烯烃聚合单活性中心非茂催化剂的最新研究进展

综述了近几年来烯烃聚合用单活性中心非茂催化剂的研究进展。简要介绍了 2 3种由前、后过渡金属组成的配位化合物催化剂的结构与性能     

炉衬产生的氧对真空钢液脱氮的动力学影响

采用 99.99%氧化镁砂捣打炉衬的 2 0kg真空感应炉 ,研究了超低碳钢熔炼时炉衬产生的氧对真空钢液脱氮的影响。试验结果表明 :钢液中氧含量在 1 2 0× 1 0 - 6 时 ,脱氮的限制性环节是界面化学反应 ;随炉衬中氧的逸出 ,当钢液中氧含量在 5 1 0×1 0 - 6 时 ,真空钢液脱氮处于界面化学反应和液相边界层扩散控制的边缘区域 ,脱氮速率降低     

掺杂Yb的TiO2光催化剂的制备和性能

采用溶胶-凝胶法制备了Yb掺杂TiO2纳米光催化剂,并通过XRD和BET等手段进行了表征.以对苯二甲酸作为探针分子,结合化学荧光技术研究了光催化剂表面羟基自由基的生成;并以苯酚为光催化降解反应模型化合物,考察了光催化剂的活性.测定了苯酚在TiO2和Yb掺杂TiO2光催化剂上的吸附常数.结果表明：Yb掺杂使TiO2的粒径减小,比表面积增大,同时导致羟基自由基的生成速率增大.Yb掺杂有利于反应底物在催化剂表面的吸附,Yb的最佳掺入量为Yb/Ti摩尔比=0.8%.     

第二代反坦克导弹射击训练计算机成绩评定方法

文中应用数理统计方法并结合教学及实弹射击实践,提出了在第二代反坦克导弹模拟训练器材中实现智能化评定射击训练成绩的主要方法.     

In-Situ observation on microfracture behavior ahead of the crack tip in 63Sn37Pb solder alloy

in-situ transmission electron microscopy (TEM) tensile tests on as-cast and aged 63Sn37Pb solder alloys were conducted, and the fracture behavior in nanometer scale ahead of the crack tip was inspected and discussed. Results show that the fracture was completed by connecting the discontinuous cracks or voids. Dislocation behavior was concentrated along the grain boundaries for as-cast samples, and displayed mainly as dislocation climb. The crack was intergranular dominated under the lower strain rate. While remarkable mutual dislocation emission was detected in the aged solder. Transgranular cracks were dominant in the fractured area, and they propagated by linking up with the nanometer scale cracks ahead of the crack tips under the effective promotion of the inverse dislocation emission. At the same time, the partial interphase or intergranular cracks in the thinned area were also found. Under this condition, a new critical stress intensity factor K _c ^′ to define the mutual dislocation emission was proposed.     

自适应抗干扰系统在引信中的应用

为了提高无线电引信的抗干扰性能,研究以自适应天线技术为基础的引信抗干扰系统.根据信号与干扰的具体环境,灵活地控制天线的参数,自动调节方向图,使其零点自适应地对准干扰方向,以实现在空间上对信号的最佳接收和对干扰的有效抑制.     

做好水电建设工程质量监督工作

水电建设工程质量监督工作自2000年开展以来，在质量监督总站指导下，经过大家的共同努力，水电建设工程的质量监督工作发展顺利，并取得了很大成效，但也存在一些不足，这方面的经验和问题很值得认真总结，以适应水电建设新形势的要求。笔者根据参加多年水电工程质量监督工作的实践，想谈谈个人看法，与同仁商榷。     

爆震室内混合物填充特性研究

爆震室内混合物的填充过程是PDE工作循环中的重要一环.为了研究爆震室内的燃料和氧化剂的填充特性,采用大型计算流体力学仿真软件对爆震室内燃料和空气的填充过程进行了数值模拟.计算结果表明,在设定的计算条件下,填充距离随填充时间的增加近似线形增大,填充完毕所需的填充时间约0.125s,且从距封闭端250mm开始,填充后的乙炔质量分数稳定在0.11.     

Perfect Blind-Channel Shortening for Multicarrier Systems

In multicarrier systems, when the order of a channel impulse response is larger than the length of the cyclic prefix (CP), there is a significant performance degradation due to interblock interference (IBI). This paper proposes a blind-channel shortening method in which the equalizer parameter vector is formed by the noise subspace of the received signal correlation matrix so that the output power is maximized. The proposed method can not only shorten the effective channel impulse response to within the CP length but also maximize the output signal-to-interference-and-noise ratio while eliminating the IBI. We point out that the performance depends on the choice of a decision delay and propose a simple method for determining the appropriate delay. We propose both a batch algorithm and an adaptive algorithm and show by simulation that they are superior to the conventional algorithms.     

ADI-FDTD Method With Fourth Order Accuracy in Time

This letter presents an unconditionally stable alternating direction implicit finite-difference time-domain (ADI-FDTD) method with fourth order accuracy in time. Analytical proof of unconditional stability and detailed analysis of numerical dispersion are presented. Compared to second order ADI-FDTD and six-steps SS-FDTD, the fourth order ADI-FDTD generally achieves lower phase velocity error for sufficiently fine mesh. Using finer mesh gridding also reduces the phase velocity error floor, which dictates the accuracy limit due to spatial discretization errors when the time step size is reduced further.