The Effects of P-Poisoning of CexZr1−xO2 on the Transient Oxygen Storage and Release Kinetics

The present work reports on the investigation of the effects of chemical poisoning of Ce_xZr_1?xO₂ solids by phosphorous (P) on the kinetics of oxygen storage and release (OSR) of the thus derived P-contaminated solids, as a function of Ce_xZr_1?xO₂ solid composition (x = 0.3, 0.5 and 0.7) for the first time. Phosphorous deposition on the surface of Ce_xZr_1?xO₂ particles followed by calcination in air at 850 °C forms nano-crystals of CePO₄, which lead to a drastic decrease in the population of surface and subsurface reactive and mobile oxygen species due to the formation of P–O–Ce bonding. The concentration (μmol/g) of exchangeable ¹⁶O in the solid with ¹⁸O from the gas phase was found to increase, and the degree of reduction in the Oxygen Storage Capacity (OSC) to decrease with increasing Ce content in the Ce_xZr_1?xO₂ solid after P-poisoning. The increase in the Ce content of Ce_xZr_1?xO₂ makes its OSR properties more resistant against P-poisoning due to the increasing number of poison-free Ce atoms, which are able to participate in the Ce³⁺ ? Ce⁴⁺ redox cycle.     

Meeting the challenge of water sustainability: The role of process systems engineering

This white paper is the result of discussions during the FIPSE-4 conference ( http://fi-in-pse.org ) in June 2018. It aims to highlight open problems and provide directions for future research in the area of water with emphasis on its agricultural usages. Some of the open problems discussed are: (a) the use of ecosystems as unit operations to understand their role in providing freshwater and in cleaning polluted water; (b) consideration of interactions and independencies between flows of water and other resources, such as food, energy, materials, ecosystem services, and environmental emissions; (c) challenges in modeling, sensing, and closed-loop control in precision irrigation. In particular, the development of agro-hydrological models that balance computing speed versus solution details and accuracy: (d) The use of state and parameter estimation approaches, through field measurements, to obtain soil moisture levels accurately; and (e) decision support systems to administer water and nutrient needs for optimum yields of agricultural products.     

Impact of spinel forming systems (Fe-/Mg-/Mn-Al-O) as functional coating materials for carbon-bonded alumina filters on steel melt filtration

Since solid, non-metallic inclusions influence considerably the quality of casted steel products, carbon-bonded alumina foam filters are used in secondary metallurgical treatments to remove these particles from steel melts. In order to attain a significant improvement of the filtration process, five different carbonaceous spinel compounds from the Fe-/Mg-/Mn-Al-O systems are applied on carbon-bonded alumina filters in this study and investigated with regard of their filtration efficiency. However, these spinel compounds decompose partially during sintering at 1400?°C under reducing atmosphere, wherefore the resulting coatings contain not only spinel compounds, but also oxidic and metallic components. The subsequent interaction with molten steel leads to the development of multicrystal structures on the filter surface, which stem from interfacial reactions between coating materials, molten steel, and inclusions. As a result of this procedure, a reduction of almost 60% alumina inclusions is measured with the aid of an automatic SEM, whereby spinel compounds from the Fe-Mn-Al-O system achieve highest filtration efficiencies.     

Optimization-based process synthesis under seasonal and daily variability: Application to concentrating solar power

We propose an optimization-based framework for process synthesis under variability in two frequencies. Low-frequency variability is represented through scenarios and high-frequency variability is modeled using modes. The proposed framework allows for the selection of different process configurations during different modes, a feature necessary to model systems under wide high frequency variability (e.g., solar-based technologies). The optimization problem is formulated as a two-stage stochastic programming model with mode subproblems nested inside each scenario. The proposed framework is applied to the design of concentrating solar power plants with thermochemical energy storage, leading to the formulation of a computationally efficient model, as well as the identification of a superior design. © 2018 American Institute of Chemical Engineers AIChE J, 65: e16458 2019     

Reticulated Porous Foam Ceramics with Different Surface Chemistries

The aim of this study was to discuss the influence of different filter surface chemistries on the properties of foam filters. For reliable results, it is essential to ensure comparable structural properties (cell size and strut thickness) for all different surface chemistries (Al₂O₃, MgAl₂O₄, 3Al₂O₃·2SiO₂, SiO₂, and TiO₂) possess the same structural properties (cell size and strut thickness). Filters made of 100% of the investigated materials and alumina skeletons coated with the investigated materials were prepared. The coated alumina samples were sintered in one and two steps. The processing route with two sintering steps resulted in improved mechanical properties and comparable shrinkage and strut thickness. The 100% bulk foams possessed different pore sizes due to the differences of the material shrinkage. In this study, a comparison of the experimental investigated properties of the ceramic foam filters and the theoretically calculated values for foam materials derived from the bulk material properties is established.     

Rapid Synthesis and Antiproliferative Properties of Polyazamacrocycle-Based Bi- and Tetra-Gold(I) Phosphine Dithiocarbamate Complexes

A family of bi- and tetrametallic gold(I) phosphine dithiocarbamate complexes were synthesized, starting from cyclam and dimethylcyclam polyazamacrocycles, respectively, along with their monometallic gold(I) chloridophosphine precursors. Their antiproliferative properties were evaluated on two cancer cell lines (A549 and NSCLC-N6-L16). Most of the mono- and bimetallic complexes displayed strong activities and, in particular, one bimetallic derivative showed antiproliferative properties in the low micromolar range. Insights into the structure–activity relationships are given, along with determination of the thioredoxin reductase inhibition potential, two-photon imaging of the fluorescent derivatives, and evaluation of gold uptake.     

Adaptive Smooth Simulcast Protocol (ASSP) for Video Applications: Description and Performance Evaluation

In this paper, we present Adaptive Smooth Simulcast Protocol (ASSP) for simulcast transmission of multimedia data over best-effort networks. ASSP is a new multiple-rate protocol that implements a single rate TCP-friendly protocol as the underlying congestion control mechanism for each simulcast stream. The key attributes of ASSP are: (a) TCP-friendly behavior, (b) adaptive per-stream transmission rates, (c) adaptive scalability to large sets of receivers and (d) smooth transmission rates that are suitable for multimedia applications. We evaluate the performance of ASSP under an integrated simulation environment which combines the measurements of both network and video performance metrics. We also compare ASSP against other proposed solutions and the results demonstrate that the performance of ASSP is significantly better than the tested solutions. Finally, ASSP is a practical solution with very low implementation complexity for video transmission over best-effort networks.     

Chord-PKI: A distributed trust infrastructure based on P2P networks

Many P2P applications require security services such as privacy, anonymity, authentication, and non-repudiation. Such services could be provided through a hierarchical Public Key Infrastructure. However, P2P networks are usually Internet-scale distributed systems comprised of nodes with an undetermined trust level, thus making hierarchical solutions unrealistic. In this paper, we propose Chord-PKI, a distributed PKI architecture which is build upon the Chord overlay network, in order to provide security services for P2P applications. Our solution distributes the functionality of a PKI across the peers by using threshold cryptography and proactive updating. We analyze the security of the proposed infrastructure and through simulations we evaluate its performance for various scenarios of untrusted node distributions.     

Stress in interactive applications: analysis of the valence-arousal space based on physiological signals and self-reported data

Measuring users’ emotional reaction to interactive multimedia and hypermedia is important. One particularly popular self-reported method for emotion assessment is the Valence-Arousal (VA) Scale: a 9?×?9 affective grid. This paper aims to identify specific stress region(s) in the VA space by combining self-reported ratings (pairs of VA) and physiological signals (skin conductance). To this end, 31 healthy volunteers participated in an experiment by performing five stressful interaction tasks while their skin conductance was monitored. The selected interaction tasks were most frequently listed as stressful by a separate group of 15 interviewees. After each task, participants expressed their perceived emotional experience using the VA rating space. Our findings show which regions in the VA rating space may reliably indicate self-reported stress that is in alignment with one’s measured skin conductance while using interactive applications. One additional important contribution of this work is the proposed approach for the empirical identification of affect regions in the VA space based on physiological signals.