Thermodynamic performance of O2/CO2 gas turbine cycle with chemical recuperation by CO2-reforming of methane

This paper proposes a novel power cycle system composed of chemical recuperative cycle with CO₂–NG (natural gas) reforming and an ammonia absorption refrigeration cycle. In which, the heat is recovered from the turbine exhaust to drive CO₂–NG reformer firstly, and then lower temperature heat from the turbine exhaust is provided with the ammonia absorption refrigeration system to generate chilled media, which is used to cool the turbine inlet gas except export. In this paper, a detailed thermodynamic analysis is carried out to reveal the performance of the proposed cycle and the influence of key parameters on performance is discussed. Based on 1 kg s⁻¹ of methane feedstock and the turbine inlet temperature of 1573 K, the simulation results shown that the optimized net power generation efficiency of the cycle rises up to 49.6% on the low-heating value and the exergy efficiency 47.9%, the new cycle system reached the net electric-power production 24.799 MW, the export chilled load 0.609 MW and 2.743 kg s⁻¹ liquid CO₂ was captured, achieved the goal of CO₂ and NO_x zero-emission.     

Oxygen evolution and hypochlorite production on Ru-Pt binary oxides

The electrocatalytic activities of Ru-Pt binary oxide electrodes prepared by thermal decomposition for both oxygen and chlorine evolution reactions (OER and CER) were investigated by cyclic voltammetry (CV) and log i/E relationships (Tafel study). Both CV and Tafel studies revealed that the electrodes from the coating solutions with 60 and 20 mol % Pt content possessed the maximum apparent activity for OER and optimal apparent activity for CER/hypochlorite production, respectively. The specific activity (i/q ^*) revealed that mixing of the RuO₂ and PtO _x had no synergistic effects for OER due to the occurrence of phase segregation, which was revealed by element mapping/surface morphologies and Auger electron spectroscopy. Lower current efficiencies for hypochlorite production were found on the freshly prepared binary electrodes (type I electrodes) than on those having been treated by repetitive CVs (type II electrodes). Stability testing of both type I and II electrodes was measured in 0.5 m NaCl solution at 300 mA cm^–2 for 480 h, indicating that both type I and II electrodes are quite stable under the above conditions.     

SBS环保耐热型装饰胶粘剂的研制

采用SBS弹性体、增粘树脂、增强剂及按一定比例配合而成的混合溶剂,制备了一种价廉物美的新型环保型胶粘剂。讨论了混合溶剂的(δ+γ)值、星型SBS与线型SBS的质量比、增强剂对胶粘剂性能的影响。结果表明:不管在高温还是在常温下,加入了增强剂的试样的剪切强度都优于市场上出售的胶粘剂。     

大理地区烤烟陈化过程中有机酸含量变化研究

使用衍生化-气质联用方法研究了大理地区烤烟连续陈化4年其有机酸变化。结果表明,烤烟在陈化过程中,①非挥发酸在6到18个月内含量明显降低,18到30个月内变化减缓,30到48个月内下降又加快,非挥发酸总量与苹果酸含量线性相关;②半挥发酸随陈化时间延长呈缓慢下降趋势;③挥发酸总量在6到24个月的陈化时间内明显增加,24到36个月内保持不变并略有下降,36到48个月内基本呈下降趋势,挥发酸总量与异戊酸含量线性相关。     

甲磺酸伊马替尼的合成

以4-甲基-3-硝基苯胺为起始原料,经过缩合、还原、环合等反应制得抗肿瘤药物甲磺酸伊马替尼。并分别讨论了采用无水碳酸钾代替二异丙基乙胺、水合肼和普通催化剂代替铂炭催化剂以及采用异戊醇作为溶剂的优点。最终反应总收率超过50%,用高效液相色谱分析产品纯度在99.5%以上。     

循环冷却水零排污运行方案的研究

对循环冷却水系统零排污的技术可行性、经济性等进行了讨论，并针对大庆炼化公司循环冷却水系统零排污方案的实施加以详细描述，对实施过程中存在的问题予以了详细说明。     

Numerical solution of viscous flow past a solid sphere with the control volume formulation

The control volume formulation with the QUICK finite difference scheme is used to solveincompressible liquid flow past a solid sphere in terms of stream function and vorticity.Several tech-nical points are addressed on improving the accuracy and efficiency of numerical simulation of similarproblems of fluid flow.In particular,the importance of suitable specification of the distortion func-tion to enforcing the far field boundarv conditions is emphasized.     

纳米碳酸钙的表面活化改性研究

本文主要介绍通过加入特定的表面改性剂,制得了表面改性的活性碳酸钙.并对活化过程中的一系列影响因素,如活化温度、活化时间、碳酸钙悬浊液浓度、表面改性剂用量进行了研究.     

氟硅唑微乳剂的研制

对国内外文献未见报道的8％氟硅唑微乳剂制剂进行了研制，测定了其冷贮和热贮稳定性等理化性状及生物活性。对黄瓜自粉病室内毒力测定和田间药效试验结果表明，药效与40％乳油相当，对黄瓜安全。     

以氧化镁和氧化锌为主稳定剂的PVC的热稳定性和力学性能

用HAAKE流变仪研究了氧化镁／氧化锌稳定体系对聚氯乙烯的动态热稳定性能。结果发现，在氧化镁／氧化锌质量比为2／3的条件下，配合环氧大豆油、硬脂酸钙、无毒亚磷酸酯和有机稳定剂作为辅助稳定剂，其初期着色和热稳定效果都超过了市售钙锌稳定体系，流变性能和动态热稳定特性接近铅盐稳定体系。用这种稳定体系稳定的PVC的力学性能与市售钙锌稳定体系稳定的相当。