利用纳米TiO2微胶粒实施对云母钛珠光颜料表面修饰的研究

本文以光化学反应制备的纳米TiO2微胶粒实施对云母钛珠光颜料表面修饰,以改善其珠光效应.实验表明此种方法可使颜料的平均反射率提高5%以上,效果明显.从结构入手研究了其修饰机理;探讨实验的工艺参数、晶型转化、杂质离子等对珠光颜料光学性能的影响.     

规整填料塔的壁流量计算

推导了板波纹填料塔的壁流量计算方法 ,并探讨填料层分段高度的选择。     

Sex Pheromone Components in Defense of Melon Fly, Bactrocera cucurbitae Against Asian House Gecko, Hemidactylus frenatus

The Asian house gecko, Hemidactylus frenatus, after being acclimatized to feeding on the melon fly, Bactrocera cucurbitae, consumed fewer numbers of 15-day-old (DO) and older male melon flies compared to sexually immature flies 10 DO and younger. The first male melon fly that performed mating did so on the 10th day after eclosion (DAE), but >80% of the males performed their first mating between 10 and 15 DAE. This confirmed that between 10 and 15 DAE most male melon flies are already sexually mature and producing sex pheromone. Synthetic 1,3-nonanediol, a component of male melon fly sex pheromone produced endogenously, when topically applied onto the thorax of housefly Musca domestica at ca. 80 or 320 ng/fly, reduced consumption by geckos compared with untreated flies in subsequent days after the first day in a four-day feeding test. Raspberry ketone (RK) is consumed and sequestered into the pheromonal gland and later released as a pheromonal component of male melon fly. Houseflies topically treated with 2.6 g RK/fly did not deter predation by geckos. However, houseflies treated with 5.1 g RK/fly caused geckos to consume fewer flies, especially on the third and fourth days during a four-day feeding test, compared with the period when they were offered untreated flies.     

板式塔的进展

介绍了板式塔的发展概况,着重浮阀塔板,喷射型塔板,旋流塔板,多降液塔板,复合塔板,并对近年来新开发的塔板的特点和性能进行了简要评述。     

铜铁试剂—示波计时电位法测天然水/饮用水中的铝含量

铜铁试剂(CUP)—示波计时电位法直接测定天然水和饮用水中的铝含量。在0.5 mol/L(NH_4)_2SO_4-NH_3·H_2O(pH值=5.4)缓冲溶液中,加入铝后,铝—CUP配合物切口电位为-1.20V,切口深度在7.2×10~(-7)～3.2×10~(-5)mol/LAl范围内有线性关系,检测下限为5.8×10~(-7)mol/L。在2.0×10~(-5)mol/L时相对标准偏差为5.1(n=10)。应用该法测定了天然水和饮用水中铝含量,并同ICP/AES所获结果进行了对照。结果基本一致。     

聚丙烯/玻璃纤维的界面改性研究(Ⅱ)聚丙烯-马来酸酐接枝共聚物的界面改性研究

研制高性能的玻璃纤维增强聚丙烯复合材料的关键是提高非极性的聚丙烯和极性的玻璃纤维的界面粘结强度。本文首次明确提出接枝率、熔融指数、结晶温度是影响聚丙烯 -马来酸酐接枝共聚物作为界面剂使用的关键因素 ,当接枝共聚物的接枝率高、熔融指数大、结晶温度与聚丙烯基体接近时 ,接枝共聚物有较好的界面改性效果 ,可以使用较少量的接枝共聚物使复合材料的力学性能得到最大程度的改善。     

A fuzzy multiobjective approach for minimization of injection molding defects

This paper describes a fuzzy multiobjective optimization approach for determining the set‐points of the injection molding processing parameters to minimize the defects formed on the molded parts. The severities of the defects are represented by membership functions using the fuzzy set theory. The minimization of these membership functions, which is a multiobjective optimization problem, is transformed into a substitute problem. The preference function in the substitute problem is original and is proposed specifically for characterizing the quality requirements of the injection molding defects. The formulated optimization problem is solved with design of experiments, in which the process behavior is approximated empirically by a set of quadratic polynomials that can be easily optimized. Experimental results are presented to emphasis the workability of the proposed methodology.     

PREPARATION OF PVA/CHITOSAN LIPASE MEMBRANE REACTOR AND ITS APPLICATION TO SYNTHESIS OF MONOGLYCERIDE

PVA/ Chitosan (CS) composite membrane was studied in this paper, which could be used for enzyme processing of fat and oils. The parameters such as concentration of lipase, pH, and cross-linking agent as well as metal ions, which influence the immobilization of lipase in membrane, were optimized. The immobilized lipase was 0.66 u/cm2 and the recovery of immobilized lipase activity was 24%. The membrane reactor could be used to synthesize monoglyceride (MG) with many batches.     

Synthesis,characterization, and properties of novel aromatic polyamides containing phthalazinone moiety

A unsymmetrical and kink non-coplanar heterocyclic dicarboxylic acid monomer, 4-[4-(4-carboxy phenoxy)-naphthyl]-2-(4-carboxyphenyl)phthalazin-1-one (3) was successfully synthesized with high purity and high yields. A series of novel polyamides containing phthalazinone were prepared from the newly synthesized dicarboxylic acid with various aromatic diamines by means of the phosphorylation polycondensation reaction. Molecular weights of the obtained polyamides were evaluated viscometrically, and the inherent viscosities (η_inh) measured were in the range 0.54–0.69 dL/g. These polyamides were amorphous and readily soluble in many organic solvents, such as N-methyl-2-pyrrolidone, N,N-dimethylacetamide, N,N-dimetheylformamide, dimethyl sulfoxide, pyridine, and m-cresol etc., and they could easily be solution-cast into transparent, flexible films with good mechanical properties, with tensile strength ranging from 63.9 to 81.6 MPa and elongation at break from 7.2 to 11.4%. These polymers still kept good thermal stability with high-glass transition temperatures in the range of 283–338 °C, and the decomposition temperature in nitrogen for a 10% weight-loss temperatures in excess of 490 °C, and char yield at 800 °C in nitrogen ranged from 56 to 63%. Furthermore, the polyamides films were essentially colorless; their cut-off wavelengths were between 365 and 379 nm.     

浅探汉代陶瓷艺术的文化内涵

汉代陶瓷艺术在我国漫长的陶瓷史上极具特色和个性张力,异彩纷呈,是中国陶瓷艺术继原始彩陶繁荣之后的又一个兴盛期.本文谨希望浅探在两汉陶瓷艺术背后所折射的其时代之文化内涵.