Effect of cations on corrosion of zinc and carbon steel covered with chloride deposits under atmospheric conditions

The effect of sodium, calcium, and magnesium chlorides deposited on zinc and carbon steel surfaces was studied under atmospheric conditions. The cations strongly affected the corrosion rate of zinc, whereas they had a significantly lower impact on the corrosion of carbon steel. The corrosivity of cations of chloride salts for zinc increased in order of Mg²⁺ < Ca²⁺ < Na⁺. The higher corrosion resistance of zinc treated with calcium and magnesium chlorides was connected to prevention of formation of hydrozincite during zinc exposure in wet air. It was observed that zinc weight loss and the carbonate to simonkolleite ratio in corrosion products were correlating. The principal protective effect of bivalent cations can be seen in the decrease of pH of the surface electrolyte, which was caused by hydrolysis of such cations and subsequent formation of simonkolleite that blocked the cathodic sites.     

3D Finite-Element Simulation of a Square Silo with Flexible Walls

Most of the studies that have been published to evaluate stresses on silo walls during filling or discharge stages are based on a rigid wall assumption. In a 2D approach, the wall flexibility can be approximately modeled by using a corrective factor applied to the whole pressure distribution. It has been shown that such models are in agreement with experimental measurements on circular silos. But in square or rectangular silos, the variation of the stiffness of the wall due to vertical or horizontal stiffeners produces nonuniform wall deformations that are not taken into account in the previous axisymmetric 2D model. The aim of this paper is to present a full 3D modeling of the filling and discharge stages using a nonlinear finite-element method. The bulk material behavior is based on an elastoplastic law. Contact elements using a Mohr-Coulomb criterion simulate the interaction between the wall and the bulk material, and the flexibility of the silo structure is modeled with beam and shell elements. A detailed analysis of the numerical results computed for a square silo filled with wheat and discharged through a central outlet is presented and discussed.     

The Safe-SADT method for aiding designers to choose and improve dependable architectures for complex automated systems

Dependability evaluation is crucial to controlling the risks associated with system failure, and for this reason, it is one of the fundamental steps in automated system design. However, the dependability evaluation methods that are currently exploited are not appropriate, given the level of complexity of such industrial systems. The ineffectiveness of the existing methods led us to develop and propose the Safe-SADT (structured analysis and design technique) method. Our method allows the explicit formalization of functional interactions, the identification of the characteristic values affecting the dependability of complex systems, the quantification of the reliability, availability, maintainability, and safety (RAMS) parameters of the system's operational architecture, and the validation of that operational architecture in terms of the dependability objectives and constraints set down in the functional requirement specifications (FRS). The results presented in this paper are limited to RAM quantification.     

Formation of Colony Odor in Ponerine Ant Pachycondyla apicalis

The mechanisms operating in the formation and maintenance of colony odor in the ponerine ant Pachycondyla apicalis were studied using radioactive tracers. Using [l-¹⁴C]acetate as a precursor, the de novo biosynthesis and distribution of pentane-extractable lipids within the ant's body were followed. Twenty-four hours after injection, newly synthesized alkanes, alkenes, as well as more polar lipids were found in the postpharyngeal gland, the epicuticle, and internally. Ants that had their mouths blocked with beeswax possessed significantly less radiolabeled lipids (all classes measured) in the postpharyngeal gland but had augmented levels in the internal pool and the epicuticle. Both hydrocarbons and more polar lipids were exchanged between the respective postpharyngeal glands and the epicuticle. The transfer to postpharyngeal glands was highest when both ants had an open mouth or when the recipient ant had an open mouth but the donor's mouth was blocked. This suggests that the transfer to the postpharyngeal gland in this species is by allogrooming and not by trophallaxis. Transfer to the cuticle was low and comparable in all treatments. Behavioral observations during the first 6 hr of the dyadic encounters and in intact colonies confirmed that the ants did not engage in trophallaxis. The level of transfer to the postpharyngeal gland in P. apicalis was significantly lower than in representatives of other Formicidae subfamilies studied so far. We attribute this difference to the evolution of trophallaxis in the higher Formicidae.     

Impairment of consciously controlled use of memory in schizophrenia.

Recent studies of memory in schizophrenia have shown that explicit but not implicit memory performance is impaired. The hypothesis that schizophrenia is associated with a failure of consciously but not unconsciously (automatic) controlled influence of memory on performance was tested using a procedure providing uncontaminated estimates of consciously controlled and automatic memory processes (i.e., the process-dissociation procedure in a stem completion task). Performance of 35 patients with schizophrenia was compared with that of 35 normal participants. Consciously controlled use but not automatic influences of memory was significantly lower in patients with schizophrenia than in controls. Consciously controlled use of memory was negatively and significantly correlated with positive symptoms of schizophrenia. Schizophrenia differentially affects 2 types of memory processes: It impairs consciously controlled use of memory but spares automatic influences. Positive symptoms could reflect the lack of control from higher level conscious processes. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Prediction of laser beam welding-induced distortions and residual stresses by numerical simulation for aeronautic application

This paper focuses on the prediction of laser beam welding-induced distortions and residual stresses through numerical simulation. Fabrication of fuselage panels of latest generation civil aircraft involves welding of stringers on thin sheets of 6056T4 aluminium alloy. The efforts are made to exercise better control over the excessive out-of-plane distortions. A series of experiments have so far been performed using small specimens. One of the test cases that include single-pass fusion welding on a 6056T4 thin sheet with the industrially used thermal and mechanical boundary and loading conditions is being studied in this work. Laser beam welding in the keyhole regime is employed. The test plate is maintained in position with the help of an air suction table made of aluminium. Although a pressure of 1 bar is used experimentally, yet the possibility of leakage cannot be overruled. Various magnitudes of pressures are, therefore, introduced during numerical simulation to study the effect of each. The effect of contact between test plate and support over thermal and mechanical results is also integrated. A 3D symmetric model of test plate and support is incorporated and the comparison between simulation and experimental results is developed. Finally, a good correlation is found between experimental and simulation results, on the basis of which residual stress state in the test plate is predicted.     

Possibilities and Limits of Application of Electrical Resistance Tomography in Hydrodynamics of Bubble Columns

Knowing the hydrodynamic regime in which is working a bubble column is of great importance because the regime affects strongly the mass transfer between the phases. To this end, we examine the potentialities of an Electrical Resistance Tomography (ERT) device. We analyse cross correlation of electrode pair measurements, of neighbouring pixels and power spectra of averaged pixels within a single plane as well as cross correlations of averaged pixels between two planes, without finding a clear signature of the churn turbulent flow. Variable gas flow rate inputs are used to determine the time resolution of the ERT.     

Characterization of interphases appearing on LiNi0.5Mn0.5O2 using Li MAS NMR

⁷Li MAS NMR, usually a bulk characterization technique, is used here to analyze the positive electrode/electrolyte interphase. The sharpening of the NMR spectra line shape as the amount of surface species increases shows that the observed signal is clearly the sum of signals due to the distribution of lithium ions in the interphase in terms of distance from the bulk of electrode active material. This technique is then used to compare characteristics of the interphase coming from the contact with LiPF₆-based electrolyte in the case of storage or electrochemical cycling. A clear influence of the change of potential on the interphase configuration and in particular on its intimacy with the bulk of active material is deduced from the change in NMR spectra lineshape. This information is hardly obtained by other characterization technique, making NMR a powerful tool for the study of interphases and passivation layers in lithium batteries materials.     

Preparation from bovine colostrum of a fraction rich in latent transforming growth factor-β2 and cleared of most allergenic proteins by one-step Cibacron Blue chromatography

A strategy was developed for the preparation of a latent transforming growth factor-β2 (latent TGF-β2) rich fraction from bovine colostrum. Different conventional chromatography techniques were tested to investigate some physicochemical properties of latent TGF-β2 complexes to optimize their recovery. Three latent TGF-β2 forms were detected by gel filtration (600, 150–250 and 65–150 kDa). Cation exchange chromatography showed that the pI of latent TGF-β2 was above pH 7; hydrophobic interaction chromatography showed that the hydrophobicity of latent TGF-β2 was much higher than that of other whey proteins. Affinity chromatography on Cibacron Blue 3G was used to separate latent TGF-β2 and immunoglobulin G from the most immunogenic proteins, α-lactalbumin, β-lactoglobulin and albumin. Optimum conditions were determined: preparation of a fraction 26 times richer in TGF-β2 than in serocolostrum was obtained with a good yield (up to 70%) of TGF-β2, 80% of which was in the latent form.     

Processing of reaction-bonded B4C–SiC composites in a single-mode microwave cavity

In this study, the reaction sintering of boron carbide, which consists in doing reactive infiltration of molten silicon throughout a porous sample made of B₄C and carbon graphite was investigated. Thus, it has been shown that a single-mode microwave cavity can be successfully used to produce reaction-bonded B₄C–SiC composite. A specific package, consisting of a SiC based susceptor and a boron nitride based insulating container, was used to heat up the B₄C–Si system using a single-mode microwaves cavity under an Ar–H₂ atmosphere. Pore-free B₄C–SiC composite successfully produced consists of a mixture of B₄C and polygonal shaped β-SiC within a residual silicon matrix. The indentation technique permits to determine mechanical properties of the samples which are compared to those obtained conventionally. It appears that the average hardness (H≈22 GPa) value is quite constant all along the sample thickness which highlights good homogeneity of the samples obtained. Some aspects of the microstructure are also discussed and compared to those of samples conventionally obtained.