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141.
Min Jeong Noh Tae Gyun Kim In Kwon Hong Ki-Pung Yoo 《Korean Journal of Chemical Engineering》1995,12(1):48-55
A new transparent microscale circulation-type high pressure equilibrium cell with on-line sampling was devised. With this
apparatus, experimental solubility of molecularly complex species such as steroids (cholesterol, stigmasterol and ergosterol)
and fatty acids (palmitic acid and stearic acid) in supercritical carbon dioxide(sc-C02) were measured. Also, to find an appropriate substance for enhancing both the polarity and the solubility power of the SC-CO2 solvent, we arbitrarily selected three polar substances such as acetone, methanol and water and the effect of these cosolvents
on the solubility of solutes in SC-CO2 are examined. The supercritical phase equilibrium data of solute-cosolvent-sc-CO2 systems were quantitatively correlated using a new equation of state based on the lattice fluid theory incorporated with
the concept of multibody interaction. We found that the addition of tracer amount of acetone or methanol to SC-CO2 enhances the solubility of all solutes about thirty to sixty times when compared with the case of pure sc-CO2 However, for the case of cosolvent water, no further enhancement of the solubility of solutes was realized. Also, the versatile
fittability of the equation of state proposed in this work was demonstrated with the newly measured ternary supercritical
equilibrium data. 相似文献
142.
143.
This paper presents the results of a study in the design of a neural network based adaptive robotic control scheme. The neural network used here is a two hidden layer feedforward network and the learning scheme is the well-known backpropagation algorithm. The neural network essentially provides the inverse of the plant and acts in conjunction with a standard PD controller in the feedback loop. The objective of the controller is to accurately control the end position of a single link manipulator in the presence of large payload variations, variations in the link length and also variations in the damping constant. Based on results of this study, guidelines are presented in selecting the number of neurons in the hidden layers and also the parameters for the learning scheme used for training the network. Results also indicate that increasing the number of neurons in the hidden layer will improve the convergence speed of learning scheme up to a certain limit beyond which the addition of neurons will cause oscillations and instability. Guidelines for selecting the proper learning rate, momentum and fast backpropagation constant that ensure stability and convergence are presented. Also, a relationship between the r.m.s. error and the number of iterations used in training the neural network is established. 相似文献
144.
A new hybrid active power filter (APF) topology 总被引:12,自引:0,他引:12
In this paper, a new hybrid active power filter topology is presented. A higher-voltage, low-switching frequency insulated gate bipolar transistor (IGBT) inverter and a lower-voltage high-switching frequency metal oxide semiconductor field effect transistor (MOSFET) inverter are used in combination to achieve harmonic current compensation. The function of the IGBT inverter is to support utility fundamental voltage and to compensate for the fundamental reactive power. The MOSFET inverter fulfills the function of harmonic current compensation. To further reduce cost and to simplify control, the IGBT and MOSFET inverters share the same DC-link via a split capacitor bank. With this approach harmonics can be cancelled over a wide frequency range. Compared to the conventional APF topology, the proposed approach employs lower dc-link voltage and generates less noise. Simulation and experimental results show that the proposed active power filter topology is capable of compensating for the load harmonics 相似文献
145.
146.
Moss C.D. Teixeira F.L. Yang Y.E. Jin Au Kong 《Geoscience and Remote Sensing, IEEE Transactions on》2002,40(1):178-186
A three-dimensional (3D) finite-difference time-domain (FDTD) scheme is introduced to model the scattering from objects in continuous random media. FDTD techniques have been previously applied to scattering from random rough surfaces and randomly placed objects in a homogeneous background, but little has been done to simulate continuous random media with embedded objects where volumetric scattering effects are important. In this work, Monte Carlo analysis is used in conjunction with FDTD to study the scattering from perfectly electrically conducting (PEC) objects embedded in continuous random media. The random medium models under consideration are chosen to be inhomogeneous soils with a spatially fluctuating random permittivities and prescribed correlation functions. The ability of frequency averaging techniques to discriminate objects in this scenarion is also briefly investigated. The simulation scheme described in this work can be adapted and used to help in interpreting the scattered field data from targets in random environments such as geophysical media, biological media, or atmospheric turbulence 相似文献
147.
148.
Kim DeFronzo Haselhoff 《Journal of Urban Affairs》2002,24(4):425-443
I argue that the motivation for the San Fernando Valley secession movement can be explained as a desire for local control based on democratic ideals, but I emphasize that the movement is also motivated in part by the tangible benefits that accompany such autonomy. After a brief look at possible economic and racial motivations behind the secession movement, I look for a political divide between the city and the Valley, based on literature that has found political divisions between urban and suburban areas. Evidence of a political divide is mixed, but does indicate that the Valley lacks representation in comparison to the rest of the city. Valley residents may also fear increasing minority political power, which could erode the dominance of Valley whites at the polls. There is also evidence that those who favor secession are most dissatisfied with representation and most concerned with getting their fair share of services from the city, indicating a strong desire for more local control. Images of a smaller, more democratic government, and a more engaged local civic community are prime motivations in the Valley’s quest for autonomy, though the possibility of reduced taxes, land use control, and increased political power do offer secessionists clear substantive benefits in addition to more democratic goals. 相似文献
149.
Hyun-Goo Kim Wha-Nam Myung K. Sumiyama K. Suzuki 《Journal of Alloys and Compounds》2002,340(1-2):270-274
We report upon the chemical leaching and magnetic properties of nanoscale crystalline Al0.6(Co25Cu75)0.4 alloy powders produced by rod milling. X-Ray diffractometry (XRD), transmission electron microscopy, differential scanning calorimetry, vibrating sample magnetometry, and superconducting quantum interference device magnetometry were used to characterize the as-milled and leached specimens. After 400 h of milling, only the b.c.c. phase of the intermetallic compound γ-Al3.892Cu6.10808 was detected by XRD. After annealing the leached specimen at 600 °C for 1 h, the nanoscale crystalline phase was transformed into the f.c.c. Cu phase, and this was accompanied by a change in the magnetic properties. The peaks of the magnetization shifted towards lower temperature with increasing external field. The temperature behavior at Tf (45 K) for direct current (d.c.) magnetic susceptibility measurements was quite different for field cooling and zero-field cooling. After cooling the leached specimen from 800 °C, magnetization increased gradually. 相似文献
150.
二过碘酸合银(Ⅲ)钾引发丙类酸甲酯在淀粉上接枝共聚合反应的研究 总被引:2,自引:0,他引:2
研究了由二过碘酸合银(Ⅲ)钾(简称Ag(Ⅲ))与可溶性淀粉组成的氧化还原体系,于碱性介质中引发淀粉的接枝共聚合反应,得到高接枝效率的接枝共聚物,测定了引发剂浓度、单体浓度、pH值和反应温度对接枝参数的影响,并探讨了引发机理。 相似文献