which is used as a safety indicator for structural members in the building, the maximum and minimum strains of columns are set as the output layer of the CNN. The CNN is trained using measured wind and wind response data to predict the column strains during a future wind load. The presented model is validated using data from a wind tunnel test of a building model. The performance of the presented model is verified through strain estimation with data that were not used in the CNN training. To assess the validity of the presented input map configuration, the estimation performance is compared with a CNN that considered only the time domain responses as input. Furthermore, the effects of the variations in the configuration of the CNN on the wind response estimation performance are examined.     

Suppression of inherent ferromagnetism in Pr-doped CeO(2) nanocrystals

Ce(1-x)Pr(x)O(2-δ) (0 ≤x≤ 0.4) nanocrystals were synthesized by self-propagating method and thoroughly characterized using X-ray diffraction, Raman and X-ray photoelectron spectroscopy and magnetic measurements. Undoped CeO(2) nanocrystals exhibited intrinsic ferromagnetism at room temperature. Despite the increased concentration of oxygen vacancies in doped samples, our results showed that ferromagnetic ordering rapidly degrades with Pr doping. The suppression of ferromagnetism can be explained in terms of the different dopant valence state, the different nature of the vacancies formed in Pr-doped samples and their ability/disability to establish the ferromagnetic ordering.     

Calcium–Alginate–Inulin Microbeads as Carriers for Aqueous Carqueja Extract

Carqueja (Pterospartum tridentatum) is an endemic species and various bioactive compounds have been identified in its aqueous extract. The aim of this study was to protect the natural antioxidants from the aqueous extract of carqueja by encapsulation in Ca–alginate microbeads and Ca–alginate microbeads containing 10% and 20% (w/v) of inulin. The microbeads produced by electrostatic extrusion technique had an average diameter from 625 μm to 830 μm depending on the portion of inulin. The sphericity factor of the hydrogel microbeads had values between 0.014 and 0.026, while freeze dried microbeads had irregular shape, especially those with no excipient. The reduction in microbeads size after freeze drying process (expressed as shrinkage factor) ranged from 0.338 (alginate microbeads with 20% (w/v) of inulin) to 0.523 (plain alginate microbeads). The expressed radical scavenging activity against ABTS and DPPH radicals was found to be between 30% and 40% for encapsulated extract, while the fresh extract showed around 47% and 57% of radical scavenging activity for ABTS and DPPH radicals, respectively. The correlation between antioxidant activity and the total phenolic content were found to be positive (in both assay methods, DPPH and ABTS), which indicate that the addition of inulin didn't have influence on antioxidant activity. The presence of inulin reduced stiffness of the hydrogel, and protected bead structure from collapse upon freeze‐drying. Alginate–inulin beads are envisaged to be used for delivery of aqueous P. tridentatum extract in functional food products.     

Power source research at USC: Development of advanced electrocatalysts for polymer electrolyte membrane fuel cells

This paper provides an overview on the development of advanced fuel cell cathode catalysts at University of South Carolina (USC) with the emphasis on the stability of non-precious metal and Pt alloy catalysts. Nitrogen-modified carbon composite (NMCC) catalysts were developed for the oxygen reduction reaction (ORR) through the pyrolysis of cobalt (iron)-nitrogen chelate followed by the treatment combination of pyrolysis, acid leaching, and re-pyrolysis. A promising stability was observed for 1050 h fuel cell operation under current density of 200 mA cm⁻² as evidenced by a potential decay rate as low as 40 μV h⁻¹. The performance degradation mechanism of the NMCC-based fuel cell is discussed. Pt and PtPd hybrid catalysts are developed that use a NMCC, which is itself active for the ORR, instead of a conventional carbon black support. The stability test at 1 A cm⁻² indicated that the Pt/NMCC hybrid catalyst (new Pt-Co/C) is more stable than the conventional Pt-Co/C without the Co leaching out. The PEM fuel cell accelerated stress test (AST) for supports and catalysts demonstrated that their stability changes in the order: Pt₃Pd₁/NMCC hybrid catalyst > Pt/NMCC hybrid catalyst > conventional Pt/C catalyst. Moreover, the hybrid catalysts exhibit higher mass activity than the Pt/C catalysts.     

Synthesis and characterization of bionanoparticle—Silica composites and mesoporous silica with large pores

A sol-gel process has been developed to incorporate bionanoparticles, such as turnip yellow mosaic virus, cowpea mosaic virus, tobacco mosaic virus, and ferritin into silica, while maintaining the integrity and morphology of the particles. The structures of the resulting materials were characterized by transmission electron microscopy, small angle X-ray scattering, and N₂ adsorption-desorption analysis. The results show that the shape and surface morphology of the bionanoparticles are largely preserved after being embedded into silica. After removal of the bionanoparticles by calcination, mesoporous silica with monodisperse pores, having the shape and surface morphology of the bionanoparticles replicated inside the silica, was produced,. This study is expected to lead to both functional composite materials and mesoporous silica with structurally well-defined large pores. Electronic Supplementary Material  Supplementary material is available for this article at and is accessible for authorized users.     

Regulation of International Watercourses under the UN/ECE Regional Agreements

Abstract

This article deals with the UN Economic Commission for Europe (UN/ECE) regional agreements, and their use as implementing instruments for protecting and managing international water courses. The background and issues of the regional instruments developed by the UN Economic Commission for Europe are addressed. The contents of the 1992 Helsinki Convention and its implementation are described, as well as the recent development of the Protocol on Water and Health. The relationship to the 1991 Espoo Convention and a comparison with the 1997 UN Convention on the Law of International Watercourses are also included. The potential of the UN/ECE conventions as tools to promote conflict prevention and dispute settlement is discussed. Lessons and conclusions are drawn from the experience on the management of transboundary waters in Europe.     

Nanosecond Fluorescence Spectroscopy

This article is a summary of a short course lecture given in conjunction with the 1984 Nuclear Science Symposium. Measuring systems for nanosecond fluorescence spectroscopy using single-photon counting techniques are presented. These involve systems based on relaxation-type spark gap light pulser and synchronously pumped mode-locked dye lasers. Furthermore, typical characteristics and optimization of operating conditions of the critical components responsible for the system time resolution are discussed. A short comparison of the most important deconvolution methods for numerical analysis of experimental data is given particularly with respect to the signal-to-noise ratio of the fluorescence signal.     

Stable adaptive control of a class of first-order nonlinearlyparameterized plants

Stable adaptive control algorithms are designed for a class of first-order nonlinearly parameterized plants containing nonlinearities similar to those arising in fermentation process models. When the plant nonlinearity is conveniently parameterized and when the controller parameters are adjusted adaptively, the output error is shown to converge to zero. Stability of the overall system is proved using the Lyapunov function with a suitably chosen cubic term